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公开(公告)号:US11098249B2
公开(公告)日:2021-08-24
申请号:US16313883
申请日:2017-06-30
Applicant: GRIREM ADVANCED MATERIALS CO., LTD.
Inventor: Ronghui Liu , Weidong Zhuang , Fu Du , Yuanhong Liu , Wei Gao , Xia Zhang , Huibing Xu , Chunpei Yan , Xiaowei Zhang
Abstract: Phosphor, a preparation method for the phosphor, and a light emitting device having the phosphor. The phosphor comprises an inorganic compound which at least comprises an element M, an element A, an element D, and an element R; the element M is one or two elements selected from the group consisting of Lu, La, Pr, Nd, Sm, Y, Tb, and Gd and must comprise Lu; the element A is Si and/or Ge; the element D is one or two elements selected from the group consisting of O, N, and F and must comprise N; the element R is Ce and/or Dy. Since the ionic radius of Lu3+ is smaller than that of La3+, when the inorganic compound comprises element Lu, the original ligand site would be contracted. In order to reduce lattice distortion due to the ligand site contraction, the adjacent ligand site expands, and the photochromic property is adjusted.
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公开(公告)号:US11066600B2
公开(公告)日:2021-07-20
申请号:US16313894
申请日:2017-06-30
Applicant: GRIREM ADVANCED MATERIALS CO., LTD.
Inventor: Ronghui Liu , Weidong Zhuang , Fu Du , Yuanhong Liu , Wei Gao , Xia Zhang , Huibing Xu , Chunpei Yan , Xiaowei Zhang
Abstract: A lutetium nitride-based phosphor and a light emitting device comprising the same, wherein the lutetium nitride-based phosphor comprises an inorganic compound, and the composition of the inorganic compound comprises at least an M element, an A element, a D element and an R element; the M element is one or two elements selected from a group consisting of Lu, La, Pr, Nd, Sm, Y, Tb and Gd, and necessarily comprises Lu; the A element is Si and/or Ge; the D element is one or two elements selected from a group consisting of O, N and F, and necessarily comprises N; the R element is Ce and/or Dy, and the atomic molar ratio of the Lu element in the M element is greater than 50%. Because the ion radius of Lu3+ is smaller than the ion radius of La3+, the light color performance thereof can be flexibly adjusted according to needs.
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公开(公告)号:US20210155848A1
公开(公告)日:2021-05-27
申请号:US16612299
申请日:2017-10-18
Applicant: GRIREM ADVANCED MATERIALS CO., LTD.
Inventor: Ronghui LIU , Guantong CHEN , Yuanhong LIU , Xiaole MA
Abstract: The present invention relates to a red phosphor, a preparation method thereof and a light-emitting device prepared therefrom. A particle of the red phosphor consists of a phosphor inner core having a chemical formula of Ax1Gez1F6:y1Mn4+ and an outer shell having a chemical formula of Bx2Mz2F6:y2Mn4+, wherein 1.596≤x1≤2.2, 1.6≤x2≤2.2, 0.001≤y1≤0.2, 0≤y2≤0.2, 0.9≤z1≤1.1, and 0.9≤z2≤1.1; A and B are independently selected from alkali metal elements; and M is Si, or Si and Ge. The red phosphor provided by the present invention has high luminous efficiency and stability. Moreover, the phosphor alone or in combination with other luminescent materials can be used for preparing a light-emitting device with high performance.
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公开(公告)号:US20190225882A1
公开(公告)日:2019-07-25
申请号:US16313894
申请日:2017-06-30
Applicant: GRIREM ADVANCED MATERIALS CO., LTD.
Inventor: Ronghui LIU , Weidong ZHUANG , Fu DU , Yuanhong LIU , Wei GAO , Xia ZHANG , Huibing XU , Chunpei YAN , Xiaowei ZHANG
Abstract: A lutetium nitride-based phosphor and a light emitting device comprising the same, wherein the lutetium nitride-based phosphor comprises an inorganic compound, and the composition of the inorganic compound comprises at least an M element, an A element, a D element and an R element; the M element is one or two elements selected from a group consisting of Lu, La, Pr, Nd, Sm, Y, Tb and Gd, and necessarily comprises Lu; the A element is Si and/or Ge; the D element is one or two elements selected from a group consisting of O, N and F, and necessarily comprises N; the R element is Ce and/or Dy, and the atomic molar ratio of the Lu element in the M element is greater than 50%. Because the ion radius of Lu3+ is smaller than the ion radius of La3+, the light color performance thereof can be flexibly adjusted according to needs.
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35.
