-
公开(公告)号：US5760265A
公开(公告)日：1998-06-02
申请号：US611162
申请日：1996-03-05
IPC分类号： B01J31/04 , C07B61/00 , C07B63/02 , C07C67/08 , C07C67/60 , C07C69/24 , C07C69/44 , C07C69/50 , C07C69/58 , C07C69/80 , C07C67/14 , C07F7/28
CPC分类号： C07C67/08
摘要： The present invention provides a process for preparation of an ester comprising reacting a carboxylic acid and an alcohol in the presence of an esterific catalyst comprising at least one compound selected from the group consisting of halides, nitrates, carboxylates, alcoholates and acetylacetone complexes of metals of the titanium group. According to the present process, substantially equal equivalent of the alcohol and the acid can be reacted completely. In addition, the present invention further provides a purification process to eliminate the catalyst from homogeneous reaction system completely.
摘要翻译： 本发明提供了一种制备酯的方法，包括使羧酸和醇在含有至少一种选自卤化物，硝酸盐，羧酸盐，醇盐和乙酰丙酮络合物的化合物存在下反应， 钛组。 根据本方法，基本上相当于醇和酸的当量可以完全反应。 此外，本发明还提供了从均匀的反应体系中完全除去催化剂的纯化方法。
-
公开(公告)号：US5571442A
公开(公告)日：1996-11-05
申请号：US469823
申请日：1995-06-06
申请人： Takao Masaki , Tomoo Komatsubara , Seizi Nakanishi
发明人： Takao Masaki , Tomoo Komatsubara , Seizi Nakanishi
IPC分类号： C08L83/04 , D01F9/22 , D06M13/02 , D06M13/144 , D06M13/224 , D06M13/322 , D06M13/342 , D06M13/345 , D06M15/53 , D06M15/643
CPC分类号： D06M15/6436 , D01F9/22 , D06M13/224 , D06M13/342 , D06M7/00 , D06M2200/40
摘要： A textile treating composition imparting durable water repellency, detachability, heat resistance, and smooth and slick handle to acrylic fiber and polyacrylo- nitril precursors for carbon fiber; and minimizing stain on guides or rolls in fiber processing is disclosed. The composition comprises amino-modified polysiloxanes, monoesters of dicarboxylic acids, nonionic surfactants, and amino carboxylic acids.
摘要翻译： 一种纺织品处理组合物，其对丙烯腈纤维和碳纤维的聚丙烯腈前体赋予耐久的拒水性，可剥离性，耐热性和光滑和光滑的手感; 并且公开了使纤维加工中的引导件或辊上的污染最小化。 该组合物包含氨基改性聚硅氧烷，二羧酸单酯，非离子表面活性剂和氨基羧酸。
-
公开(公告)号：US4582756A
公开(公告)日：1986-04-15
申请号：US630125
申请日：1984-07-12
申请人： Kikuo Niinuma , Yoshifumi Morimoto
发明人： Kikuo Niinuma , Yoshifumi Morimoto
IPC分类号： B01J13/02 , B01J13/22 , B05D7/00 , B29K105/04 , C08J9/32 , C08K7/22 , C08L101/00 , C09D7/12 , B32B5/16 , B32B3/26
CPC分类号： C09D7/1291 , B01J13/22 , C08J9/32 , C08K7/22 , C09D7/125 , C08L2205/20 , C08L27/04 , C08L33/18 , Y10T428/249971 , Y10T428/249972 , Y10T428/254 , Y10T428/2991 , Y10T428/2998 , Y10T428/31786 , Y10T428/3192 , Y10T428/31928 , Y10T428/31942
摘要： Inorganic fillers such as silica balloons are used as a lightweight filler for resin moldings. But the specific gravity of these inorganic fillers is about 0.2 at most, so that there is a limit to reduction in weight. The foamed product of organic polymers is obtained as a lightweight substance, but it is hardly put to practical use because of its poor solvent resistance and thermal resistance.The microballoon of the present invention is produced by coating the surface of a hollow particle having the wall film of a thermoplastic high polymer with a thermosetting resin.The present invention provides a microballoon having excellent solvent resistance and thermal resistance as well as a very low specific gravity, and said microballoon is useful as a lightweight filler for resin moldings, aggregate for FRP, ingredient for paints, and the like.
摘要翻译： 无机填料如二氧化硅气球用作树脂模制品的轻质填料。 但是，这些无机填料的比重最多为0.2左右，因此重量减少是有限度的。 获得有机聚合物的发泡产物作为轻质物质，但由于其耐溶剂性和耐热性差，所以难以实际应用。 本发明的微球通过用热固性树脂涂布具有热塑性高分子聚合物的壁的中空颗粒的表面来制造。 本发明提供了具有优异的耐溶剂性和耐热性以及非常低的比重的微球，并且所述微球可用作树脂模制品的轻质填料，FRP用聚集体，油漆成分等。
-
公开(公告)号：US20220127478A1
公开(公告)日：2022-04-28
申请号：US17437923
申请日：2020-03-17
发明人： Koichi SAKABE , Katsushi MIKI
摘要： Hollow resin particles for thermosensitive recording media containing a thermoplastic resin shell and a hollow part surrounded by the shell. The hollow resin particles contain a thermally-vaporizable hydrocarbon in an encapsulation ratio of at least 0.2 wt %. The hollow resin particles preferably have a mean volume particle size ranging from 0.1 to 10 μm.
