摘要:
The present invention is directed to novel urea group-containing polyisocyanates modified with long chain compounds having molecular weights of 400 to about 10,000. The present invention is also directed to a process for the preparation of modified urea group-containing polyisocyanates by reacting starting polyisocyanates which are free from urea groups with water to form urea groups in an inert reaction medium or in an aqueous mixture containing a dispersion stabilizer, wherein the starting polyisocyanates are mixed or reacted with long chain compounds having molecular weights of 400 to about 10,000 before the reacting the starting polyisocyanates with water and/or the long chain compounds are added to the inert reaction medium and/or to the water.
摘要:
Polyurethanes containing uretdione rings are produced by reacting a polyisocyanate containing a uretdione ring with a relatively high molecular weight dihydroxyl compound in the presence of a bismuth salt of an organic carboxylic acid and a low molecular weight aromatic diamine. The low molecular weight aromatic diamine is used in a quantity which is 5 to 10 times the quantity of bismuth salt used. These solid polyurethanes are formed in relatively short reaction times and possess outstanding mechanical properties.
摘要:
The present invention is directed to a process for the production of a thixotropic agent by reacting a polyisocyanate containing a uretdione group with a polybasic carboxylic acid containing at least one carboxyl group and, optionally, OH groups. The present invention is also directed to thixotropic high molecular weight polyols containing the above thixotropic agent. Finally, the present invention is directed to storable, reactive polyurethane systems comprising thixotropic polyols and polyisocyanates which are essentially unreactive with the polyols at room temperature.
摘要:
The present invention relates to cold setting compositions of (A) suspensions of solid polyisocyanates with retarded reactivity in aliphatic polyamines, and which are stable under storage due to a polyadduct covering, and (B) polyols and/or water. The activation of the composition is caused by the polyol or water. Additional activating materials can also be added for hardening. Such compositions, which already harden at ambient temperature, are stable under storage, have a long potlife for processing and, in relation to the potlife, have a very short hardening time to the final reaction product.
摘要:
The present invention relates to the use of thermosetting polyurethane urea reactive adhesive compositions which are stable at ambient temperature but rapidly set at higher temperatures, wherein the adhesive comprises stabilized finely-divided polyisocyanates of retarded reactivity of which 0.1 to 25% of the NCO-groups are surface-modified and higher and/or lower molecular polyamines (optionally with polyols as additional reactive components). An important feature of these thermosetting reactive adhesive compositions is their capacity for storage at ambient temperature and their spontaneous increase in viscosity at relatively low heating temperatures which prevents the adhesive from running off during the heating period when applied to vertical surfaces.
摘要:
Aromatic uret dione diurea diamines corresponding to the formula ##STR1## in which X, Y, m and n are as defined herein are produced by reacting an aromatic diamine with a diisocyanate corresponding to a specified formula in a molar ratio of diamine to diisocyanate of at least 1.8 to 1. These diamines are particularly useful in the production of elastomers.
摘要:
Low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates corresponding to the formula: ##STR1## wherein n is a number from 0 to 1,are made by dimerizing diphenylmethane-4,4'-diisocyanate at a temperature of 50.degree. C. or less in a mixture of non-polar and moderately polar solvents in the presence of a dimerization catalyst. The dimerization product may then be worked up at low temperatures (i.e., .ltoreq.50.degree. C.). The dimerization products of diphenylmethane-diisocyanate thus obtained generally have only a small amount of oligomeric uretdione-diisocyanates present. These dimerization products may be used advantageously in the synthesis of polyurethanes.
摘要:
Diisocyanates corresponding to the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 (an isocyanate-containing radical) are as defined herein are made by several processes. These diisocyanates may be made by phosgenating the diamine in which the diisocyanate is based. They may also be produced by treating the bis-urethane of the tertiary alcohol corresponding to the diisocyanate with phosgene. Such diisocyanates may also be made by treating a specific type of bis-urea with hydrogen chloride. The diisocyanates corresponding to the above-given formula are particularly useful in the production of polyurethanes having good flame-proof and mechanical properties.
摘要:
This invention relates to a process for the production of polyurethanes, particularly polyurethane foam moldings having a compact skin and a cellular core, using special tin activators.
摘要:
Polyurethane urea elastomers are produced by reacting polyisocyanates with compounds containing at least two isocyanate reactive hydrogen atoms having a molecular weight of 400 to 10,000 and mononuclear or dinuclear aromatic diamines. The aromatic diamines must have at least one sulfonamide group as a substituent on at least one of their aromatic rings. Known chain lengthening agents, activators, blowing agents, auxiliary agents and additives may also be included in the reaction mixture.Polyurethane elastomers produced by this process have excellent mechanical properties. In particular, such elastomers are soft yet have high tear propagation resistance.