公开(公告)号:US10280482B2
公开(公告)日:2019-05-07
申请号:US15736874
申请日:2016-06-16
Applicant: GRIREM ADVANCED MATERIALS CO., LTD.
Inventor: Xiaowei Huang , Yang Xu , Jinyu Wang , Liangshi Wang , Zongyu Feng , Dali Cui , Zhiqi Long , Xu Sun , Na Zhao
IPC: C22B7/00 , C01F7/04 , C01F7/06 , C01F7/22 , C01F7/24 , C01F7/26 , C01F17/00 , C22B21/00 , C22B59/00 , C22B3/44
Abstract: Disclosed is a method of recovering rare earth, aluminum and silicon from rare earth-containing aluminum-silicon scrap. The method comprises: S1, acid-leaching the rare earth-containing aluminum-silicon scrap with an inorganic acid aqueous solution to obtain a silicon-rich slag and acid leached solution containing rare earth and aluminum element; S2, adding an alkaline substance into the acid leached solution containing the rare earth and aluminum element and controlling a PH value of the acid leaching solution between 3.5 to 5.2, performing a solid-liquid separation to obtain a aluminum hydroxide-containing precipitate and a rare earth-containing solution filter; S3, reacting the aluminum hydroxide containing precipitate with sodium hydroxide to obtain sodium metaaluminate solution and aluminum-silicon slag, and preparing a rare earth compound product with the rare earth-containing filtrate. The method dissolves an the aluminum and the rare earth with the acid and then via step wise alkaline conversion, convert aluminum icons to an aluminum hydroxide precipitate separated from rare earth ions, and then adds excessive amounts of sodium hydroxide to convert the aluminum hydroxide to a sodium metaaluminate solution, thereby realizing high-efficiency recovery of both rare earth and aluminum while significantly reducing the consumption of the sodium hydroxide and thus recovery cost.
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公开(公告)号:US09926489B2
公开(公告)日:2018-03-27
申请号:US14900198
申请日:2014-06-20
Inventor: Ronghui Liu , Huibing Xu , Xiaofang Zhou , Chunlei Zhao , Qian Ma , Yuanhong Liu , Huaqiang He , Xiaowei Huang
CPC classification number: C09K11/7792 , C09K11/0883 , C09K11/7721 , C09K11/7734 , C09K11/7749 , C09K11/7773 , C09K11/7774 , H01L33/504
Abstract: The present disclosure relates to a fluorescent powder and a light-emitting device including the same. The fluorescent powder includes an inorganic compound. The inorganic compound contains components including an element M, an element A, an element D, an element E, and an element R. The element M is selected from Eu, Ce, Mn, Tb, Dy, and Tm, the element A is selected from Mg, Ca, Sr, and Ba, the element D is selected from B, Al, Ga, In, La, Gd, Sc, Lu, and Y, the element E is selected from Si, Ge, Zr, and Hf, and the element R is at least two elements selected from N, O, F, and Cl. In a powder X-Ray Diffraction (XRD) spectrum with CoKα radiation, the inorganic compound at least has diffraction peaks within ranges of an Bragg angle (2θ) from 27.3° to 28.3°, 29.7° to 30.7°, 41.9° to 42.9°, and 43.5° to 44.5°.
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37.
公开(公告)号:US20170218267A1
公开(公告)日:2017-08-03
申请号:US15321956
申请日:2015-08-03
Inventor: Weidong Zhuang , Jiyou Zhong , Ronghui Liu , Yanfeng Li , Yuanhong Liu , Huibing Xu , Lei Chen
CPC classification number: C09K11/7792 , C09K11/7718 , C09K11/7721 , C09K11/7769 , C09K11/7774 , C30B1/10 , C30B29/22 , H01L33/502 , H01L33/505
Abstract: The application relates to fluorescent powder which has a garnet structure and can be effectively excited by ultraviolet light or blue light, a method for preparing the fluorescent powder, and a light emitting device, an image display device and an illumination device comprising the fluorescent powder. A chemical formula of the fluorescent powder is expressed as: (M1a-xM2x)ZrbM3cOd, where M1 is one or two elements selected from Sr, Ca, La, Y, Lu and Gd, Ca or Sr being necessary; M2 is one or two elements selected from Ce, Pr, Sm, Eu, Tb and Dy, Ce being necessary; M3 is at least one element selected from Ga, Si, and Ge, Ga being necessary; and 2.8≦a≦3.2, 1.9≦b≦2.1, 2.8≦c≦3.2, 11.8≦d≦12.2, and 0.002≦x≦0.6.
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公开(公告)号:US20240390878A1
公开(公告)日:2024-11-28
申请号:US18796186
申请日:2024-08-06
Applicant: GRIREM HI-TECH CO., LTD. , GRIREM ADVANCED MATERIALS CO., LTD. , Rare Earth Functional Materials (Xiong 'an) Innovation Center Co., Ltd.
