公开(公告)号：US08147918B2

公开(公告)日：2012-04-03

申请号：US12159785

申请日：2006-12-06

申请人： Burkhard Standke ,  Christian Wassmer ,  Peter Jenkner

发明人： Burkhard Standke ,  Christian Wassmer ,  Peter Jenkner

IPC分类号： B05D1/00 ,  B05D3/00

CPC分类号： C09D4/00 ,  C09D5/08 ,  C09D183/14 ,  C23C2222/20 ,  Y10T428/31663 ,  C08G77/04

摘要： The present invention provides a sol-gel composition which is dilutable with water in any proportion and is based on the reaction of at least the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >1% by weight, (iii) an organic acid as hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, starting from a mass ratio of the solids mass of component (ii) to component (i) 0.75, a process for preparing it and its use, in particular as a sol-gel composition for corrosion control coatings, a corresponding corrosion control coat or primer coat, and articles equipped with such a coating.

摘要翻译： 本发明提供一种溶胶 - 凝胶组合物，其可以以任何比例用水稀释，并且基于至少以下组分的反应：（i）缩水甘油氧基丙基烷氧基硅烷，（ii）固体含量> 1的水性硅溶胶 （iii）作为水解催化剂的有机酸，和（iv）锆酸正丙酯，钛酸丁酯或乙酰丙酮钛作为交联剂，从组分（ii）与组分（i）的固体质量的质量比开始， 0.75，其制备方法及其用途，特别是作为腐蚀控制涂料的溶胶 - 凝胶组合物，相应的腐蚀控制涂层或底漆涂层以及配备有这种涂层的制品。

公开(公告)号：US20100160649A1

公开(公告)日：2010-06-24

申请号：US12376786

申请日：2007-07-09

申请人： Juergen Erwin Lang ,  Georg Markowz ,  Dietmar Wewers ,  Harald Metz ,  Norbert Schladerbeck ,  Peter Jenkner

发明人： Juergen Erwin Lang ,  Georg Markowz ,  Dietmar Wewers ,  Harald Metz ,  Norbert Schladerbeck ,  Peter Jenkner

IPC分类号： C07F7/08 ,  B01J19/00 ,  B01J8/00

CPC分类号： B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00837 ,  B01J2219/0086 ,  B01J2219/00867 ,  B01J2219/00869 ,  B01J2219/00873 ,  B01J2219/00889 ,  C07F7/1876

摘要： The present invention relates to a system, to a reactor and to a process for continuous industrial performance of a reaction wherein allyl glycidyl ether A is reacted with an HSi compound B in the presence of a catalyst C and optionally of further assistants, and the system is based at least on the combination of reactants (3) for components A (1) and B (2), at least one multielement reactor (5) which in turn comprises at least two reactor units in the form of exchangeable pre-reactors (5.1) and at least one further reactor unit (5.3) connected downstream of the prereactors, and on a product workup (8).

摘要翻译： 本发明涉及反应器的系统，以及连续工业化反应的方法，其中烯丙基缩水甘油醚A与催化剂C和任选的其它助剂的存在下与HSi化合物B反应，并且系统 至少基于组分A（1）和B（2）的反应物（3）的组合，至少一个多元素反应器（5），其又包含至少两个可交换的预反应器形式的反应器单元（ 5.1）和连接在预反应器下游的至少一个另外的反应器单元（5.3）和产品后处理（8）。

公开(公告)号：US06528585B1

公开(公告)日：2003-03-04

申请号：US09830157

申请日：2001-07-19

申请人： Burkhard Standke ,  Jaroslaw Monkiewicz ,  Albert-Johannes Frings ,  Ralf Laven ,  Roland Edelmann ,  Peter Jenkner ,  Helmut Mack ,  Michael Horn

发明人： Burkhard Standke ,  Jaroslaw Monkiewicz ,  Albert-Johannes Frings ,  Ralf Laven ,  Roland Edelmann ,  Peter Jenkner ,  Helmut Mack ,  Michael Horn

IPC分类号： C08F800

CPC分类号： C08F255/02 ,  C08F291/00

摘要： The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is carried out in the presence of (a) an alkylsilane of the formula I, R1(SiR2nX3−n)m,  (I)  where R1 is a monovalent hydrocarbon radical having from 1 to 33 carbon atoms or a divalent hydrocarbon radical having from 4 to 24 carbon atoms, R2 is a hydrocarbon radical having from 1 to 10 carbon atoms, X are identical or different hydrolyzable radicals, n is 0, 1 or 2 and m is 1 or 2 and/or (b) a fluoroalkylsilane of the formula R3xSiR4yXz,  (II)  where R3 is a fluoroalkyl radical, R4 is an alkyl radical and X is a hydrolyzable radical, x is an integer from 1 to 3, y is 0, 1 or 2 and z is an integer from 1 to 3,  with the proviso that the sum x+y+z=4.

