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公开(公告)号：US20150203662A1
公开(公告)日：2015-07-23
申请号：US14623424
申请日：2015-02-16
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan
IPC分类号： C08K5/544 , C08K5/5419 , C08K3/36
CPC分类号： C08K5/544 , C08C19/44 , C08F36/04 , C08K3/36 , C08K5/5419 , C08K5/548 , C08K5/549 , C08L7/00 , C08L15/00 , C08F4/48
摘要： Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a group or compound that can act to covalently bond the filler particles and the polymer. The group can be provided as a substituent of the filler particle, or a discreet compound can be provided in the composition.
摘要翻译： 具有所需性质的硫化剂可以从包含含有羟基的芳基官能团的二氧化硅或其它颗粒填料的组合物中获得，所述聚合物含有或包含硅的氧化物和可以共同键合填料颗粒的基团或化合物， 聚合物。 该基团可以作为填料颗粒的取代基提供，或者可以在组合物中提供离散的化合物。
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公开(公告)号：US08637600B2
公开(公告)日：2014-01-28
申请号：US13207694
申请日：2011-08-11
申请人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
发明人： Xiao-Dong Pan , Zengquan Qin , Yuan-Yong Yan , Jessica Kurasch
摘要： Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a compound that includes multiple hydroxyl groups. The compound can act to disrupt the interactivity of the functionalities and the particulate filler particles during processing of the composition, thereby facilitating processing of the composition.
摘要翻译： 具有期望性质的硫化橡胶可以从包含含羟基芳基官能团的聚合物的组合物，二氧化硅或其中包含或包括硅的氧化物和包括多个羟基的化合物的其它颗粒填料获得。 该组合物可以在组合物加工期间起作用以破坏功能性和颗粒填料颗粒的相互作用，从而有助于组合物的加工。
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公开(公告)号：US08541509B2
公开(公告)日：2013-09-24
申请号：US13309958
申请日：2011-12-02
申请人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
发明人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
CPC分类号： C08C19/44 , C08L9/00 , C08L19/006 , C08L2666/08
摘要： A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound.
摘要翻译： 一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）通过使用镧系元素基催化剂聚合共轭二烯单体以形成反应性聚合物，和（ii）使反应性聚合物与受保护的肟化合物反应。
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公开(公告)号：US20120283387A1
公开(公告)日：2012-11-08
申请号：US13462221
申请日：2012-05-02
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
IPC分类号： C08F8/30
CPC分类号： C08C19/44 , C08F36/04 , C08F212/08 , C08F4/48 , C08F4/58
摘要： A macromolecule includes at least one polymer chain and terminal functionality. The terminal functionality includes a ring-opened radical of a cyclosilazane or cyclic hydrosiloxane. The polymer can include unsaturated mer units and can be provided via anionic polymerization techniques. The macromolecule can be used as a component of a composition that also includes particulate fillers, with the composition being useful for the production of vulcanizates.
摘要翻译： 大分子包括至少一个聚合物链和末端官能团。 末端官能团包括环硅氮烷或环状硅氧烷的开环基团。 聚合物可以包括不饱和聚合单元，并且可以通过阴离子聚合技术提供。 大分子可以用作组合物的组分，该组合物还包括颗粒填料，该组合物可用于生产硫化橡胶。
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公开(公告)号：US08236888B2
公开(公告)日：2012-08-07
申请号：US13191737
申请日：2011-07-27
申请人： Yuan-Yong Yan , Jason Poulton , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
发明人： Yuan-Yong Yan , Jason Poulton , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
CPC分类号： C08L19/006 , C08C19/44 , C08F291/00 , C08K3/013 , C08L15/00 , C08L51/10
摘要： A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
摘要翻译： 化学键合到聚合物末端的聚合物和多面体基团的大分子提供许多加工和性能优点。 这种高分子的进一步官能化也被描述为在某些情况下是有利的。 还提供了提供，功能化和利用大分子的方法。
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公开(公告)号：US20120136128A1
公开(公告)日：2012-05-31
申请号：US13381311
申请日：2010-06-28
申请人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan , David M. Roggeman
发明人： Yuan-Yong Yan , Zengquan Qin , Xiao-Dong Pan , David M. Roggeman
IPC分类号： C08F236/10 , C07F7/02
CPC分类号： C08F4/48 , C07F1/02 , C08F4/484 , C08F12/08 , C08F36/04 , C08F136/04 , C08F236/04 , C08F2810/40 , C08F236/10
摘要： A group of compounds defined by the general formula (I) can be used to anionically initiate polymerization of unsaturated monomers. In the formula, M is an alkali metal atom, R1 is an aryl group having at least one OR2 substituent group where each R2 is a group that is nonreactive toward M, and R is a hydrocarbyl group. The subject initiators can be used in semi-batch and continuous polymerization processes, even those which are performed at elevated temperatures.
