Abstract:
A fuel feed system for use in a gasification system includes a feed preparation section, a pressurization and conveyance section, and a slag additive section. The feed preparation section is configured to grind the fuel to a predetermined size and to adjust the moisture content within the particulate fuel. The pressurization and conveyance section is coupled in flow communication with the feed preparation section, and includes at least one solids pump configured to receive a flow of the particulate fuel at a first pressure and discharge the particulate fuel at a second pressure. The slag additive section is configured to feed a slag additive mixture into the gasifier and to substantially control the total water content within the gasification system.
Abstract:
A process for upgrading plastic material containing inorganic filler or reinforcement material for use as feedstock in a partial oxidation gas generator for the production of raw synthesis gas, fuel gas or reducing gas. The plastic material is granulated and partially liquefied by heating in a closed autoclave at a temperature in the range of about 400.degree. F. to 495.degree. F. and a pressure in the range of about 150 psig to 750 psig while the plastic material is in contact with a pumpable hydrocarbonaceous liquid solvent. A pumpable slurry is thereby produced comprising solubilized plastic, unsolubilized plastic, hydrocarbonaceous liquid solvent, separated inorganic material and unseparated inorganic material. After removing the separated inorganic material, the remainder of the slurry is then reacted by partial oxidation to produce said raw synthesis gas, fuel gas or reducing gas.
Abstract:
A process for disposing of sewage sludge comprising the steps of, (1) dewatering the sewage sludge to produce an aqueous slurry of sewage sludge having a solids content of about 10 to 30 wt. %; (2) simultaneously heating and shearing said dewatered sewage sludge at about 150.degree. F. to 210.degree. F. in the absence of air for 0.5 seconds to 60 minutes while being continuously passed through a tubular-shaped processing means containing a plurality of rotating agitators, thereby producing a pumpable slurry having a viscosity of less than about 2000 centipoise; (3) dewatering the sewage sludge if necessary; (4) mixing at a temperature in the range of about ambient to 180.degree. F. in a ribbon or in-line static mixer the slurry of sewage sludge from (2) and/or (3) with a supplemental solid carbonaceous fuel e.g. coal and/or petroleum-coke to produce a pumpable aqueous slurry of sewage sludge and supplemental fuel having a solids content in the range of about 50 to 60 wt. %; (5) mixing the slurry of sewage sludge and supplemental fuel from (4) in a steam jacketed continuous rotary disc mixer at about 180.degree. F. to 250.degree. F. while removing steam to produce a pumpable slurry of dewatered sewage sludge and solid fuel having a solids content of 50 to 65 wt. % and a HHV of 6,000 to 18,000 BTU/LB; and (6) burning said pumpable slurry from (5) in a partial oxidation gasifier, furnace, boiler, or incinerator to produce an effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated. By this process, noxious sewage sludge may be disposed of without contaminating the environment. By-product synthesis gas, reducing gas, or fuel gas may be produced.
Abstract:
A method of preventing the adherence of the ash to a gasifier wall in a process for gasifying petroleum coke in the gasifier by partial oxidization reaction. The petroleum coke is mixed with 10 to 30 wt % of coal based on the petroleum coke and the mixture is gasified at a gasifying temperature higher than the melting point of the ash of said coal.
Abstract:
A two-stage upflow process for coal gasification and an apparatus useful therefor. An oxygen-containing gas and a first increment of a coal-in-water slurry are ignited in a horizontal fired slagging reactor by means of horizontal coaxial juxtaposed burner nozzles mounted in the reactor, thereby converting the oxygen, the coal, and the water into steam and gaseous combustion products. The discharge from the fired reactor is contacted overhead with a second increment of coal-water slurry in a vertical unfired heat-recovery unit connected to the upper end of the reactor. The heat evolved in the reactor is used in the heat recovery unit to convert the second increment of coal-water slurry into more steam, char and synthesis gas. The gas effluent is separated from the solid char, and synthesis gas is passed into a fire-tube boiler to recover heat and the cooled product gas is recovered as the desired fuel-rich product. The solid char is reslurried and recycled to the fired reactor 3 for further combustion.
