摘要:
A process for fireproofing polyester fibers in which a sulphonamide of the formula ##STR1## in which R is an aromatic, cycloaliphatic or aliphatic radical or hydrogen and in which the ring A is unsubstituted or further substituted or in which a hydrazonium or ammonium salt of such a sulphonamide is applied to the fiber material which is then dried and subjected to a heat treatment. The sulphonamide may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.
摘要:
The invention relates to a flameproofing agent which contains a brominated cycloalkane and a dispersant. The flame-proofing agent may also contain a protective colloid and/or water. In addition, a method of providing synthetic materials of polyester or polyamide with a flame-retardant finish with the aqueous flameproofing agents is disclosed.
摘要:
The invention relates to a fluorescent pigment comprising a) a melamine-formaldehyde polycondensation product, b) a distyryl biphenyl fluorescent whitening agent (FWA) of the formula (1), in which R1 represents hydrogen, chlorine or C1-C4alkoxy and M represents hydrogen, an alkaline or alkaline earth metal, ammonium or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl or C2-C4hydroxyalkyl and, optionally, c) at least one additional fluorescent whitening agent, a process for its preparation and use thereof for the fluorescent whitening of paper, especially in coating.
摘要:
A whitening pigment comprising the reaction product of (a) a melamine-formaldehyde and/or a melamine-urea poly-condensation product and (b) a water-soluble fluorescent whitening agent of the formula (1), wherein each of the two R1 groups, independent of the other, represents a C1-C6alkyl or C1-C4alkyl-O—C1-C4alkyl residue, which is substituted by one or two —CONH2, —CONHC1-C4alkyl, —COOH, —SO2NH2, —SO2NHC1-C4alkyl or —NH2 groups, each of the two R2 groups, independent of the other, represents hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl or C1-C4alkoxyC1-C4alkyl, or R1 and R2 together with the nitrogen atom complete a piperazine ring, each of the two X1 groups, independently, represent —OH, —OC1-C4alkyl, —Oaryl or the group —NR3R4, wherein R3 and R4 each, independently, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalky, C1-C4alkoxyC1-C4alkyl, a phenyl, phenyl mono- or disulphonic acid residue or, R3 and R4, together with the nitrogen atom to which they are attached, complete a morpholino, piperidino or pyrrolidino ring or, alternatively, X1 represents an amino acid residue from which a hydrogen atom has been abstracted from the amino group and M is hydrogen, an alkaline or alkaline earth metal ion, ammonium, mono- di-, tri- or tetra-substituted C1-C4alkylammonium or C2-C4hydroxyalkylammonium or mixtures thereof, a process for preparation of the pigments and the use thereof for the fluorescent whitening of paper.
摘要:
The present invention provides novel bis-triazinylaminostilbene amphoteric fluorescent whitening agents, comprising both individual components and mixtures thereof, a process for their preparation, intermediates useful for their prepartion and use of the fluorescent whitening agents for the fluorescents whitening of paper.
摘要:
The present invention relates to a fluorescent whitening agent comprising a mixture of two symmetrically and one asymmetrically substituted triazinylaminostilbene disulphonic acids, novel asymmetrically substituted derivatives, a process for their preparations and use of the mixture for whitening synthetic or natural organic materials, especially paper and for the fluorescent whitening and improvement of sun protection factors of textile materials.
摘要:
The use of whitening pigments comprising (a) a melamine-formaldehyde or phenol-formaldehyde polycondensation product and (b) a water-soluble fluorescent whitening agent of formula (1), wherein R1 and R2 are each independently of the other —OH, —Cl, —NH2, —O—C1-C4alkyl, —O—aryl, —NH—C1-C4alkyl, —N(C1-C4alkyl)2, —N(C1-C4alkyl)(C1-C4hydroxyalkyl), —N(C1-C4hydroxyalkyl)2, or —NH—aryl, for example aniline-mono- or -di-sulfonic acid or an anilinesulfon-amide, morpholino, S—C1-C4alkyl(aryl), or a radical of an amino acid, for example aspartic acid or inimoacetic acid, which radical is substited at the amino group, and M is hydrogen; sodium; potassium; calcium; magnesium; ammonium; mono-, di-, tri- or tetra-C1-C4alkylammoniun; mono-, di- or tri-C1-C4hydroxyalkylammonium; or ammonium di- or tri-substitue by a mixture of C1-C4 alkyl and C1-C4hydroxyalkyl groups, for whitening paper coating compositions.
摘要:
The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine, L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.
摘要:
Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.
摘要:
A process for fireproofing polyester fibers is provided in which a substituted mono- or disulphurylamide of the formula ##STR1## wherein n is 1 or 2, R are aromatic, cycloaliphatic or aliphatic radicals or hydrogen and A is alkylene or an ammonium salt of such a sulphurylamide is applied to the fiber material which is then dried and subjected to a heat treatment. The sulphurylamide may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.