公开(公告)号：US4246355A

公开(公告)日：1981-01-20

申请号：US864474

申请日：1977-12-27

Applicant: Brian A. Bolto ,  David R. Dixon ,  Robert J. Eldridge

Inventor： Brian A. Bolto ,  David R. Dixon ,  Robert J. Eldridge

IPC: C08F2/00 ,  B01J39/16 ,  B01J39/17 ,  B01J41/08 ,  B01J41/14 ,  B01J47/00 ,  B01J47/016 ,  B01J47/018 ,  B01J49/00 ,  B01J49/45 ,  C02F1/28 ,  C02F1/48 ,  C02F1/54 ,  C08F2/44 ,  C08F4/00 ,  C08F4/40 ,  C08F261/04 ,  C08F265/10 ,  C08F291/00 ,  C08F292/00 ,  C08J5/20 ,  C08K3/22 ,  C09C1/22 ,  C09C1/24 ,  G11B5/702 ,  H01F1/113 ,  H01F1/37 ,  H01F1/42 ,  C08J9/00

CPC classification number: H01F1/42 ,  B01J20/28009 ,  B01J20/3293 ,  B01J39/165 ,  B01J47/006 ,  B01J47/007 ,  B01J49/006 ,  C02F1/288 ,  C02F1/488 ,  C02F1/54 ,  C08F261/04 ,  C08F265/10 ,  C08F291/00 ,  C08F292/00 ,  C09C1/22 ,  C09C1/24 ,  G11B5/7027 ,  H01F1/113 ,  H01F1/37 ,  C01P2004/61 ,  C01P2006/42

Abstract: Processes for making copolymers comprising treating a reaction mixture of a monomer and a substrate comprising ferromagnetic material located in a polymeric matrix so as to polymerize the monomer in a manner that it forms a polymeric shell grafted on to and surrounding the substrate, the polymerization of the monomer being initiated by adding the components of a redox system sequentially to the reaction mixture.

Abstract translation: 制备共聚物的方法包括处理包含位于聚合物基质中的铁磁性材料的单体和底物的反应混合物，以使聚合单体以使其形成接枝到基底上并围绕基底的聚合物壳的方式聚合， 通过将氧化还原系统的组分依次加入到反应混合物中来引发单体。

公开(公告)号：US4167481A

公开(公告)日：1979-09-11

申请号：US818060

申请日：1977-07-22

Applicant: Adrien E. J. Cremers ,  Andre P. A. Maes ,  Paul G. L. Piegneur

Inventor： Adrien E. J. Cremers ,  Andre P. A. Maes ,  Paul G. L. Piegneur

IPC: B01J39/02 ,  B01J47/00 ,  C02F1/28 ,  B01D15/04 ,  C02B1/16 ,  C02C5/02

CPC classification number: B01J47/006 ,  B01J39/02 ,  C02F1/281 ,  C02F1/288 ,  Y10S210/912 ,  Y10S210/914

Abstract: Several metal ions, such as mercury, cadmium, copper, zinc, nickel and cobalt, may be removed from waste waters and similar solutions by treating such solutions with a cation exchanger in the presence of a polyamine. A treatment with clay minerals such as bentonite or montmorillonite in the presence of tetraethylenepentamine is preferred. The solution may be first combined with polyamine and then contacted with the cation exchanger, but in a preferred embodiment, the polyamine and cation exchanger are combined first to form a solid adsorbent and then contacted with the solution.

