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公开(公告)号:US20190165410A1
公开(公告)日:2019-05-30
申请号:US16092389
申请日:2016-05-04
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhiqiang YU , Haijing LIU
IPC: H01M10/058 , H01M10/052 , H01M4/04 , H01G11/06 , H01G11/62 , H01G11/52 , H01G11/28 , H01G11/60 , H01G11/84 , H01G11/20
Abstract: A method involves contacting a material for a lithium-based energy storage device with a supercritical substance maintained at or above its critical point. A lithium-based energy storage device is also provided, in which at least one of the various component parts (battery separator, lithium salt, negative electrode, negative current collector, positive electrode, and positive current collector) is substantially free of residual water by contact with the supercritical substance maintained at or above its critical point.
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32.
公开(公告)号:US20250140900A1
公开(公告)日:2025-05-01
申请号:US18521081
申请日:2023-11-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Xin ZHANG , Zhe LI , Qili SU , Thomas A. YERSAK , Haijing LIU
IPC: H01M10/056 , H01M10/052
Abstract: An electrolyte membrane for a battery that cycles lithium ions includes a sulfide-based solid electrolyte, a polymer binder, an inorganic filler, an inorganic lithium salt, and an ionic liquid. The sulfide-based solid electrolyte includes lithium sulfide (Li2S) and at least one element selected from the group consisting of phosphorus (P), tin (Sn), silicon (Si), germanium (Ge), boron (B), gallium (Ga), and aluminum (Al). The ionic liquid includes substantially equimolar amounts of a cation and an anion. The cation includes a complex of lithium (Li+) and an ethylene glycol dimethyl ether, an imidazolium ion, a piperidinium ion, a pyrrolidinium ion, an ammonium ion, a phosphonium ion, or a combination thereof. The anion includes an arsenate ion, a phosphate ion, a sulfonylimide ion, a borate ion, a chlorate ion, or a combination thereof.
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公开(公告)号:US20240396077A1
公开(公告)日:2024-11-28
申请号:US18365365
申请日:2023-08-04
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhe LI , Qili SU , Yong LU , Dave G. RICH , Haijing LIU
IPC: H01M10/056
Abstract: A solid-state battery cell includes an anode electrode comprising an anode current collector, anode active material, a solid electrolyte, and a gel polymer electrolyte. A cathode electrode comprises a cathode current collector, a cathode active material, a solid electrolyte, and the gel polymer electrolyte. A separator layer comprises the gel polymer electrolyte and a solid electrolyte composite including a solid electrolyte coating arranged on an outer surface of an oxide core.
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34.
公开(公告)号:US20240113300A1
公开(公告)日:2024-04-04
申请号:US18070090
申请日:2022-11-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Yong LU , Meiyuan WU , Dewen KONG , Haijing LIU
IPC: H01M4/62 , C08L27/18 , H01M10/0525
CPC classification number: H01M4/623 , C08L27/18 , H01M10/0525 , C08L2207/53
Abstract: The present disclosure provides a modified binder for use in an electrochemical cell that cycles lithium ions. The modified binder includes one or more agglomerates of polytetrafluoroethylene nanoparticles, where each of the polytetrafluoroethylene nanoparticles includes a polytetrafluoroethylene core and a polymeric shell that is disposed on exposed surfaces of the core. The polymeric shell can include a polymer selected from the group consisting of: polyethylene oxide, polyglycidyl methacrylate, polyvinylidene difluoride, fluoride-hexafluoropropylene, polypropylene oxide, polyacrylonitrile, polymethacrylonitrile, polymethyl methacrylate, derivatives and co-polymers, and combinations thereof, and in certain instances, also a humidity tolerant lithium salt. The polytetrafluoroethylene core can have a first particle size ranging from about 10 nanometers to about 500 nanometers, the polymeric shell can have an average thickness ranging from about 10 nanometers to about 1,000 nanometers, and each of the one or more agglomerates can have an average size ranging from about 100 micrometers about 1,000 micrometers.
