METHOD FOR PRODUCING NITROUS ACID ESTER, AND METHOD FOR PRODUCING DIALKYL OXALATE AND DIALKYL CARBONATE
    25.
    发明申请
    METHOD FOR PRODUCING NITROUS ACID ESTER, AND METHOD FOR PRODUCING DIALKYL OXALATE AND DIALKYL CARBONATE 有权
    生产硝酸酯的方法,以及生产二烷基氧化铝和碳酸二乙酯的方法

    公开(公告)号:US20150065742A1

    公开(公告)日:2015-03-05

    申请号:US14389583

    申请日:2013-02-27

    Abstract: A method for producing nitrous acid ester in which nitric oxide, oxygen, and an alcohol are reacted, thereby generating nitrous acid ester includes a step of generating nitrous acid ester by supplying a bottom liquid from a bottom part of the reaction column, and nitric oxide and/or carbon monoxide, a step of supplying nitrous acid ester to the reaction column; a step of supplying a reaction liquid containing water, nitric acid, and the alcohol to a nitric acid condensing column from the reactor; and a step of separating a low-boiling point component by distillation from the reaction liquid under control of a concentration of the alcohol in a condensed liquid being generated at a bottom part of the nitric acid condensing column to be less than 4.0% by weight so as to introduce the condensed liquid into the reactor from the nitric acid condensing column.

    Abstract translation: 一氧化氮,氧和醇反应生成亚硝酸酯的方法,从而产生亚硝酸酯包括通过从反应塔的底部供应底部液体和一氧化氮产生亚硝酸酯的步骤 和/或一氧化碳,向反应塔供应亚硝酸酯的步骤; 将含有水,硝酸和醇的反应液体从反应器供给到硝酸冷凝塔的步骤; 在硝酸浓缩塔的底部产生的冷凝液中,醇的浓度控制下,通过蒸馏将反应液中的低沸点成分分离成低于4.0重量%的步骤,从而 将浓缩的液体从硝酸冷凝塔引入反应器。

    Nitration of organic compounds and organic nitrogen compounds produced
    27.
    发明授权
    Nitration of organic compounds and organic nitrogen compounds produced 失效
    生成有机化合物和有机氮化合物的硝化

    公开(公告)号:US4496783A

    公开(公告)日:1985-01-29

    申请号:US489467

    申请日:1983-04-28

    CPC classification number: C07C201/08 C07C201/02 C07C201/04

    Abstract: Nitration of organic compounds and organic nitrogen compounds produced.Organic nitrogen compounds are formed in the vapor phase by organic radical formation by reaction of an organic compound with hydroxyl radicals derived from the reaction between hydrogen peroxide and nitrogen dioxide and the nitration of the organic radicals, suitably with nitrogen dioxide. The process may be conducted as a single stage process using an excess of nitrogen dioxide over that required for hydroxyl radical formation. The production of hydroxyl radicals is maximized by the use of a catalytic solid surface such as a solid acid or an acidic oxide or mixed oxide. The product may be a mixture of some or all of the nitrite, nitrate and nitro-derivative which may be used as such, e.g. as a fuel additive, as a source of the individual compounds or as a feedstock for a further synthesis.

    Abstract translation: 生成有机化合物和有机氮化合物的硝化。 通过有机化合物与过氧化氢和二氧化氮之间的反应衍生的羟基自由基反应形成有机氮化合物,并适当地用二氧化氮硝化有机氮化合物。 该方法可以作为使用过量二氧化氮超过羟基自由基形成所需的二氧化氮的单阶段方法进行。 通过使用催化固体表面如固体酸或酸性氧化物或混合氧化物,使羟基自由基的产生最大化。 产物可以是一些或全部亚硝酸根,硝酸根和硝基衍生物的混合物,可以如此使用。 作为燃料添加剂,作为单独化合物的来源或作为进一步合成的原料。

Patent Agency Ranking