Abstract:
There is disclosed a polycrystalline lithium-ion conductive membrane for a lithium-air battery that comprises at least one surface, a polycrystalline lithium-ion conductive material comprising grain boundaries, and at least one modifying phase, wherein (a) the at least one modifying phase is incorporated into the grain boundaries to form a modified polycrystalline lithium-ion conductive material comprising modified grain boundaries, (b) the at least one modifying phase is incorporated into the at least one surface to form a modified surface, or both (a) and (b). Various lithium based batteries, including lithium ion, lithium-air, and lithium-water batteries are disclosed, as well as methods for modifying the polycrystalline lithium-ion conductive membrane to allow it to be used in such battery applications.
Abstract:
A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.
Abstract:
Glass articles including a glass laminate substrate having a plurality of flow channels formed therein are provided. The glass laminate substrate includes a first glass layer and a second glass layer fused together. In various embodiments, at least 80% of a total area of a floor of each of the flow channels has a local surface flatness of less than 100 nm/mm2, measured along a length and width of the floor of each of the plurality of flow channels Such glass articles are manufactured using a method including contacting a first portion of the first glass layer with a first etchant for a first etch time to at least partially form flow channels in the glass substrate and contacting the flow channels with a second etchant for a second etch time to flatten a floor of each of the flow channels.
Abstract:
A method of plugging channels of a honeycomb body and a honeycomb body including plugged channels. The method includes applying a shear force to a plugging mixture including a plurality of inorganic particles, clay, and a liquid vehicle to alter the viscosity of the plugging mixture from a first viscosity prior to the vibrating to a second viscosity which is less than the first viscosity. A honeycomb body is placed into contact with the plugging mixture such that a portion of the plugging mixture having the second viscosity flows into the plurality of channels. Application of the shear force is stopped or reduced to increase the viscosity of the portion of the plugging mixture in the plurality of channels to greater than the first viscosity.
Abstract:
An air stable solid garnet composition, comprising:a bulk composition and a surface protonated composition on at least a portion of the bulk composition as defined herein, and the protonated surface composition is present on at least a portion of the exterior surface of the bulk composition at a thickness of from 0.1 to 10,000 nm. Also disclosed is a composite electrolyte structure, and methods of making and using the composition and the composite electrolyte structure.
Abstract:
A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.
Abstract:
Described herein are methods for improved transfer of graphene from formation substrates to target substrates. In particular, the methods described herein are useful in the transfer of high-quality chemical vapor deposition-grown monolayers of graphene from metal, e.g., copper, formation substrates to ultrathin, flexible glass targets. The improved processes provide graphene materials with less defects in the structure.
Abstract:
A catalyst-free CVD method for forming graphene. The method involves placing a substrate within a reaction chamber, heating the substrate to a temperature between 600° C. and 1100° C., and introducing a carbon precursor into the chamber to form a graphene layer on a surface of the substrate. The method does not use plasma or a metal catalyst to form the graphene.
Abstract:
An insulating glass-ceramic substrate for synthesizing graphene includes discrete, crystalline, nanophase metallic regions capable of catalyzing graphene growth. The nanophase regions may be formed by thermal treatment of a glass-ceramic substrate containing the corresponding metal oxide. Single layer and double layer graphene are prepared on the modified glass-ceramic substrate in a vacuum chemical vapor deposition (CVD) process from hydrocarbon precursors. The graphene-coated glass-ceramic substrate is electrically conductive.