Abstract translation: 通过在多胺的存在下用阳离子交换剂处理这些溶液，可以从废水和类似溶液中除去几种金属离子，如汞，镉，铜，锌，镍和钴。 优选在四亚乙基五胺的存在下用粘土矿物如膨润土或蒙脱石处理。 该溶液可以首先与多胺结合，然后与阳离子交换剂接触，但在优选的实施方案中，首先将多胺和阳离子交换剂混合以形成固体吸附剂，然后与溶液接触。

公开(公告)号：US4116857A

公开(公告)日：1978-09-26

申请号：US812542

申请日：1977-07-05

Applicant: John M. Lee ,  William C. Bauman

Inventor： John M. Lee ,  William C. Bauman

IPC: B01D15/04 ,  B01J41/08 ,  B01J47/00 ,  C01F7/00

CPC classification number: B01J47/006 ,  B01J41/08 ,  C01F7/002

Abstract: Magnesium values are selectively recovered from salt brines, even salt brines which contain competing ions such as Li.sup.+, Ca.sup.++, and Sr.sup.++, by contacting the brine with an anion exchange resin which has dispersed therein a microcrystalline structure of the formula MgX.sub.2.2Al(OH).sub.3, where X is a halide.

Abstract translation: 通过使盐水与分散有式MgX2.2Al（OH）的微晶结构的阴离子交换树脂接触，从盐盐水，甚至含有竞争离子的盐盐，即Li +，Ca ++和Sr ++的盐水中选择性地回收镁值， 3，其中X是卤化物。

公开(公告)号：US4101460A

公开(公告)日：1978-07-18

申请号：US593345

申请日：1975-07-07

Applicant: Hamish Small ,  Timothy S. Stevens

Inventor： Hamish Small ,  Timothy S. Stevens

IPC: B08B3/12 ,  B01D15/04 ,  B01D15/36 ,  B01J20/281 ,  B01J20/285 ,  B01J39/16 ,  B01J41/08 ,  B01J47/00 ,  C08J7/04 ,  G01N30/88 ,  C08J5/20

CPC classification number: B01D15/361 ,  B01J20/3221 ,  B01J47/006 ,  C08J7/04

Abstract: An ion exchange composition comprising an insoluble substrate of a synthetic resin having ion exchanging sites at least on its available surface; and a finely divided, insoluble material comprising synthetic resin particles of from about 0.1 to about 5 microns median diameter (with respect to volume) having, at least on their outer surfaces, ion exchanging sites which attract the ion exchanging sites of the substrate, irreversibly attached as a monolayer to the available surface of the substrate. The composition is used for removal and separation of ions, and is especially useful in liquid ion exchange chromatography. For example, a chromatographic separation of halide ions is effected with high speed and resolution by contacting an aqueous solution thereof with a bed of the ion exchange composition which consists of surface sulfonated resin beads of a styrene-divinylbenzene copolymer to the surface of which is irreversibly attached a monolayer of quaternary ammonium-bearing styrene-divinylbenzene copolymer resin particles in the hydroxy form, and then eluting the bed with an aqueous sodium hydroxide solution.

Abstract translation: 一种离子交换组合物，其包含至少在其可用表面上具有离子交换位点的合成树脂的不溶性底物; 和细碎的不溶性材料，其包含约0.1至约5微米中等直径（相对于体积）的合成树脂颗粒，其至少在其外表面上具有吸引衬底的离子交换位点的离子交换位点，不可逆地 作为单层附着到基材的可用表面。 该组合物用于离子的去除和分离，并且在液体离子交换色谱中特别有用。 例如，通过使其水溶液与由苯乙烯 - 二乙烯基苯共聚物的表面磺化树脂珠组成的离子交换组合物的床接触，使其卤化物离子的色谱分离以高速和分辨率进行，其表面不可逆地 将含有羟基的季铵含量苯乙烯 - 二乙烯基苯共聚物树脂颗粒单层，然后用氢氧化钠水溶液洗脱床。

公开(公告)号：US09011693B2

公开(公告)日：2015-04-21

申请号：US11721428

申请日：2005-12-15

Applicant: Gregory Mark Vero ,  Anthony Price ,  Colin Bruce Ritchie

Inventor： Gregory Mark Vero ,  Anthony Price ,  Colin Bruce Ritchie

IPC: B03C1/02 ,  B03C1/30 ,  C02F1/42 ,  C02F1/48 ,  B01J47/00 ,  B01J20/28 ,  B01J47/10 ,  B01J49/00 ,  B03C1/28

CPC classification number: B01J47/006 ,  B01J20/28009 ,  B01J47/016 ,  B01J47/10 ,  B01J49/00 ,  B03C1/286 ,  C02F1/42 ,  C02F1/488

Abstract: The invention provides a process for separating a solution from magnetic resin portions, particles and/or fines by passing a solution containing the resin portions, particles and/or fines through a bed of particulate magnetic material.

