公开(公告)号：US10260395B2

公开(公告)日：2019-04-16

申请号：US15738879

申请日：2016-06-30

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley A. Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01D53/94 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J23/00 ,  B01J23/63 ,  B01J23/66 ,  B01J23/89 ,  B01J23/44 ,  B01J23/46 ,  B01J35/10

Abstract: A nitrous oxide (N2O) removal catalyst composite is described, which includes: a N2O removal catalytic material on a carrier, wherein the catalytic material comprises a platinum group metal (PGM) component on a ceria-containing support having a single phase, cubic fluorite crystal structure. The catalytic material is effective to decompose nitrous oxide (N2O) to nitrogen (N2) and oxygen (O2) and/or to reduce N2O to N2 and water (H2O) and/or (CO2) under conditions of an exhaust stream of an internal combustion engine operating under conditions that are stoichiometric or lean with periodic rich transient excursions. Methods of making and using the same are also provided.

公开(公告)号：US10201804B2

公开(公告)日：2019-02-12

申请号：US15546953

申请日：2016-01-29

Applicant: BASF Corporation ,  Georgia Tech Research Corporation

Inventor： Andrey Karpov ,  David Preli ,  Knut Wassermann ,  Andreas Sundermann ,  Sang-IL Choi ,  Ping Lu ,  Younan Xia

IPC: B01D53/94 ,  B01J23/44 ,  B01J35/00 ,  B01J37/04 ,  B01J37/00 ,  B01J37/02 ,  B01J21/04 ,  B01J35/10 ,  B01J23/40 ,  B01J37/16 ,  B01J37/08 ,  F01N3/10

Abstract: Catalytic materials for exhaust gas purifying catalyst composites comprise platinum group metal (PGM)-containing catalysts whose PGM component(s) are provided as nanoparticles and are affixed to a refractory metal oxide, which may be provided as a precursor. Upon calcination of the catalysts, the PGM is thermally affixed to and well-dispersed throughout the support. Excellent conversion of hydrocarbons and nitrogen oxides can advantageously be achieved using such catalysts.

公开(公告)号：US09138725B2

公开(公告)日：2015-09-22

申请号：US14203862

申请日：2014-03-11

Applicant: BASF Corporation

Inventor： Jeffrey B. Hoke ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01D53/56 ,  B01D53/94 ,  B01J8/02 ,  C01B21/00 ,  C01B23/00 ,  C01B25/00 ,  C01B31/00 ,  C01B33/00 ,  C01B35/00 ,  C01G28/00 ,  C01G30/00 ,  F01N3/10 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/10 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J21/04 ,  B01J23/63

CPC classification number: B01J23/63 ,  B01D53/9413 ,  B01D53/9427 ,  B01D53/9459 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/102 ,  B01D2255/2065 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2523/00 ,  Y02T10/24 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/22 ,  B01J2523/25 ,  B01J2523/41

Abstract: A catalyst material for the oxidation of NO comprising a catalyst carrier including a ceria-alumina support having platinum and optionally palladium dispersed on the support is described. When palladium is present, the ratio of platinum to palladium by weight is at least 1:1. The amount of ceria in the support is in the range of 1% to 12% by weight. The catalyst material is useful for methods and systems of abating pollutants from automotive exhaust gas from lean burn engines.

Abstract translation: 描述了用于氧化NO的催化剂材料，其包含催化剂载体，其包含具有铂的二氧化铈 - 氧化铝载体和任选的钯分散在载体上。 当钯存在时，铂与钯的重量比至少为1:1。 载体中二氧化铈的量在1重量％至12重量％的范围内。 催化剂材料可用于减轻来自稀燃燃烧发动机的汽车尾气污染物的方法和系统。

公开(公告)号：US20150165422A1

公开(公告)日：2015-06-18

申请号：US14107704

申请日：2013-12-16

Applicant: BASF Corporation

Inventor： Shiang Sung ,  Stanley A. Roth ,  Claudia Zabel ,  Susanne Stiebels ,  Andreas Sundermann ,  Olga Gerlach

IPC: B01J29/076 ,  B01D53/94

CPC classification number: B01J29/076 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/945 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2255/912 ,  B01J23/40 ,  B01J23/6562 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  Y02T10/24

Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.

Abstract translation: 描述了用于处理来自柴油发动机的废气排放物的氧化催化剂复合材料，方法和系统。 更具体地，描述了包括包含Pt组分和Pd组分的第一修补基面涂层和包含含有锰，沸石和铂组分的难熔金属氧化物载体的第二修补基面涂层的氧化催化剂复合物。

公开(公告)号：US09034287B2

公开(公告)日：2015-05-19

申请号：US14205049

申请日：2014-03-11

Applicant: BASF Corporation

Inventor： Olga Gerlach ,  Andreas Sundermann ,  Jeffrey B. Hoke

IPC: B01D29/74 ,  B01D53/94 ,  B01J29/74 ,  B01J23/42 ,  B01J23/44 ,  B01J29/70 ,  B01J35/02 ,  B01J35/04 ,  B01J35/08 ,  B01J37/02

CPC classification number: B01J29/7415 ,  B01D53/945 ,  B01D2255/102 ,  B01D2255/2047 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9202 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/58 ,  B01J29/0354 ,  B01J29/068 ,  B01J29/12 ,  B01J29/22 ,  B01J29/44 ,  B01J29/7007 ,  B01J29/74 ,  B01J29/85 ,  B01J35/023 ,  B01J35/04 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0215 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/824 ,  B01J2523/828

Abstract: Described are catalyst compositions, catalytic articles, exhaust gas treatment systems and methods that utilize the catalytic articles. The catalyst composition comprises a washcoat including a zeolite, refractory metal oxide support particles, and a platinum group metal supported on the refractory metal oxide support particles. Greater than 90% of the refractory metal oxide particles supporting PGM have a particle size greater than 1 μm and a d50 less than 40 microns.

Abstract translation: 描述了催化剂组合物，催化制品，废气处理系统和利用催化制品的方法。 催化剂组合物包括包含沸石，耐火金属氧化物载体颗粒和负载在难熔金属氧化物载体颗粒上的铂族金属的修补基面涂层。 支持PGM的高于90％的难熔金属氧化物颗粒具有大于1μm的粒度和小于40微米的d50。