摘要翻译： 由通式（I）定义的一组化合物可用于阴离子引发不饱和单体的聚合。 在该式中，M为碱金属原子，R1为具有至少一个OR 2取代基的芳基，其中每个R 2为不对M反应的基团，R为烃基。 本发明的引发剂可以用于半间歇和连续聚合过程中，甚至可以在高温下进行。
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37.发明授权Method of improving affinity between filler and polymers having a low degree of unsaturation 有权提高填充剂与低度不饱和度的聚合物之间的亲和性的方法公开(公告)号：US08158700B2
公开(公告)日：2012-04-17
申请号：US12200103
申请日：2008-08-28
CPC分类号： C08L21/00 , C08C19/02 , C08C19/44 , C08J3/22 , C08J2309/00 , C08K3/013 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/00 , C08L15/00 , C08L23/16 , C08L2666/02 , C08L2666/08
摘要： Provided is a composition comprising at least one polymer having a degree of unsaturation of no more than about 50 mol %; a filler selected from the group consisting of carbon black, silica, and mixtures thereof; and a polymeric additive comprising a functional end group reactive with said filler, wherein said polymeric additive has a degree of unsaturation of no more than about 50 mol % and a number average molecular weight between about 1,000 and about 25,000. The composition may optionally contain one or more polymers having a degree of unsaturation of more than 50 mol %. The composition may be particularly useful as a component for a tire.
摘要翻译： 提供了包含至少一种不饱和度不大于约50mol％的聚合物的组合物; 选自碳黑，二氧化硅及其混合物的填料; 以及包含与所述填料反应的官能端基的聚合物添加剂，其中所述聚合物添加剂的不饱和度不超过约50摩尔％，数均分子量在约1,000至约25,000之间。 组合物可以任选地含有一种或多种不饱和度大于50mol％的聚合物。 组合物可以特别用作轮胎的组分。
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38.发明申请Hairy Polymeric Nanoparticles With First And Second Shell Block Polymer Arms 有权具有第一和第二壳块聚合物臂的多毛聚合物纳米颗粒公开(公告)号：US20110213066A1
公开(公告)日：2011-09-01
申请号：US12754367
申请日：2010-04-05
申请人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
发明人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
IPC分类号： C08F271/02 , C08F279/02 , C08L53/02 , B82B1/00
CPC分类号： C08F279/02 , C08F297/046 , C08L9/06 , C08L21/00 , C08L2205/03 , C08L2207/53 , C08L7/00 , C08L9/00 , C08L53/00 , C08L53/02
摘要： Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要翻译： 包括用于制备毛发聚合物纳米颗粒的组合物和方法，包括第一和第二壳嵌段聚合物臂至少部分地相分离并且围绕聚合物芯。 一种类型的聚合物臂可以具有比其它类型的聚合物臂更大的极性。 还提供了包含毛状纳米颗粒的橡胶组合物。
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公开(公告)号：US20110172369A1
公开(公告)日：2011-07-14
申请号：US12935863
申请日：2009-03-30
申请人： Yuan-Yong Yan , Steven Luo , Mark T. Arigo
发明人： Yuan-Yong Yan , Steven Luo , Mark T. Arigo
摘要： A macromolecule includes at least one polymer chain with at least one functionality. The polymer can include unsaturated mer units and can be provided via anionic and pseudo-living polymerization techniques. In either technique, the functionality can include at least one 5- or 6-membered ring which includes a secondary amine group and at least one additional heteroatom; in the latter technique, the functionality can include a hydrazone radical. Such polymers can be used to provide compositions that also include particulate fillers, such compositions being useful for the production of vulcanizates.
摘要翻译： 大分子包括至少一个具有至少一个官能团的聚合物链。 聚合物可以包括不饱和聚合单元，并且可以通过阴离子和假活性聚合技术提供。 在任一技术中，官能团可以包括至少一个5-或6-元环，其包括仲胺基团和至少一个另外的杂原子; 在后一种技术中，官能团可以包括腙基团。 这样的聚合物可用于提供还包括颗粒填料的组合物，这种组合物可用于生产硫化橡胶。
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公开(公告)号：US20100286348A1
公开(公告)日：2010-11-11
申请号：US12810846
申请日：2008-12-28
CPC分类号： C08F36/06 , C07D339/08 , C08C19/44 , C08F36/04 , C08F212/14 , C08F290/06 , C08F290/14 , C08F297/02 , C08F297/04 , C08K3/013 , C08L53/02 , Y02P20/55 , C08F4/48 , C08L2666/02 , C08L15/00
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要翻译： 具有所需性能的硫化橡胶可以从包含含羟基芳基官能团的聚合物的化合物中获得。 可以通过使用任何或所有合适的引发剂，单体和任选的终止化合物来掺入官能团。 这些聚合物与常规和非常规填料都具有优异的相互作用。
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