公开(公告)号：US20100010161A1

公开(公告)日：2010-01-14

申请号：US12377019

申请日：2007-08-23

Applicant: Daniel J. Arriola ,  Brain A. Jazdzewski ,  Francis J. Timmers ,  Paul C. Vosejpka ,  Nicole L. Wagner ,  Brian G. Landes ,  Guenter A. Jueptner ,  David H. Bank ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Brain A. Jazdzewski ,  Francis J. Timmers ,  Paul C. Vosejpka ,  Nicole L. Wagner ,  Brian G. Landes ,  Guenter A. Jueptner ,  David H. Bank ,  Timothy T. Wenzel

IPC: C08F8/00

CPC classification number: C08F299/00 ,  C08L9/00 ,  C08L23/16 ,  C08L2312/00 ,  C08L2666/08

Abstract: Two or more chemically distinguishable ethylenically unsaturated polymers, at least one having from 0.001 to 50 mole percent unsaturation and at least one other having an expected Tg or measured Tm value greater than 100° C. are cross-metathesized to form thermoplastic elastomers having improved performance properties.

Abstract translation: 两种或更多种化学上可区分的烯键式不饱和聚合物，至少一种具有0.001至50摩尔％不饱和度和至少一种具有预期Tg或测量的Tm值大于100℃的其它聚合物进行交叉分层以形成具有改进性能的热塑性弹性体 属性。

公开(公告)号：US20090186985A1

公开(公告)日：2009-07-23

申请号：US10585597

申请日：2005-01-21

Applicant: Roger L. Kuhlman ,  Timothy T. Wenzel ,  Yunwa W. Cheung ,  Phillip D. Hustad ,  Edmund M. Carnahan ,  John R. Briggs ,  Brian A. Jazdzewski ,  Wenbin Liang ,  Roji Mori ,  Kouichi Kizu ,  Nobuo Kawahara ,  Shingo Matuso ,  Shinichi Kojoh ,  Norio Kashiwa

Inventor： Roger L. Kuhlman ,  Timothy T. Wenzel ,  Yunwa W. Cheung ,  Phillip D. Hustad ,  Edmund M. Carnahan ,  John R. Briggs ,  Brian A. Jazdzewski ,  Wenbin Liang ,  Roji Mori ,  Kouichi Kizu ,  Nobuo Kawahara ,  Shingo Matuso ,  Shinichi Kojoh ,  Norio Kashiwa

IPC: C08L53/00

CPC classification number: C08G81/021

Abstract: The present invention relates to olefinic compositions comprising a functionalized branched olefin copolymer containing functionalized sidechains derived from olefin and at least one chain end nucleophilic heteroatom containing functional group with at least one protic hydrogen, optionally with one or more copolymerizable monomers, the copolymer characterized by having A) a Tg 100° C.; C) an elongation at break of greater than or equal to 500 percent; D) a Tensile Strength of greater than or equal to 1,500 psi (10,300 kPa) at 25° C.; E) a TMA temperature>80° C., and F) an elastic recovery of greater than or equal to 50 percent.

Abstract translation: 本发明涉及烯烃组合物，其包含官能化的支链烯烃共聚物，其含有衍生自烯烃的官能化侧链和至少一个具有至少一个官能团的链末端亲核杂原子与至少一个质子氢，任选具有一个或多个可共聚单体，所述共聚物的特征在于具有 A）通过DSC测量的Tg <-10℃; B）Ta> 100℃。 C）断裂伸长率大于或等于500％; D）在25℃下的拉伸强度大于或等于1,500psi（10,300kPa）; E）TMA温度> 80℃，F）大于或等于50％的弹性恢复。

公开(公告)号：US20090163667A1

公开(公告)日：2009-06-25

申请号：US12065867

申请日：2006-09-14

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

IPC: C08L23/16 ,  C08F4/44 ,  C08F2/00 ,  C08F210/00

CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2/001 ,  C08F4/64048 ,  C08F4/64144 ,  C08F4/64148 ,  C08F4/64193

Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.

Abstract translation: 聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂， 支链聚合物，优选包括伪嵌段分子结构。

公开(公告)号：US06956089B2

公开(公告)日：2005-10-18

申请号：US10373121

申请日：2003-02-24

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/64 ,  B01J31/38 ,  C08F210/14

CPC classification number: B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06825287B2

公开(公告)日：2004-11-30

申请号：US10772921

申请日：2004-02-05

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F234

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

Abstract translation: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US06689847B2

公开(公告)日：2004-02-10

申请号：US09995043

申请日：2001-11-27

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F464

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/903 ,  Y10S526/907 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06180735B2

公开(公告)日：2001-01-30

申请号：US09215432

申请日：1998-12-17

Applicant: Timothy T. Wenzel

Inventor： Timothy T. Wenzel

IPC: C08F442

CPC classification number: C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943 ,  C08F2/40

Abstract: The present invention relates to a catalyst composition and a method for making the catalyst composition of a polymerization catalyst and a carbonyl compound. The invention is also directed to the use of the catalyst composition in the polymerization of olefin(s). In particular, the polymerization catalyst system is supported on a carrier. More particularly, the polymerization catalyst comprises a bulky ligand metallocene-type catalyst system.