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公开(公告)号:US20240079699A1
公开(公告)日:2024-03-07
申请号:US18364203
申请日:2023-08-02
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhe LI , Meiyuan WU , Qili SU , Yong LU , Haijing LIU
IPC: H01M50/186 , H01M4/66 , H01M4/70 , H01M10/0585 , H01M50/112 , H01M50/148 , H01M50/174 , H01M50/193 , H01M50/198 , H01M50/30 , H01M50/548
CPC classification number: H01M50/186 , H01M4/661 , H01M4/667 , H01M4/70 , H01M10/0585 , H01M50/112 , H01M50/148 , H01M50/174 , H01M50/193 , H01M50/198 , H01M50/30 , H01M50/548 , H01M2004/029
Abstract: A bipolar battery includes N battery cores each comprising a cathode electrode, an anode electrode, and a separator, where N is an integer greater than one. N−1 bipolar plates include a first layer made of a first material, a second layer made of a second material, a center portion, and first and second sides extending transversely relative to the center portion. A battery enclosure including a cover and a lower portion including sides defining a cavity. The N−1 bipolar plates are arranged in the cavity between adjacent ones of the N battery cores and the N battery cores are connected in series by the N−1 bipolar plates. The first and second sides of the N−1 bipolar plates are one of inserted into “L”-shaped slots in the sides of the lower portion, and molded into the sides of the lower portion.
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公开(公告)号:US20240079655A1
公开(公告)日:2024-03-07
申请号:US17961804
申请日:2022-10-07
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Zhe LI , Meiyuan WU , Haijing LIU , Dave G. RICH
IPC: H01M10/0585 , H01M4/66 , H01M10/0562 , H01M10/0565 , H01M10/0566 , H01M50/148 , H01M50/172 , H01M50/186 , H01M50/193 , H01M50/30 , H01M50/417 , H01M50/431 , H01M50/449 , H01M50/533 , H01M50/534 , H01M50/548
CPC classification number: H01M10/0585 , H01M4/661 , H01M10/0562 , H01M10/0565 , H01M10/0566 , H01M50/148 , H01M50/172 , H01M50/186 , H01M50/193 , H01M50/30 , H01M50/417 , H01M50/431 , H01M50/449 , H01M50/533 , H01M50/534 , H01M50/548 , H01M2300/0025 , H01M2300/0071 , H01M2300/0082
Abstract: A bipolar solid-state battery includes N solid-state battery cells. Each of the N solid-state battery cells includes M solid-state cores each comprising a first current collector, cathode active material, a separator, anode active material, and a second current collector, where N and M are integers greater than one. The M solid-state cores are connected in parallel by connecting the first current collectors of the M solid-state cores in each of the N solid-state battery cells together and by connecting the second current collectors of the M solid-state cores in each of the N solid-state battery cells together. N−1 clad plates including a first side made of a first material and a second side made of a second material. The N−1 clad plates are arranged between adjacent ones of the N solid-state battery cells and the N solid-state battery cells are connected in series by the N−1 clad plates.
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公开(公告)号:US20230411687A1
公开(公告)日:2023-12-21
申请号:US17877011
申请日:2022-07-29
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Dewen KONG , Haijing LIU , Lidan XING
IPC: H01M10/0567 , H01M16/00 , H01G11/50 , H01G11/58
CPC classification number: H01M10/0567 , H01M16/00 , H01M2004/028 , H01G11/58 , H01M2300/0025 , H01G11/50
Abstract: A capacitor-assisted battery is provided. The capacitor-assisted battery includes an electrolyte system having a lithium-ion conducting component and one or more additives. The one or more additives include a first additive that includes 3-trimethylsilylphenylboronic acid, and a second additive that includes succinic anhydride. The capacitor-assisted battery includes an electrode having an electroactive material and a capacitor material. The electroactive material has a first coating defined thereon, and the capacitor material has a second coating defined thereon. The first and second coatings are defined by the first and second additives. The first coating is a substantially continuous that covers greater than or equal to about 80%, of a total exposed surface area of the electroactive material. The second coating is a discontinuous coating covers greater than or equal to about 20% to less than or equal to about 80% of a total exposed surface area of capacitor material.