Abstract:
Disclosed is a burner for the partial combustion of a solid carbonaceous fuel wherein coal, e.g., finely divided coal, is supplied to a reactor space via a central channel disposed along the longitudinal axis of the burner, and oxygen-containing gas is supplied via two annular channels surrounding said central channel, and heat from the combustion is removed from the hollow front face of the burner by coolant flowed through said front face spirally about the longitudinal axis of the burner.
Abstract:
An improved burner nozzle and process for making a synthetic or fuel gas mixture containing hydrogen and carbon monoxide by the partial oxidation, in a free-flowing hollow reactor, of a slurry of solid carbonaceous fuel in a liquid carrier admixed with a gas containing free oxygen. The nozzle may also be used in other applications where nozzles are required to handle slurries having a high concentration of finely-divided solids that must be uniformly admixed with a gas, as for example, in the aeration or incineration processes of a waste disposal plant. The nozzle and process include enveloping of an annular slurry stream between a central layer and an annular layer of high velocity gas, impinging the annular slurry stream on a downstream nozzle diffuser where a zone of high shear forces produce a uniform atomized admixture of solids, liquids and gases, and then transporting the admixture through an exit orifice at an accelerated velocity to further atomize the admixture.
Abstract:
An ash fusion temperature reducing agent principally comprising at least 50.0 wt. % of a manganese compound, such as MnO, and the remainder of the agent comprising a silicon compound, such as SiO.sub.2 is mixed with an ash-containing fuel comprising a pumpable liquid hydrocarbonaceous material and/or petroleum coke to produce Mixture A. In one embodiment, the ash fusion temperature reducing agent comprises a comminuted pyrolusite ore in which the following elements are present in weight percent basis ore: manganese in the range of about 50-75, calcium in the range of about 0-1.0, silicon in the range of about 0-3.0, magnesium in the range of about 0-1.0, and aluminum in the range of about 0-1.0. Mixture A is reacted with a free-oxygen containing gas in a free-flow refractory lined reaction zone of a partial oxidation gas generator. A hot raw effluent gas stream comprising H.sub.2 +CO along with molten ash having a reduced initial deformation temperature are produced at a lower temperature. Alternatively, Mixture A may be first introduced into a coking zone and converted into petroleum coke in which the ash fusion temperature reducing agent is dispersed throughout. The petroleum coke entrained in a liquid or gaseous carrier is then introduced into the partial oxidation gas generator where a hot raw effluent gas stream comprising H.sub.2 +CO is produced along with molten ash having a reduced ash fusion temperature. The molten ash is readily separated from the effluent gas stream; and, the gas generator may be operated at a lower temperature thereby extending the life of the refractory lined reaction zone.
Abstract:
An ash fusion temperature reducing agent comprising a comminuted ore mixture of the silicates of iron, calcium, magnesium and aluminum is mixed with an ash containing pumpable liquid hydrocarbonaceous material to produce Mixture A. Mixture A is reacted with a free-oxygen containing gas in a partial oxidation gas generator. A hot raw effluent gas stream comprising H.sub.2 +CO along with molten ash having a reduced ash fusion temperature are produced at a lower temperature. Alternatively, Mixture A may be first introduced into a coking zone and converted into petroleum coke in which the ash fusion temperature reducing agent is dispersed throughout. The petroleum coke is then introduced into the partial oxidation gas generator where the hot raw effluent gas stream comprising H.sub.2 +CO is produced along with molten petroleum coke ash having a reduced ash fusion temperature. The molten ash is readily separated from the effluent gas stream and the gas generator may be operated at a lower temperature thereby extending the life of the refractory lined reaction zone.
Abstract:
Coal gasification apparatus wherein a combustible mixture is formed and burned, comprising a combustion supporting gas such as oxygen, and a coal slurry. The hot products of combustion which issue from the burner, are directed into the reaction chamber of a synthesis gas generator. To avoid deposition of slag and ash particles along the hot, exposed face of the burner, a dynamic fluid blanket or barrier is directed transversely of the burner face. The reaction chamber includes an elongated port in which the burner is registered. To shield the burner, a manifold depends from the reaction chamber wall adjacent to the burner face and projects a stream of coolant fluid transversely of the face.