Abstract:
In the fighting of fires or protection of objects from fire by applying thereto water, the improvement which comprises dispersing in the water particles of a cross-linked water-insoluble but hightly water-swellable acrylic acid derivative polymer in an amount insufficient to bring the viscosity above 100 mPa's. Advantageously, the particles are present in an amount such that after swelling the swollen particles hold 60 to 70% by weight of the total water, the particles are from 0.1 to 3 mm in diameter and are present in from 0.1 to 0.6% by weight of the water, the polymer being a copolymer of an acrylic acid, the water containing silicic acid and/or a silicate as well as sodium, potassium or ammonium ions. The water is freely pumpable but the swollen particles adhere to surfaces they contact rather than running off rapidly.
Abstract:
The activated charcoal filter layer for gas masks contains a highly air-permeable, three-dimensional carrier framework essentially stable in shape, formed of wires, monofilaments or stays, to which a layer of granular, particularly spherical activated charcoal particles with a diameter of 0.1 to 1 mm is affixed. The carrier framework can be composed of wires, monofilaments or stays, the distance between them being at least twice as great as the diameter of the activated charcoal particles. The carrier framework can also be a large-pore reticulated polyurethane foam which has a weight of 20 to 60 g/l and pores with a diameter of 1.5 to 3 mm. The carrier framework can furthermore consist of wire netting or wire mesh arranged in layers, as well as of plastic or wire spirals with a length equal to and up to 10 times their diameter, or of wires or monofilaments with a length of 2 to 10 mm, which are held by twisted metal or plastic wires and project perpendicular from this axis in the shape of a spiral staircase. In spite of a very slight pressure drop, the filter performance is excellent.
Abstract:
In a particulate additive for water for fire fighting containing a strongly swelling water-insoluble high molecular weight polymer as gelatinizing agent, the improvement which comprises a water-soluble release agent which does not cause the particles of said gelatinizing agent to swell, the particles of the gelatinizing agent being encased or dispersed in the release agent. Suitable release agents include polyethylene glycol, diammonium biphosphate, sugars, mannitol, etc. The gelatinizing agent may be a moderately cross-linked water-insoluble acrylic or methacrylic acid copolymer.
Abstract:
Textile flat-shaped structures exhibiting specific properties, such as flame-resistance or adsorbing capacity, are required for technical purposes, said structures being at the same time characterized by a high flexibility and tensile strength, as well as good wearing characteristics when used for protective suits. This is achieved by the invention by yarns that are sheathed with active ingredients, such as adsorbents, fire-proofing agents, ion-exchangers, decontaminating agents for chemical combat agents, catalysts or fixed enzymes. The active ingredients are adhered to the surface of the yarn or embedded in a binding agent. The sheathing may be additionally braided or flocked.
Abstract:
A yarn is prepared from a mixture of textile staple fibers and active carbon staple fibers which consists of 5 to 75%, preferably 20 to 40%, of the latter by weight, by chopping active carbon monofilaments into staple fibers, mixing them with textile staple fibers in a liquid vehicle, separating the fibers from the liquid vehicle and spinning them to yarn which can be used in weaving fabrics of tensile strengths of as much as 2000 newtons per 5 centimeters, which in turn can be used in making filters and protective suits.
Abstract:
The invention relates to a process for producing granular, particularly spherical activated carbon by carbonization of suitable carbonaceous polymers in the form of polymer granules, in particular polymer spherules, as a starting material, which are convertible by carbonization into carbon at least essentially, wherein the polymer granules, in particular the polymer spherules, are continuously moved through a carbonization apparatus comprising a plurality of temperature zones and/or a temperature gradient so that an at least essentially complete conversion of the starting material to carbon is effected.
Abstract:
The invention refers to a process for producing activated carbon having catalytic activity by carbonization and subsequent activation of carbonaceous organic polymers, wherein carbonaceous organic polymers into which, in the course of their formation, at least one metal atom and/or metal ion has been interpolymerized are subjected to a carbonization and subsequent activation, forming an activated carbon loaded with the metal atom and/or metal ion. This obviates subsequent loading with the metal by costly and inconvenient impregnation after the activated carbon has been produced. By endowing the starting materials with the metal, moreover, a more homogeneous loading is achieved, and that homogeneous throughout all kinds of pores (i.e. macropores, mesopores and micropores), so that catalytic activity is enhanced, and in addition, activation is accelerated.
Abstract:
A filtering material with adsorbing properties which comprises a flat carrier, the carrier being provided on one or both sides with a binder coating which becomes tacky when heated and to which an adsorption material is adhered. An adsorption filter can be produced from at least two layers of the filtering material. The invention also relates to a process for producing the filtering material.
Abstract:
A method of processing spent ion-exchange resins contaminated with suspended particles, inorganic residues and/or organic foreign matter so as to render the resin ineffective for continued use, by which method this waste material can be processed to produce useful activated carbon particles instead of simply being dumped in a landfill. In accordance with the invention, granular spent organic ion-exchange resin having an ash content of from 5 to 30% is first dried, then carbonized under a substantially inert atmosphere at a temperature of 300 to 900° C., the inert atmosphere containing 0.2 to 4 volume percent oxygen up to 400° C., and finally activated at a temperature of at least 700° C. under a substantially inert atmosphere containing 3 to 50 volume percent steam.
Abstract:
The present invention relates to a process for the decontamination of chemical warfare agents which are present on the skin or have penetrated below the surface into the skin, or materials contaminated therewith, by a micro-emulsion which contains a C.sub.8 -C.sub.14 alkane, an anionic surfactant, an aliphatic C.sub.3 -C.sub.10 alcohol, and water, and to which possibly a wetting agent and/or antifreeze components such as antifreeze agents, NaCl or CaCl.sub.2 are also added.