摘要翻译： 本发明涉及制备具有至少一个可水解基团的可交联聚合物的交联聚合物的方法，所述硅烷基团具有至少一个可水解基团的烯属不饱和硅烷通过自由基引发接枝基础聚合物，其中接枝在 存在（a）式I的烷基硅烷，其中R 1是具有1至33个碳原子的一价烃基或具有4至24个碳原子的二价烃基，R 2是具有1至10个碳原子的烃基 X为相同或不同的可水解基团，n为0,1或2，m为1或2，和/或（b）下式的氟代烷基硅烷，其中R 3为氟代烷基，R 4为烷基，X为可水解基团，x为 是1至3的整数，y是0,1或2，z是1至3的整数，条件是和x + y + z = 4。

公开(公告)号：US06288256B1

公开(公告)日：2001-09-11

申请号：US09229124

申请日：1999-01-12

申请人： Burkhard Standke ,  Roland Edelmann ,  Albert-Johannes Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Helmut Mack ,  Jaroslaw Monkiewicz

发明人： Burkhard Standke ,  Roland Edelmann ,  Albert-Johannes Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Helmut Mack ,  Jaroslaw Monkiewicz

IPC分类号： C07F708

CPC分类号： C04B41/009 ,  B05D1/18 ,  B05D5/08 ,  B05D5/083 ,  B05D2201/00 ,  B05D2202/00 ,  B05D2203/20 ,  B05D2203/22 ,  B05D2203/24 ,  B05D2203/30 ,  B05D2203/35 ,  C03C17/30 ,  C04B41/4961 ,  C04B41/64 ,  C04B41/84 ,  C04B2111/1012 ,  C04B2111/203 ,  C04B2111/27 ,  C08G77/24 ,  C08G77/26 ,  C09D183/08 ,  C09K3/18 ,  C23C30/00 ,  C23C2222/20 ,  D06M15/6436 ,  D06M15/657 ,  D06M2101/06 ,  D21H17/59 ,  D21H21/16 ,  Y10T428/24355 ,  Y10T428/24372 ,  Y10T428/2438 ,  Y10T428/24388 ,  Y10T428/24405 ,  Y10T428/24994 ,  Y10T428/249946 ,  Y10T428/249947 ,  Y10T428/249974 ,  Y10T428/8305 ,  C04B33/00 ,  C04B14/043 ,  C04B28/02

摘要： An aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO [Si(A)(CH3)z(OH)1−zO]a[Si(B)(R2)y(OH)1−yO]b[Si(C)(CH3)O]c[Si(D)(OH)O]dH.(HX)e  (I), wherein A is an aminoalkyl group of formula II: H2N (CH2)f(NH)g(CH2)hSi(OR)3−z(CH3)z  (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R1—Y—(CH2)2Si(R2)Y(OR)3−y  (III) wherein R1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms, or a mono-, oligo- or perfluorinated aryl group, Y is a CH2, O or S group, R2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R3—Si(CH3)(OR)2  (IV), and D is an alkyl group of formula V: R3—Si(OR)3  (V) wherein R3, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and HX is an acid, in which X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

摘要翻译： 含有机聚硅氧烷的组合物包含式I的有机聚硅氧烷：其中A是式II的氨基烷基：其中0≤f≤6，如果f = 0，则g = 0，如果f> 0，则g = = h <= 6且0 <= z <= 1; B是式III的氟烷基：其中R1是具有1-9个C原子的单，低聚或全氟化烷基，或单 - 或全氟化芳基，Y为CH 2，O或S基团，R 2为具有1-8个碳原子或芳基且0 <= y <1的直链，支链或环状烷基; C为 式Ⅳ：和D是式Ⅴ的烷基：其中R 3在每种情况下是相同或不同的，并且是具有1-8个C原子的直链，支链或环状的烷基，R在每种情况下是相同的或 不同的是具有1-8个碳原子或芳基的直链，支链或环状的烷基; HX是酸，其中X是无机或有机酸基，0 <= y <= 1,0 <= z <= 1，a> 0，b> 0，c> = 0，d> = 0，e> = 0，（a + b + c + d）> = 2， 有机溶剂，闪点高于70℃，在用水稀释时通过水解基本上不释放醇。

公开(公告)号：US5932757A

公开(公告)日：1999-08-03

申请号：US877556

申请日：1997-06-17

申请人： Burkhard Standke ,  Roland Edelmann ,  Albert Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Jaroslaw Monkiewicz ,  Lothar Elfenthal ,  Hans-Hermann Luginsland