Inventor: Yongqi ZHANG , Xiaowei HUANG , Weixin ZHAO , Xinlin PENG , Zheng ZHAO , Yongke HOU , Zhizhe ZHAI , Qiang ZHONG
IPC: B01J23/00 , B01D53/94 , B01J23/34 , B01J23/889 , B01J27/043 , B01J27/135 , B01J27/187 , B01J27/24 , B01J37/03 , B01J37/04 , B01J37/08
Abstract: Disclosed are a grain boundary and surface-doped rare earth manganese-zirconium composite compound as well as a preparation method and use thereof. A rare earth manganese oxide with a special structure is formed at grain boundary and surface of a rare earth zirconium-based oxide by a grain boundary doping method so as to increase oxygen defects at the grain boundary and the surface, thereby increasing the amount of active oxygen, improving the catalytic activity of the rare earth manganese-zirconium composite compound, inhibiting high-temperature sintering of the rare earth manganese-zirconium composite compound, and improving the NO catalytic oxidation capability. When the rare earth manganese-zirconium composite compound is applied to a catalyst, the consumption of noble metal can be greatly reduced.
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公开(公告)号:US20240363896A1
公开(公告)日:2024-10-31
申请号:US18770300
申请日:2024-07-11
Applicant: GRIREM HI-TECH CO., LTD. , GRIREM ADVANCED MATERIALS CO., LTD. , Rare Earth Functional Materials (Xiong 'an) Innovation Center Co., Ltd.
Inventor: Xiaowei HUANG , Xiaobao ZHANG , Juanyu YANG , Ning WANG , Zongyu FENG , Yang XU , Qiang ZHONG , Yiyang XIAO
IPC: H01M10/0562 , C01B25/45 , C01G25/00 , C01G33/00 , C01G35/00 , C01G45/12 , C01G49/00 , C01G51/00 , C01G53/00
CPC classification number: H01M10/0562 , C01B25/45 , C01G25/006 , C01G33/006 , C01G35/006 , C01G45/1292 , C01G49/0054 , C01G51/70 , C01G53/70 , C01P2002/54 , C01P2006/40 , H01M2300/0071
Abstract: Disclosed are a grain boundary- and surface-doped lithium-lanthanum-zirconium composite oxide solid electrolyte, a preparation method therefor, and an application thereof. Part of doping elements are step-doped at the grain boundary and the surface of the lithium-lanthanum-zirconium composite oxide solid electrolyte to improve the distribution state of the doping elements at the grain boundaries, reduce the number of grain boundaries, lower the grain boundary resistance of the lithium-lanthanum-zirconium composite oxide, thereby obtaining high ionic conductivity. The doping method has the advantages of being simple and convenient in process, low in cost and high in universality, can meet the requirements of different solid electrolytes on doping elements, and is suitable for large-scale application. The solid electrolyte obtained from the technical solution of the present application can be used in fields such as all-solid-state lithium or lithium ion batteries, semi-solid lithium ion batteries, lithium air batteries and the like.
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公开(公告)号:US20240360330A1
公开(公告)日:2024-10-31
申请号:US18624935
申请日:2024-04-02
Inventor: Xiaojun SUN , Yang LUO , Zilong WANG , Dunbo YU , Jiyuan GUO , Jiping DUAN , Yan WANG , Yuanfei YANG , Hongbin ZHANG , Kaiwen WU
IPC: C09D11/037 , C09D11/033 , C09D11/104 , C09D11/107 , C09D11/14
CPC classification number: C09D11/037 , C09D11/033 , C09D11/104 , C09D11/107 , C09D11/14
Abstract: Disclosed are an organic slurry with a gradient volatilization rate and a preparation method. The organic slurry includes a rare earth powder, an organic solvent, a resin, a dispersant, and/or an anti-settling agent, and/or a synergist, weight percentages of which are as follows: rare earth powder 50%-90%; organic solvent 8%-50%; resin 0.4%-6%; dispersant 0%-5%; anti-settling agent 0%-3%; and synergist 0%-3%. The preparation method includes: weighing the rare earth powder, organic solvent, resin, dispersant, and/or anti-settling agent, and/or synergist by weight percentage; sequentially adding the weighed ingredients into a mixer, stirring at a constant temperature, and then cooling to room temperature to obtain an organic carrier; adding the organic carrier and the weighed rare earth powder into a vacuum high-speed disperser to obtain a crude organic slurry; and transferring the crude organic slurry to a gap adjustable three-roll grinder for grinding to obtain a fine organic slurry.
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