Abstract translation: 本发明提供了一种通过使包含树脂部分，颗粒和/或细粒的溶液通过颗粒状磁性材料床而将溶液与磁性树脂部分，颗粒和/或细粒分离的方法。

公开(公告)号：US5472616A

公开(公告)日：1995-12-05

申请号：US143489

申请日：1993-10-27

Applicant: Charles R. Szmanda ,  Richard J. Carey

Inventor： Charles R. Szmanda ,  Richard J. Carey

IPC: B01J41/04 ,  B01J47/00 ,  B01J41/08

CPC classification number: B01J41/046 ,  B01J47/006

Abstract: The invention is for a process of removing anions from an organic solution, especially one having base labile components. The process comprises modifying an anion exchange resin by treatment with a solution of a source of anions less basic than the hydroxyl anion and contacting said modified ion exchange resin with an organic solution containing anions. The process is especially useful for treating photoresist compositions.

Abstract translation: 本发明涉及从有机溶液中除去阴离子的方法，特别是具有碱不稳定组分的阴离子。 该方法包括通过用比羟基阴离子碱性低的阴离子溶液处理并使所述改性离子交换树脂与含有阴离子的有机溶液接触来改性阴离子交换树脂。 该方法对于处理光致抗蚀剂组合物特别有用。

公开(公告)号：US5294652A

公开(公告)日：1994-03-15

申请号：US19287

申请日：1993-02-18

Applicant: Norman B. Rainer

Inventor： Norman B. Rainer

IPC: B01J41/08 ,  B01J45/00 ,  B01J47/00 ,  C08L11/00 ,  B01D15/00 ,  C08C69/26 ,  C08J5/20

CPC classification number: B01J47/007 ,  B01J41/085 ,  B01J45/00 ,  B01J47/006

Abstract: A process for absorbing silver from photographic hypo solutions involves passing the hypo solution through a bed consisting of a multitude of a sponge product confined within a vessel. The sponge product is derived from an open-celled cellulosic sponge into which there has been incorporated 30% to 80% by weight of a polymer produced by the thermal interaction of polyethyleneimine (PEI) with a polycarboxylic acid. The polymer further contains an activating multivalent cation and between 90% and 300% water. Silver is eluted from the sponge product employing aqueous solutions of a complexing agent such as an ammonium compound or a cyanide compound. Following a water wash, the bed of sponge product is ready for its next cycle of silver absorption.

Abstract translation: 从照相底层溶液中吸收银的方法包括使次溶液通过由限制在容器内的大量海绵产品组成的床。 海绵产品来源于开孔的纤维素海绵，其中掺入30％至80％重量的通过聚乙烯亚胺（PEI）与多元羧酸的热相互作用产生的聚合物。 聚合物还含有活化多价阳离子和90％至300％的水。 使用络合剂如铵化合物或氰化物化合物的水溶液，从海绵产品中洗脱银。 水洗后，海绵产品床准备下一次银吸收循环。

公开(公告)号：US4973607A

公开(公告)日：1990-11-27

申请号：US248529

申请日：1988-09-23

Applicant: James R. Stahlbush ,  Robert M. Strom

Inventor： James R. Stahlbush ,  Robert M. Strom

IPC: C08J5/20 ,  B01J39/20 ,  B01J47/00 ,  C08K5/10 ,  C08K5/13 ,  C08L25/00

CPC classification number: B01J47/006

Abstract: Cation exchange resins with improved stability prepared by treating the resins with an antioxidant are disclosed.

