Free-standing MOF-derived hybrid porous carbon nanofiber mats

    公开(公告)号:US10998550B2

    公开(公告)日:2021-05-04

    申请号:US16069707

    申请日:2017-01-16

    Abstract: According to the present disclosure, a method of fabricating a metal-carbon fibrous structure is provided. The method comprises the steps of: (a) forming a fibrous support structure comprising composite nanocrystals and polymeric fibers, wherein each of the composite nanocrystals comprises metal ions connected by organic ligands; (b) growing the composite nanocrystals on the fibrous support structure; and (c) subjecting the fibrous support structure of step (b) to carbonization to form the metal-carbon fibrous structure, wherein the metal-carbon fibrous structure comprises metal nanoparticles derived from the composite nanocrystals comprising metal organic framework (MOF), particularly zeolitic imidazolate framework (ZIF). A metal-carbon fibrous structure comprising carbon based fibers arranged to form a porous network and the carbon based fibers are doped with metal nanoparticles, wherein the carbon based fibers have surfaces which comprise graphitic carbon, is also disclosed herein.

    FREE-STANDING POROUS CARBON FIBROUS MATS AND APPLICATIONS THEREOF

    公开(公告)号:US20210046445A1

    公开(公告)日:2021-02-18

    申请号:US16994216

    申请日:2020-08-14

    Inventor: Xu Li Suxi Wang

    Abstract: A method of producing a porous carbon composite fibrous mats formed of a network of carbon fibers incorporated with porous carbon particles. The method includes electrospinning a polymer solution to form a porous layer of polymeric fibers and the polymeric fibers are doped with a precursor of conductive metal particles, wherein the polymer solution includes a polymer and the precursor of the conductive metal particles, electrospraying a metal organic framework suspension onto the porous layer of polymeric fibers, wherein the metal organic framework suspension includes metal organic framework particles, repeating the electrospinning and electrospraying in an alternating manner to form a porous network of polymeric fibers incorporated with the metal organic framework particles, and heating the porous network of polymeric fibers incorporated with the metal organic framework particles to form the porous carbon composite fibrous mats. The porous carbon composite fibrous mats and its applications thereof are also disclosed herein.

    One-step process for making a polymer composite coating with high barrier

    公开(公告)号:US10233297B2

    公开(公告)日:2019-03-19

    申请号:US15313091

    申请日:2015-05-21

    Abstract: This invention relates to a a one-step process for making a polymer composite suspension for coating plastic films characterized in that a first polymer is synthesized in-situ optionally in the presence of other polymers and in the presence of clay. Preferably the polymer composite suspension comprises a) 1.0 to 11.0 wt % of clay or silane modified clay, b) 0.1 to 10.0 wt % of poly (acrylic acid), which is a copolymer of acrylic acid (AA) with at least one other monomer selected from 2-ethylhexyl acrylate (EHA), β-carboxyethyl acrylate (β-CEA), methacrylamidoethyl ethylene urea (WAM II) and ethoxylated behenyl methacrylate (β-EM), c) 1.0 to 15.0 wt % of other polymers, preferably poly (vinyl alcohol) and d) 70 to 97 wt % of water or mixture of water with 2-propanol. The coating films made from the suspensions show good barrier capabilities against water vapor and oxygen can be used to make barrier layers on or within plastic films for packaging applications. The invention also relates to methods for making silane modified clay usable in the process for making the suspensions.

    CONDUCTIVE FIBROUS MATERIALS
    39.
    发明申请
    CONDUCTIVE FIBROUS MATERIALS 审中-公开
    导电纤维材料

    公开(公告)号:US20160111723A1

    公开(公告)日:2016-04-21

    申请号:US14890410

    申请日:2014-05-12

    Abstract: There is provided a conductive fibrous material comprising a plurality of carbonaceous fibers, wherein each carbonaceous fiber is fused to at least one other fiber. The carbonaceous fibers may be fused at fiber-to-fiber contact points by a polymer. The process of making the conductive fibrous material comprises mixing a phenolic polymer with a second polymer to form a polymer solution, preparing phenolic fibers having nano- or micro-scale diameters by electrospinning the polymer solution, and subsequent carbonization of the obtained phenolic fibers, thereby generating carbonaceous fibers, wherein each carbonaceous fiber is fused to at least one other fiber. The conductive fibrous material may be useful in electrode materials for energy storage devices.

    Abstract translation: 提供了包含多个碳质纤维的导电纤维材料,其中每个碳质纤维与至少一种其它纤维融合。 碳纤维可以通过聚合物在纤维 - 纤维接触点处熔融。 制造导电纤维材料的方法包括将酚类聚合物与第二聚合物混合以形成聚合物溶液,通过静电纺丝聚合物溶液制备具有纳米级或微尺度直径的酚醛纤维,并随后碳化得到的酚醛纤维 产生含碳纤维,其中每个碳质纤维与至少一种其它纤维融合。 导电纤维材料可用于储能装置的电极材料中。

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