Abstract:
A water treatment system is disclosed having electrolytic cell for liberating hydrogen from a base solution. The base solution may be a solution of brine for generating sodium hypochlorite, or potable water to be oxidized. The cell has first and second opposing electrode endplates held apart from each other by a pair of supports such that the supports enclose opposing sides of the endplates to form a cell chamber. One or more inner electrode plates are spaced apart from each other in the cell chamber in between the first and second electrode plates. The supports are configured to electrically isolate the first and second electrode plates and the inner electrode plates from each other. The first and second electrode plates are configured to receive opposite polarity charges that passively charge the inner electrode plates via conduction from the base solution to form a chemical reaction in the base solution as the base solution passes through the cell chamber.
Abstract:
An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The batter further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes. As the electrolyte enters the battery of ells, t flows through a continuous open serpentine channel defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cells, ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. As the electrodes of each cell of the battery are saturated with the removed ions, the battery is regenerated electrically at a reversed polarity from that during the deionization step of the cycle, thus significantly minimizing secondary wastes.
Abstract:
An apparatus for water treatment by means of an electrical field is provided with an anode and a cathode in at least one treatment chamber through which the water to be treated passes. The apparatus is characterized in that the at least one treatment chamber forms a prismatic space with an elongated cross section, the anode and the cathode are formed by pairs of parallel, stick-shaped electrodes which extend spaced apart into said space and a voltage is applicable between the electrodes. One end of the at least one treatment chamber is connected to a water inlet and the other end of the at least one treatment chamber is connected to a water outlet, whereby a waterflow from one electrode to the other is generatable which is substantially transverse to the longitudinal axes of the electrodes.
Abstract:
An electrolysis cell comprises a housing receiving a plurality of parallel electrodes separated by guides to define a plurality of passageways through which an electrolyte solution is flowed from an inlet end to an outlet end, the solution being subjected to electrolysis by applying an electrical potential between electrodes. At the inlet and outlet ends, spaced wall means engage with the electrodes to extend the electrolyte passageways and confine electrolyte to the respective passageways whereby a short circuit through the electrolyte between electrodes is avoided.
Abstract:
Improvements in product water throughput from a reverse osmosis (RO) membrane achieved by thinner feed spacers in the RO element (22), enhanced recovery (ratio of permeate to feed), pressure recovery of the retentate fluid pressure opposing the feed water pressure, and fluid pulsing of the RO element feed stream. These features are preferably combined to optimize the performance and cost per unit volume of water produced. The system of the invention preferably comprises a dual head reciprocating pump (20), an RO element (22) with a housing, and a differential pressure activated (nullDPAnull) valve (24). The DPA valve (24), in combination with offsetting fluid pressures on the two pump heads (28, 30), generate energy recovery. The frequency and amplitude of the reciprocating pump (20) create a pulse wave in the RO element (22) that improves permeate quality and throughput. A control system preferably monitors system parameters to optimize the reciprocating pump (20) speed and amplitude to tune the optimal frequency and amplitude required for maximum throughput and permeate quality from any given RO element (22) configuration.
Abstract:
An apparatus for generating ozone, oxygen, hydrogen, and/or other products of water electrolysis, having an electrolyte cell that can be acted upon by water. The water is delivered and carried away in a supply line communicating with the electrolyte cell, wherein a bypass line is embodied around the supply line. The electrolyte cell can be connected via the bypass line to the supply line and subjected to water from the supply line. A valve engaging the supply line and the bypass line is provided, and with the valve, the supply line and the bypass line can be opened and/or closed.
Abstract:
A method and apparatus for contaminant separation utilizes an interleaved array of oppositely charged electrode plates for fluid treatment. Spacing between the parallel electrode plates is graduated so that the volume of the cavities between the opposing electrodes provides varying levels of treatment of a broad range of contaminants from a variety of fluid columns. A fluid flow path extending substantially orthogonal to the direction of the electrical field established between opposing electrode plates provides a feed stream with exposure to the varying levels of electrical charges between the electrode plates. The method and apparatus provides an effective means of contaminant separation by a device having a small footprint and requiring low amounts of electrical energy.
Abstract:
An apparatus for continuously electrolyzing waste liquid has a series (10) of tanks comprising a plurality of electrolytic tanks each having an anode (22) and a cathode (23), the electrolytic tanks being connected in series, vibrating flow generating means (16) which is equipped to each of the electrolytic tanks and generates vibrating flow in waste liquid (14) to be treated, and a power supply circuit (34) for applying a voltage between the anode (22) and the cathode (23). The vibrating flow generating means (16) has a vibration motor (16d), vibration transmitting rods (16e) which are operationally connected to the vibration motor (16d) so as to vibrate in the waste liquid (14) to be treated; and vibrating vanes (16f) fixed to the vibration transmitting rods (16e). The distance between the anode (22) and the cathode (23) is equal to 5 to 50 mm. Vibrating stress dispersing means is interposed between the vibration motor (16d) and the vibration transmitting rods (16e) and/or between the vibration transmitting rods (16e) and the vibrating vanes (16f). The vibration motor (16d) is commonly used by plural vibrating flow generating means. Plural electrolytic tanks constituting the series (10) of tanks are unified, and the electrolytic tanks thus unified are partitioned by partition walls (11).
Abstract:
Deionizers using the electrode configurations of electrochemical capacitors are described, wherein the deionizing process is called capacitive deionization (CDI). During deionization, a DC electric field is applied to the cells and ions are adsorbed on the electrodes with a potential being developed across the electrodes. As electrosorption reaches a maximum or the cell voltage is built up to the applied voltage, the CDI electrodes are regenerated quickly and quantitatively by energy discharge to storage devices such as supercapacitors. In conjunction with a carousel or Ferris wheel design, the CDI electrodes can simultaneously and continuously undergo deionization and regeneration. By the responsive regeneration, the CDI electrodes can perform direct purification on solutions with salt content higher than seawater. More importantly, electrodes are restored, energy is recovered and contaminants are retained at regeneration, while regeneration requires no chemicals and produces no pollution.
Abstract:
A method of operating a reactor for removing impurities by electrochemical means from liquids, such as aqueous solutions. The liquid is passed through series of plateshaped reaction electrodes electrically insulated against each other with a liquid speed above a minimum to prevent dissociation into constituent gases, but sufficient to ensure interaction with an electrical current passing between the plateshaped electrodes. The latter has corrugated forms and/or their surfaces provided with embossed relief patterns to enhance the electrochemical effect between the electrodes. The conductivity of the treated liquid, the organic contents of the liquid and the flow of the liquid is measured and the length of the flow path for the liquid in the reactor is established in dependence on the measured parameters. Ultrasonic vibrations are generated in the flow path for stimulating a reaction process.