Abstract translation: 公开了通过用抗氧化剂处理树脂制备的具有改进的稳定性的阳离子交换树脂。 抗氧化剂的实例是2，b-二叔丁基-4-甲基苯酚和2，b-二叔丁基-α-二甲基氨基 - 对甲酚。 本发明的阳离子交换树脂可用于水处理，食品和药品的纯化，催化等。

公开(公告)号：US4927539A

公开(公告)日：1990-05-22

申请号：US262074

申请日：1988-10-24

Applicant: Timothy S. Stevens ,  Martin A. Langhorst ,  Osro W. Randall, III

Inventor： Timothy S. Stevens ,  Martin A. Langhorst ,  Osro W. Randall, III

IPC: B01D15/04 ,  B01D15/36 ,  B01J41/20 ,  B01J47/00

CPC classification number: B01D15/363 ,  B01J20/3221 ,  B01J41/20 ,  B01J47/006 ,  B01J2220/54

Abstract: An anion-exchange chromatographic packing composition which comprises:a substrate which consists essentially of particles having cation-exchanging sites at least on their available surfaces, the particles being of a diameter of between about 1 to about 75 microns; anda liquid coating which consists essentially of a hydrophilic, water soluble, film forming resin having anion-exchanging sites which attract available cation-exchanging sites of the substrate, wherein the liquid coating is retained by electrostatic bonds on the available surfaces of the substrate particles. The invention further includes a chromatographic column and process using the described packing composition.

Abstract translation: 阴离子交换色谱填料组合物，其包含：基本上由至少在其可用表面上具有阳离子交换位点的颗粒组成的颗粒，所述颗粒直径在约1至约75微米之间; 以及液体涂层，其基本上由亲水的，水溶性的成膜树脂组成，其具有阴离子交换位点，其吸引基材的可用的阳离子交换位点，其中液体涂层由基材颗粒的可用表面上的静电键保持 。 本发明还包括色谱柱和使用所述包装组合物的方法。

公开(公告)号：US4505888A

公开(公告)日：1985-03-19

申请号：US498867

申请日：1983-05-27

Applicant: Herbert Moore ,  Stephen Santos ,  Robert D. Wysong

Inventor： Herbert Moore ,  Stephen Santos ,  Robert D. Wysong

IPC: A61K51/12 ,  B01J47/00 ,  A61K43/00 ,  A61K49/00

CPC classification number: A61K51/1282 ,  A61K51/1251 ,  B01J47/006 ,  A61K2123/00

Abstract: An improved tracer particle is described comprising an ion exchange core having a polymer coating thereon, the coated ion exchange core having a reaction site capable of reacting with a compound containing an oxirane group, said coated ion exchange core having been treated with a compound containing an oxirane group to react with said coated ion exchange core causing an increase in mass of the tracer particle. Preferably, the ion exchange core is labelled with a radionuclide. These particles have improved characteristics including improved stability against leaching and improved handling properties. Such particles are useful in circulatory determinations involving the injection of the particles as a suspension in a physiologically acceptable carrier or medium into the circulatory system of animals.

Abstract translation: 描述了一种改进的示踪剂颗粒，其包含其上具有聚合物涂层的离子交换核心，所述涂覆的离子交换核心具有能够与含有环氧乙烷基团的化合物反应的反应位点，所述涂覆的离子交换核心已经用含有 环氧乙烷基团与所述涂覆的离子交换核心反应，导致示踪剂颗粒的质量增加。 优选地，离子交换核心用放射性核素标记。 这些颗粒具有改进的特性，包括提高对浸出的稳定性和改进的处理性能。 这种颗粒可用于循环测定，包括将颗粒作为悬浮液注入生理学上可接受的载体或介质进入动物的循环系统。