摘要:
A novel catalyst for catalytic reduction of nitrogen oxide using a hydrocarbon as a reducing agent is provided, which comprises (a) at least an element of the platinum group selected from the group consisting of platinum, iridium, rhodium and ruthenium and (b) gold, and which may further comprises (c) at least a metallic oxide selected from the group consisting of cerium oxide, lanthanum oxide, neodymium oxide, germanium oxide and gallium oxide.
摘要:
A composite dielectric is formed with a matrix synthetic resin and particulate porous, inorganic dielectric dispersed in the matrix synthetic resin. The dielectric constant of this composite dielectric can be thereby elevated effectively without enlarging the dissipation factor (tan .delta.) of the composite dielectric.
摘要:
A catalyst for ozone decomposition which comprises:(a) at least one selected from the group consisting of clay and carbon;(b) manganese dioxide; and optionally(c) titanium dioxide; and/or(d) at least one oxide of a metal selected from the group consisting of Cu, Co, Fe, Ni and Ag.A further catalyst for ozone decomposition which comprises:(a) at least one oxide of a metal selected from the group consisting of alkali metals and alkaline earth metals;(b) manganese dioxide; and optionally(c) titanium dioxide; and/or(d) at least one selected from the group consisting of clay and carbon.
摘要:
The present invention provides an exhaust gas treating method by which exhaust gas is passed through a catalyst layer at an areal velocity of 100 to 5000 m.sup.3 /m.sup.2 .multidot.hr to selectively produce carbon monoxide from particulates contained in the exhaust gas, so that nitrogen oxides contained in the exhaust gas are removed by the carbon monoxide thus produced. The exhaust gas treating method of the present invention can readily and securely remove particulates and nitrogen oxides contained in exhaust gas, i.e., two primary causes of air pollution, by merely passing the exhaust gas through a catalyst layer at a specific areal velocity.
摘要:
A process for producing microcrystalline barium ferrite platelets which comprises: forming an aqueous alkaline dispersion containing coprecipitates of hydroxides of barium ions, iron (III) ions, and optionally ions of a substituent element; heating the dispersion to a temperature of not less than 50.degree. C. and not more than the boiling point of the dispersion under an atmospheric pressure to convert the coprecipitates to precursors of the barium ferrite; calcining the precursors to provide microcrystalline barium ferrite platelets; the improvement comprising the step of adding a carbonating agent such as sodium carbonate to the aqueous alkaline dispersion before or after the heating of the aqueous dispersion to insolubilize water soluble barium ions therein, and the step of calcining the barium ferrite precursors in the presnece of sodium sulfate at temperatures of 700.degree.-900.degree. C., to provide microcrystalline barium ferrite platelets of about 0.03-0.1 .mu.m in average particle size and 2-5 in planarity ratio.
摘要:
A denitrizing catalyst which comprises:(a) an alkali metal oxide or an alkaline earth metal oxide in amounts of 50-90% by weight as oxides;(b) at least one metal oxide selected from the group consisting of Co.sub.3 O.sub.4, Cu.sub.2 O, Cr.sub.2 O.sub.3, Mn.sub.2 O.sub.3, NiO, PbO, Bi.sub.2 O.sub.3, MoO.sub.2, Al.sub.2 O.sub.3, SiO.sub.2, ZrO.sub.2, Fe.sub.2 O.sub.3, TiO.sub.2, WO.sub.3, MoO.sub.3, SnO.sub.2 and ZnO in amounts of 5-50% by weight as oxides; and(c) at least one metal or at least one oxide of metals selected from the group consisting of Ru, Rh, Pd, Ag, Pt and Au in amounts of 0.01-10% by weight as metals.Nitrogen oxides contained in waste gases are denitrized effectively by putting the gases into contact with the catalysts in the absence or presence of carbon monoxide as a reducing agent.
摘要:
There is provided a method of producing titanium-oxides which comprises: admixing an aqueous solution of titanium tetrachloride with sulfuric acid in amounts of at least 0.5 times is moles as the titanium tetrachloride; adding an alkali to the resultant solution to produce titanium hydroxide; and drying and calcining the titanium hydroxide. A further method is provided which comprises: adding a solution of an alkali to an aqueous solution of titanium tetrachloride having a concentration of not more than 2.5 moles/l at temperatures of not less than 50.degree. C., thereby to substantially thermally hydrolyze the titanium tetrachloride and to produce titanium hydroxide; and drying and calcining the titanium hydroxide.
摘要:
A catalyst for denitrizing nitrogen oxides contained in waste gas which contains a substantial amount of arsenic compounds therein, which comprises:(a) titanium, and(b) at least one element selected from the group consisting of arsenic and manganese. The catalyst is resistant to deactivation by arsenic compounds and retains high denitrizing activity over a long period of time. The catalyst may further contain at least one base metal selected from the group consisting of V, W, Mo, Cu, Fe, Cr, Co, Ni, Zn and Sn.
摘要:
A molded catalyst for fitting into a reactor vessel having an inlet and an outlet for a reactant gas, the catalyst having openings therethrough parallel to the direction of a reactant gas which is introduced into the reactor vessel from the inlet, the catalyst comprising: a wear-resistant front surface facing the inlet of the reactor vessel and a continuation of the front surface extending therefrom, the both being the front portion of the catalyst, and the remaining part of the catalyst made so wear-susceptible as to have either:(a) a wearability of 2-10% in a shaking abrasion test wherein grinding particles having an average particle size of 100 .mu.m and a Mohs scale of 9 are placed in the openings of the catalyst in an amount of 50% by volume based on the total volume of the openings, and the catalyst is shaked for three hours with an amplitude of 77 mm and a frequency of 320 per minute; or(b) a wearability of 7.5-35% in an air abrasion test wherein an air which contains silica particles having an average particle size of 40 .mu.m in amounts of 70 g/m.sup.3 is passed through in a reactor vessel including a rectangular parallelepipedic catalyst of 45 mm wide, 45 mm thich and 100 mm long so fitted thereinto that the catalyst extends longitudinally in the direction of the flow of the air for 30 min. at a superficial velocity of 40 m/sec. at the front face of the catalyst.
摘要:
A catalyst for denitrizing nitrogen oxides contained in waste gases, which comprises:(a) titanium, and(b) at least one base metal selected from the group consisting of V, W, Mo, Mn, Cu, Fe, Cr, Co, Ni, Zn and Sn, the catalyst containing titanium and the base metals in amounts of at least about 50% by weight in terms of oxides based on the catalyst, and titanium in amounts of about 80-99% by weight in terms of oxides and the base metals in amounts of about 20-1% by weight in terms of oxides, respectively, based on the total weight in terms of oxides of titanium and the base metals, and the catalyst having micropores of about 50-75000 .ANG. in radius in amounts of about 0.25-0.45 ml/g, and micropores of about 50-100 .ANG. in radius in amounts of about 10-40% by volume and micropores of about 500-60000 .ANG. in radius in amounts of not less than about 10% by volume, respectively, based on the total volume of the micropores of about 50-75000 .ANG. in radius, in the presence of a reducing gas at elevated temperatures.The catalyst retains a higher denitrizing activity over a long period time than the conventional catalysts, and is substantially free from deactivation with arsenic or arsenic compounds contained in waste gases.