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公开(公告)号:US20230268547A1
公开(公告)日:2023-08-24
申请号:US17828898
申请日:2022-05-31
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Zhe LI , Xiaochao QUE , Haijing LIU
IPC: H01M10/056 , H01M10/0525
CPC classification number: H01M10/056 , H01M10/0525 , H01M2220/20
Abstract: The present disclosure provides an electrochemical cell that cycles lithium ions, where the electrochemical cell includes an electrode, a solid-state electrolyte layer, and a solid-state interlayer disposed between the electrode and the solid-state electrolyte layer. The solid-state interlayer includes a plurality of solid-state electrolyte particles. In certain instances, the solid-state interlayer includes a plurality of through-holes dispersed therewithin. The through-holes have an average diameter between about 0.05 to about 100 micrometers. The solid-state interlay covers between about 50% and about 100% of a total surface area of the electrode. In each variation, solid-state interlayer has a thickness greater than or equal to about 0.1 to less than or equal to about 8 micrometers, and the electrochemical cell may include a polymeric gel electrolyte that at least partially fills voids between solid-state electroactive particle and solid-state electrolyte particles.
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公开(公告)号:US20230246310A1
公开(公告)日:2023-08-03
申请号:US17696567
申请日:2022-03-16
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Yong LU , Zhe LI , Mengyan HOU , Qili SU , Meiyuan WU , Xiaochao QUE , Haijing LIU , Si CHEN
IPC: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583
CPC classification number: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583 , H01M2300/0082 , H01M2004/029
Abstract: A high-power gel-assisted battery stack that cycles lithium ions is provided with two terminal electrodes having opposite polarities and at least one bipolar electrode assembly disposed therebetween. A first electrode is disposed on a first side of a bipolar current collector and a second electrode with an opposite polarity to the first electrode is disposed on a second side of the bipolar current collector. Each electrode includes a porous layer having an electroactive material and a solid-state electrolyte disposed in a polymeric binder. A polymer gel electrolyte is distributed in pores of the porous. The stack also includes at least two free-standing gel separator layers each being disposed between the at least one bipolar electrode assembly and terminal electrodes. Each respective free-standing gel separator layer comprises polyacrylonitrile (PAN) and an electrolyte distributed therein. The high-power gel-assisted battery stack has a maximum voltage rating of ≥about 12V.
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40.
公开(公告)号:US20230231110A1
公开(公告)日:2023-07-20
申请号:US17882876
申请日:2022-08-08
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Mengyan HOU , Haijing LIU , Xiaochao QUE , Meiyuan WU
IPC: H01M4/36 , H01M4/38 , H01M10/0525 , H01M4/62 , H01M4/04
CPC classification number: H01M4/366 , H01M4/386 , H01M10/0525 , H01M4/625 , H01M4/0471 , H01M4/0416 , H01M2004/027
Abstract: Negative electrodes for electrochemical cells that cycle lithium ions are provided. The negative electrodes comprise electroactive material particles that exhibit a core-shell structure defining a core made of a lithiated silicon-based material and a shell surrounding the core that is a bi-layer structure including first and second carbon coating layers. An electrical conductivity of the first carbon coating layer is greater than that of the second carbon coating layer. A method of manufacturing a negative electrode material is provided in which a first carbon coating layer is formed on an outer surface of a silicon-based precursor particle. The silicon-based precursor particle is exposed to a lithium source to form a lithiated silicon-based particle having the first carbon coating layer. A second carbon coating layer is formed on the first carbon coating layer over the lithiated silicon-based particle to form an electroactive material particle.
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