Abstract translation: 本发明涉及催化剂组合物和制备聚合催化剂和羰基化合物的催化剂组合物的方法。 本发明还涉及催化剂组合物在烯烃聚合中的用途。 特别地，聚合催化剂体系被负载在载体上。 更具体地，聚合催化剂包含庞大配体金属茂型催化剂体系。

公开(公告)号：US5136105A

公开(公告)日：1992-08-04

申请号：US676439

申请日：1991-03-28

Applicant: Timothy T. Wenzel

Inventor： Timothy T. Wenzel

IPC: B01J31/30 ,  C07B61/00 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/68 ,  C07C47/02 ,  C07C67/29

CPC classification number: C07C45/68 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C67/29

Abstract: A process for the oxidation of a compound having a terminal carbon-carbon double bond to produce the corresponding aldehyde is disclosed. In one embodiment, the process comprises contacting the compound with molecular oxygen in the presence of a Group VIII metal component initially substantially free of NO ligands and NO.sub.2 ligands in an amount effective to promote the oxidation of the compound, a reoxidation component in an amount effective to reoxidize a reduced Group VIII metal component to the Group VIII metal component and at least one alcohol selected from secondary alcohols, tertiary alcohols and mixture thereof in an amount effective to increase the aldehyde selectivity of the oxidation. The contacting occurs at conditions effective to oxidize the compound and the form the corresponding aldehyde.

公开(公告)号：US09296836B2

公开(公告)日：2016-03-29

申请号：US14116788

申请日：2012-05-11

Applicant: Matthew D. Christianson ,  Timothy S. De Vries ,  Robert D. Froese ,  Matthias S. Ober ,  Jasson T. Patton ,  Duane R. Romer ,  Gordon R. Roof ,  Lixin Sun ,  Endre Szuromi ,  Curt N. Theriault ,  Dean M. Welsh ,  Timothy T. Wenzel ,  Paul H. Moran

Inventor： Matthew D. Christianson ,  Timothy S. De Vries ,  Robert D. Froese ,  Matthias S. Ober ,  Jasson T. Patton ,  Duane R. Romer ,  Gordon R. Roof ,  Lixin Sun ,  Endre Szuromi ,  Curt N. Theriault ,  Dean M. Welsh ,  Timothy T. Wenzel ,  Paul H. Moran

IPC: C08F4/78 ,  C08F10/00 ,  C08F210/06 ,  C07F11/00 ,  C08F110/06

CPC classification number: C08F4/78 ,  C07F11/00 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/69112 ,  C08F210/16 ,  C08F2500/15

Abstract: Provided is a non-cyclopentadienyl-based chromium-ligand complex, preferably a chromium-ligand complex of formula (J): LCr(RA)m(D)k (J), wherein L is a non-Cp monoanionic ligand; Cr (chromium) is in a formal oxidation state of +3 or +2; when Cr formally is Cr+3, either m is 1 and RA is hydrocarbylene (a hydrocarbylene chromium-ligand complex of formula (J)) or m is 2 and each RA independently is hydrocarbyl (a dihydrocarbyl chromium-ligand complex of formula (J)), wherein each hydrocarbyl or hydrocarbylene of RA independently is unsubstituted or substituted by from 1 to 5 RAS; each RAS independently is a neutral aprotic heteroalkyl, neutral aprotic heterocycloalkyl, neutral aprotic heteroaryl, or neutral aprotic aryl; when Cr formally is Cr+2, m is 1 and RA is hydrocarbyl (a hydrocarbyl chromium-ligand complex of formula (J)); k is an integer of 0 or 1; D is absent when k is 0 or D is a neutral ligand when k is 1; wherein the chromium-ligand complex of formula (J) is overall neutral and lacks a cyclopentadienyl-based (Cp-based) moiety. Also provided is a chromium catalyst comprising or prepared from the complex. Also provided is a process of making the catalyst and a process employing the chromium catalyst for polymerizing the olefin monomer, especially a straight chain 1-alkene, to prepare the polyolefin, especially a partially chain-straightened poly(1-alkene) or olefin block copolymer. Further provided is the partially chain-straightened poly(1-alkene) or olefin block copolymer prepared thereby. Also provided is a high throughput workflow.

公开(公告)号：US07989551B2

公开(公告)日：2011-08-02

申请号：US11817344

申请日：2006-01-30

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  Marilyn Bokota ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel ,  Pamela J. Stirn

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  Marilyn Bokota ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel ,  Pamela J. Stirn

IPC: C08F2/38 ,  C08F297/08 ,  C08F4/646

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/06 ,  C08F210/16 ,  C08F297/06 ,  C08F297/08 ,  C08F297/083 ,  C08F2410/01 ,  C08L23/10 ,  C08L23/16 ,  C08L2308/00 ,  C08F4/65912 ,  C08F4/6465 ,  C08F2/38 ,  C08L2666/06 ,  C08F2500/17 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/03 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64144

Abstract: A process for the polymerization of one or more addition polymerizable monomers to form a copolymer comprising multiple regions or segments of differentiated polymer composition or properties comprising contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions with a composition comprising at least one olefin polymerization catalyst, a cocatalyst and a chain shuttling agent, said process being characterized by formation of at least some of the growing polymer chains under differentiated process conditions such that two or more blocks or segments formed within at least some of the resulting polymer are chemically or physically distinguishable.

Abstract translation: 一种用于聚合一种或多种可加聚的单体以形成共聚物的方法，所述共聚物包含分化聚合物组合物或性质的多个区域或链段，包括在加成聚合条件下使加成聚合单体或单体混合物与包含至少一种烯烃聚合 催化剂，助催化剂和链穿梭剂，所述方法的特征在于在不同的工艺条件下形成至少一些生长的聚合物链，使得在至少一些所得聚合物内形成的两个或多个嵌段或链段是化学或物理的 可区分