发明人： Burkhard Standke ,  Roland Edelmann ,  Albert Frings ,  Michael Horn ,  Peter Jenkner ,  Ralf Laven ,  Jaroslaw Monkiewicz ,  Lothar Elfenthal ,  Hans-Hermann Luginsland

IPC分类号： C07F7/18 ,  B01J2/30 ,  C07F7/08 ,  C07F7/21 ,  C08G77/04 ,  C09D183/04

CPC分类号： B01J2/30 ,  C07F7/0859 ,  C07F7/21 ,  C08G77/045 ,  C09D183/04

摘要： A mixture of oligomers of alkylalkoxysilanes condensed in the chain and/or cyclic form, said mixture of oligomers containing less than 2% by weight of free alcohols and the condensed alkoxysilanes satisfying formula I: ##STR1## wherein R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen, or is (iii) ethyl or hydrogen, the degree of oligomerization being in the range 2.ltoreq.x.ltoreq.20 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1; and/orsatisfying formula II: ##STR2## in which R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen or is (iii) ethyl or hydrogen, the degree of oligomerization being x.gtoreq.3 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1.

摘要翻译： 以链和/或环状缩合的烷基烷氧基硅烷的低聚物的混合物，所述含低于2重量％游离醇的低聚物混合物和满足式I的缩合烷氧基硅烷：其中R是具有3至18个碳原子的烷基 ，并且每个R'是选自甲基，乙基或氢的成员（i），或（ii）甲基或氢，或（iii）乙基或氢，低聚度的范围为2 = 1的商; 和/或满足式II：其中R是具有3至18个碳原子的烷基，并且每个R'是选自甲基，乙基或氢的成员（i），或者是（ⅱ）甲基或 氢或是（ⅲ）乙基或氢，低聚度为x≥3，摩尔比[Si /烷氧基]> = 1的商。

公开(公告)号：US5817854A

公开(公告)日：1998-10-06

申请号：US978025

申请日：1997-11-25

申请人： Michael Horn ,  Albert-Johannes Frings ,  Peter Jenkner ,  Jaroslaw Monkiewicz ,  Claus-Dietrich Seiler ,  Burkhard Standke ,  Bertram Trautvetter

发明人： Michael Horn ,  Albert-Johannes Frings ,  Peter Jenkner ,  Jaroslaw Monkiewicz ,  Claus-Dietrich Seiler ,  Burkhard Standke ,  Bertram Trautvetter

IPC分类号： B01J31/02 ,  C07B61/00 ,  C07F7/18 ,  C07F7/08

CPC分类号： C07F7/1896

摘要： Organocarbonoyloxysilanes are prepared by reacting an organochlorosilane with a carboxylic acid in a first step which liberates HCl, removing the HCl which is formed, reacting the reaction mixture from the first step with a carboxylic acid anhydride in a second reaction step, the first and/or second reaction steps being conducted in the presence of a catalyst, and isolating the resulting organocarbonoyloxysilane product from the reaction mixture.

摘要翻译： 有机氯硅烷与羧酸反应制备，第一步是释放HCl，除去形成的HCl，使第一步的反应混合物与羧酸酐在第二反应步骤中反应，第一和/或 在催化剂存在下进行第二反应步骤，并从反应混合物中分离得到的有机碳硅烷氧基硅烷产物。

公开(公告)号：US08039110B2

公开(公告)日：2011-10-18

申请号：US11995215

申请日：2006-06-02

申请人： Peter Jenkner ,  Burkhard Standke ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Alireza Kharazipour ,  Lars Kloeser

发明人： Peter Jenkner ,  Burkhard Standke ,  Jaroslaw Monkiewicz ,  Roland Edelmann ,  Alireza Kharazipour ,  Lars Kloeser

IPC分类号： B32B3/12 ,  B32B5/24 ,  B32B5/16

CPC分类号： C08L97/02 ,  C08K5/544 ,  Y10T428/24124 ,  Y10T428/249965 ,  Y10T428/249972 ,  Y10T428/253 ,  Y10T428/254 ,  Y10T428/31591 ,  C08L2666/44

摘要： A composite material, useful in producing wood-based materials, comprises (a) at least one cellulose- or lignocellulose-containing material and (b) at least one aminoalkylsilane, or at least one cocondensate of the at least one aminoalkylsilane and at least one further functional silane, or an aqueous solution which contains the at least one aminoalkylsilane or the at least one cocondensate of the at least one aminoalkylsilane and the at least one further functional silane.

