摘要:
The combined capillary electrophoresis electrospray mass spectrometry apparatus has a circuit to handle excess current allows separations under a wide range of electrophoretic conditions. The apparatus includes an electrospray with an emitter and an electrospray interface connected with a separation capillary configured to transport a sample with an injection end and a distal end. The injection end of the separation capillary is inserted into a reservoir containing a background electrolyte and the distal end is threaded within the electrospray interface and sized and shaped to mate with the electrospray interface. A power supply is electrically connected to the injection end and an amplifier at least one first diode positioned between the amplifier and the distal end allows current to flow to the distal end only. A second diode positioned between the distal end and a ground configured to allow current flow to the ground.
摘要:
Methods and systems for the separation of isotopes from an aqueous stream are described as can be utilized in one embodiment to remove and recover tritium from contaminated water. Methods include counter-current flow of an aqueous stream on either side of a separation membrane. The separation membrane includes an isotope selective layer (e.g., graphene) and an ion conductive supporting layer (e.g., Nafion®). An electronic driving force encourages passage of isotopes selectively across the membrane to enrich the flow in the isotopes.
摘要:
A system and method for continuously separating different isotopes of a particular element, such as Uranium, Zirconium, or Hydrogen, in an electrolytic medium. The ions of the isotopes to be separated are moved in the electrolytic medium using electric field. As the lighter ions will move faster than the heavier ions, the separation will happen and the lighter ions will be ahead of the heavier ions by a separation distance. To improve the separation, other forces (either proportional to the mass or not) are generated on the ions in directions that add additional separation factors. These forces could be centrifugal, electromagnetic, resistive dragging, mechanical (flow), etc. The invented separation process and device is simple and less expensive than other comparable devices, providing outstanding separation at low cost, and could be built using the already available materials and technologies that exist in any country in the world.
摘要:
Novel method and apparatus for separating, purifying and/or concentrating ions in a mixture of different molecular species using a method of electrophoresis in the presence of a counterflowing carrier fluid are provided. By selecting the appropriate carrier fluid flow rate, magnitude of the current and varying separation characteristics in a separation chamber, one or more similarly charged species of ions can be segregated into separate or discrete equilibrium zones within the chamber.