Silica glass containing TiO2 and process for its production
    23.
    发明授权
    Silica glass containing TiO2 and process for its production 有权
    含二氧化硅的硅玻璃及其生产工艺

    公开(公告)号:US07538052B2

    公开(公告)日:2009-05-26

    申请号:US11957855

    申请日:2007-12-17

    Abstract: A silica glass containing TiO2, which has a fictive temperature of at most 1,200° C., a F concentration of at least 100 ppm and a coefficient of thermal expansion of 0±200 ppb/° C. from 0 to 100° C.A process for producing a silica glass containing TiO2, which comprises a step of forming a porous glass body on a target quartz glass particles obtained by flame hydrolysis of glass-forming materials, a step of obtaining a fluorine-containing porous glass body, a step of obtaining a fluorine-containing vitrified glass body, a step of obtaining a fluorine-containing formed glass body and a step of carrying out annealing treatment.

    Abstract translation: 含有TiO 2的二氧化硅玻璃,其假想温度为至多1200℃,F浓度为至少100ppm,热膨胀系数为0±200ppb /℃,为0〜100℃。 含有TiO 2的二氧化硅玻璃的制造方法,其包括在通过玻璃形成材料的火焰水解得到的目标石英玻璃粒子上形成多孔玻璃体的工序,得到含氟多孔玻璃体的工序, 获得含氟玻璃化玻璃体,获得含氟成形玻璃体的步骤和进行退火处理的步骤。

    FUSED SILICA ARTICLE LOADED WITH DEUTERIUM AND METHOD OF MAKING
    25.
    发明申请
    FUSED SILICA ARTICLE LOADED WITH DEUTERIUM AND METHOD OF MAKING 审中-公开
    熔融二氧化硅装置与脱色剂和制备方法

    公开(公告)号:US20090056381A1

    公开(公告)日:2009-03-05

    申请号:US12139853

    申请日:2008-06-16

    Abstract: A method of making a fused silica article having a combined concentration of protium and deuterium in a range from about 1×1016 molecules/cm3 up to about 6×1019 molecules/cm3. In some embodiments, deuterium is present in an amount greater than its natural isotopic abundance. The method includes the steps of providing a fused silica boule, diffusing at least one of protium and deuterium into the boule, and annealing the boule to form the fused silica article. A method of diffusing hydrogen into fused silica and a fused silica article loaded with hydrogen formed by the method are also described.

    Abstract translation: 制备具有约1×10 16分子/ cm 3至多约6×1019分子/ cm 3范围内的ium和氘的组合浓度的熔融二氧化硅制品的方法。 在一些实施方案中,氘的存在量大于其天然同位素丰度。 该方法包括以下步骤:提供熔融二氧化硅焦耳,将钚和氘中的至少一种扩散到该原子核中,以及对该坯进行退火以形成熔融二氧化硅制品。 还描述了将氢扩散到熔融二氧化硅中的方法和通过该方法形成的负载有氢的熔融二氧化硅制品。

    Method for producing an optical component of synthetic quartz glass with enhanced radiation resistance, and blank for producing the component
    26.
    发明申请
    Method for producing an optical component of synthetic quartz glass with enhanced radiation resistance, and blank for producing the component 有权
    用于制造具有增强的耐辐射性的合成石英玻璃的光学部件的制造方法和用于制造该部件的坯料

    公开(公告)号:US20090004088A1

    公开(公告)日:2009-01-01

    申请号:US12148338

    申请日:2008-04-18

    Abstract: To optimize an optical component of synthetic quartz glass, in the case of which a quartz glass blank is subjected to a multistage annealing treatment, with respect to compaction and central birefringence, the present invention suggests a method comprising the following steps: (a) a first treatment phase during which the quartz glass blank is treated in an upper temperature range between 1130° C. and 1240° C., (b) cooling the quartz glass blank at a first-higher-mean cooling rate to a quenching temperature below 1100° C., a fictive temperature with a high mean value of 1100° C. or more being reached in the quartz glass, (c) a second treatment phase which comprises cooling of the quartz glass blank at a second-lower-mean cooling rate, and in which the quartz glass blank is treated in a lower temperature range between 950° C. and 1100° C. such that a fictive temperature is reached in the quartz glass with a low mean value which is at least 50° C. lower than the high mean value of the fictive temperature according to method step (b).

    Abstract translation: 为了优化合成石英玻璃的光学部件,在石英玻璃坯料进行多段退火处理的情况下,关于压实和中心双折射,本发明提出了一种方法,包括以下步骤:(a) 第一处理阶段,其中在1130℃和1240℃之间的较高温度范围内处理石英玻璃坯料,(b)以第一高平均冷却速率将石英玻璃坯料冷却至低于1100℃的淬火温度 在石英玻璃中达到1100℃或更高平均值的假想温度,(c)第二处理阶段,其包括以第二低平均冷却速度冷却石英玻璃坯料 ,其中在950℃至1100℃的较低温度范围内处理石英玻璃坯料,使得石英玻璃中具有低至少50℃的低平均值的假想温度降低 比平均值高 根据方法步骤(b)的假想温度。

    Silica glass containing TiO2 and process for its production
    28.
    发明授权
    Silica glass containing TiO2 and process for its production 有权
    含二氧化硅的硅玻璃及其生产工艺

    公开(公告)号:US07419924B2

    公开(公告)日:2008-09-02

    申请号:US11589875

    申请日:2006-10-31

    Abstract: It is to provide a silica glass containing TiO2, having a wide temperature range wherein the coefficient of thermal expansion is substantially zero.A silica glass containing TiO2, which has a TiO2 concentration of from 3 to 10 mass %, a OH group concentration of at most 600 mass ppm and a Ti3+ concentration of at most 70 mass ppm, characterized by having a fictive temperature of at most 1,200° C., a coefficient of thermal expansion from 0 to 100° C. of 0±150 ppb/° C., and an internal transmittance T400-700 per 1 mm thickness in a wavelength range of from 400 to 700 nm of at least 80%. A process for producing a silica glass containing TiO2, which comprises porous glass body formation step, F-doping step, oxygen treatment step, densification step and vitrification step.

    Abstract translation: 提供含有TiO 2的二氧化硅玻璃,其具有宽的温度范围,其中热膨胀系数基本上为零。 含有TiO 2浓度为3〜10质量%,OH基浓度为600质量ppm以下且Ti 3 +浓度为70质量ppm以下,其特征在于具有至多1200℃的假想温度,0〜100℃的热膨胀系数为0±150ppb /℃。 并且在400至700nm的波长范围内每1mm厚度的内部透射率T 400-700 至少为80%。 一种制备含有TiO 2的二氧化硅玻璃的方法,其包括多孔玻璃体形成步骤,F掺杂步骤,氧处理步骤,致密化步骤和玻璃化步骤。

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