摘要翻译： 可用于生产木质材料的复合材料包括（a）至少一种含纤维素或木质素纤维素的材料和（b）至少一种氨基烷基硅烷，或至少一种氨基烷基硅烷的至少一种缩聚物和至少一种 进一步官能的硅烷或含有至少一种氨基烷基硅烷或至少一种氨基烷基硅烷和至少一种其它官能硅烷的至少一种缩聚物的水溶液。

公开(公告)号：US20080003448A1

公开(公告)日：2008-01-03

申请号：US11569363

申请日：2005-05-12

申请人： Burkhard Standke ,  Peter Jenkner

发明人： Burkhard Standke ,  Peter Jenkner

IPC分类号： C07F7/21 ,  C08G77/26 ,  C09D183/00 ,  C09D4/00

CPC分类号： C08J3/095 ,  C07F7/21 ,  C08J2383/08 ,  Y10T428/12569 ,  Y10T428/31612 ,  Y10T428/31663

摘要： Stable, low-chloride solutions of hydrosalts of organic acids with cationic N substituted aminopolysiloxanes of the formula (I) in which groups R independently of each other are each benzyl or vinylbenzyl, groups Y are identical or different and Y is an alkoxy or hydroxyl group or 01/2, A is an organic carboxylic acid and 0≦a

摘要翻译： 其中基团R各自独立地为苄基或乙烯基苄基的式（I）的阳离子N取代的氨基聚硅氧烷的有机酸稳定的低氯化物溶液是相同或不同的，Y是烷氧基或羟基 或0 <1/2，A是有机羧酸，0 <= a <2,0 <= b <= c1 = 0.125,0.125 <=（a + b）≤3 和x> = 2，其基本上以低级醇中的T结构单元的形式存在。 通过与NaOH或醇钠或与有机羧酸A的钠盐反应，从阳离子N-取代的氨基聚硅氧烷的相应的盐酸盐进行制备，析出和除去NaCl。 这些溶液用作有机和无机表面之间的粘合促进剂，与有机聚合物与无机填料，玻璃纤维或金属颗粒的增强有关，或与无机表面与有机聚合物的涂层有关，其中氨基聚硅氧烷涂层厚度为 达到800nm。

公开(公告)号：US06500883B1

公开(公告)日：2002-12-31

申请号：US09660173

申请日：2000-09-12

申请人： Helmut Mack ,  Peter Jenkner ,  Roland Edelmann ,  Dieter Barfurth ,  Alber-Johannes Frings ,  Burkhard Standke ,  Jaroslaw Monkiewicz ,  Michael Horn ,  Thomas Schlosser

发明人： Helmut Mack ,  Peter Jenkner ,  Roland Edelmann ,  Dieter Barfurth ,  Alber-Johannes Frings ,  Burkhard Standke ,  Jaroslaw Monkiewicz ,  Michael Horn ,  Thomas Schlosser

IPC分类号： C08K906

CPC分类号： C08K9/06 ,  C08L77/00

摘要： Fillers surface-modified by treatment with an organosilane- and/or organosiloxane-containing agent for preparing filled polyamide compositions.

摘要翻译： 用用于制备填充的聚酰胺组合物的有机硅烷和/或含有机硅氧烷的试剂进行表面改性的填料。

公开(公告)号：US06491838B1

公开(公告)日：2002-12-10

申请号：US09712224

申请日：2000-11-15

申请人： Burkhard Standke ,  Michael Horn ,  Peter Jenkner ,  Jaroslaw Monkiewicz

发明人： Burkhard Standke ,  Michael Horn ,  Peter Jenkner ,  Jaroslaw Monkiewicz

IPC分类号： C14C900

CPC分类号： C04B41/009 ,  C01P2004/64 ,  C02F1/00 ,  C04B41/4961 ,  C07F7/12 ,  C08G77/24 ,  C08G77/26 ,  C08L83/08 ,  C09C3/12 ,  C09D183/08 ,  C23C2222/20 ,  C04B14/043

摘要： An organosiloxane which has at least one triamino group of formula I: [NHx(CH2)aNHy(CH2)bNHz]—  (I) which is bonded to at least one silicon atom via at least one N-bonded alkylene group having 1 to 4 C atoms, a and b are identical or different and are each an integer ranging from 1 to 6, x is 0 or 1 or 2, y is 0 or 1, z is 0 or 1 or 2, with the proviso that (x+y+z)≦4, and at least one Si—C-bonded fluoroalkyl group of formula II: F3C(CF2)r(CH2)s—  (II)  wherein r is 0 or an integer ranging from 1 to 18 and s is 0 or 2.

摘要翻译： 具有至少一个式I的三氨基的有机硅氧烷：其通过至少一个具有1-4个C原子的N-键合的亚烷基与至少一个硅原子键合，a和b相同或不同，并且各自为整数 范围从1到6，x是0或1或2，y是0或1，z是0或1或2，条件是（x + y + z）<= 4，并且至少一个Si-C- 式II的键合氟代烷基：其中r为0或1至18的整数，s为0或2。