-
公开(公告)号：US20210275982A1
公开(公告)日：2021-09-09
申请号：US17259242
申请日：2019-07-05
发明人： Nobuaki FUJII , Sachiko TOKUMURA , Katsushi MIKI
IPC分类号： B01J13/18 , C08F220/44 , C08F220/14 , C08F2/16 , C09D7/65 , C09D5/03
摘要： Heat-expandable microspheres containing a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is a polymer of a polymerizable component containing acrylonitrile, methacrylonitrile and acrylate ester and which satisfies specific conditions 1 and 2, where Condition 1: the amount of the acrylonitrile (A)
-
公开(公告)号：US10941267B2
公开(公告)日：2021-03-09
申请号：US15575125
申请日：2016-05-18
发明人： Sachiko Tokumura , Yu Kita
摘要： Heat-expandable microspheres and applications thereof, the heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is produced by polymerizing a polymerizable component containing (A) a nitrile monomer including methacrylonitrile, (B) a carboxyl-group-containing monomer and (C) a monomer having a functional group reactive with the carboxyl group. The polymerizable component satisfies the following conditions 1 and 2:
Condition 1: The weight fraction of the monomers (A), (B) and (C) in the polymerizable component satisfy the inequality shown below. Weight fraction of the monomer (C)-
公开(公告)号：US20200332085A1
公开(公告)日：2020-10-22
申请号：US16954576
申请日：2018-12-14
发明人： Takumi EBE , Katsushi MIKI
摘要： A resin composition containing heat-expandable microspheres including a thermoplastic resin shell and a thermally vaporizable blowing agent encapsulated therein and at least one base resin selected from rubbers, olefin resins and thermoplastic elastomers. The thermoplastic resin is a polymer of a polymerizable component containing N-substituted maleimide and a nitrile monomer containing methacrylonitrile. Also disclosed are molded articles manufactured by molding the resin composition.
-
公开(公告)号：US20190194415A1
公开(公告)日：2019-06-27
申请号：US16322218
申请日：2017-07-07
发明人： Naoya TAYAGAKI , Katsushi MIKI
摘要： Hollow resin particles, a production process for producing the same and application thereof. The hollow resin particles include a thermoplastic resin shell and a hollow part surrounded by the shell. The thermoplastic resin is a polymer produced from a polymerizable component containing 0.6 to 3.0 wt % of a crosslinkable monomer having at least two polymerizable carbon-carbon double bonds per molecule and 97 to 99.4 wt % of an uncrosslinkable monomer having one polymerizable carbon-carbon double bond per molecule. A blowing agent is encapsulated in the hollow resin particles. The blowing agent contains 50 to 100 wt % of an organic compound having a vapor pressure higher than 100 kPa at 25° C. Further, the encapsulation ratio of the blowing agent ranges from 3 to 13 wt % of the hollow resin particles.
-
公开(公告)号：US10130928B2
公开(公告)日：2018-11-20
申请号：US15104628
申请日：2014-12-15
发明人： Daisuke Nakatomi , Kazunari Ueda , Katsushi Miki
IPC分类号： C08J9/14 , B32B27/00 , B01J13/18 , B32B13/00 , B01J13/14 , H01M4/04 , H01M4/133 , H01M4/134 , H01M4/38 , H01M4/583 , H01M4/62 , H01M4/66 , H01M10/0525 , H01M4/1393 , H01M4/587 , H01M4/02 , H01M10/052
摘要： A process for producing heat-expandable microspheres including a thermoplastic resin shell and a blowing agent encapsulated therein. The process includes the steps of dispersing a polymerizable component and the blowing agent in an aqueous dispersion medium having a pH of 7 or less and containing a fine-particle metal compound having a mean particle size ranging from 1.0 to 10 nm, and polymerizing the polymerizable component. The amount of the fine-particle metal compound ranges from 0.15 to 20 parts by weight to 100 parts by weight of the total amount of the polymerizable component and the blowing agent. Also disclosed are heat-expandable microspheres produced by dispersing a polymerizable component and a blowing agent in an aqueous dispersion medium containing colloidal silica and polymerizing the polymerizable component. Also disclosed is a composition containing the heat-expandable microspheres and a base component, a formed product, a slurry composition for use in forming a negative electrode of a lithium-ion secondary battery and a negative electrode.
-
公开(公告)号：US20170081492A1
公开(公告)日：2017-03-23
申请号：US15311742
申请日：2015-05-18
发明人： Koichi SAKABE , Katsushi MIKI , Yasuyuki NOMURA
CPC分类号： C08J9/20 , B01J13/18 , B01J13/185 , C08F2/18 , C08F220/00 , C08F220/14 , C08J9/0061 , C08J9/141 , C08J9/16 , C08J9/228 , C08J9/32 , C08J2201/024 , C08J2203/14 , C08J2323/06 , C08J2331/04 , C08J2333/12 , C08J2423/08 , C08J2431/04 , C08J2433/12 , C08F220/06 , C08F220/44 , C08F2220/1808
摘要： Heat-expandable microspheres having an almost spherical shape and high expansion performance and exhibiting good workability when mixed with a resin, a process for producing the heat-expandable microspheres, and applications thereof. The heat-expandable microspheres include a thermoplastic resin shell and a blowing agent encapsulated therein and vaporizable by heating. The thermoplastic resin is produced by polymerizing a polymerizable component containing a methacrylate monomer and a carboxyl-containing monomer, and optionally containing a nitrile monomer in an amount ranging from 0 to 30 parts by weight to 100 parts by weight of the total amount of the methacrylate monomer and the carboxyl-containing monomer. The blowing agent contains a hydrocarbon having at least 8 carbon atoms per molecule.
-
-
-
-
-
-
-
-
-
搜索结果
105 条记录 (耗时 0.031 秒)