6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides
    34.
    发明授权
    6-Substituted 2,4-diamino-1,3,5-triazine derivatives having at least two asymmetrically substituted carbon atoms, the production thereof, and their use as herbicides 失效
    具有至少两个不对称取代的碳原子的6-取代的2,4-二氨基-1,3,5-三嗪衍生物,其制备及其作为除草剂的用途

    公开(公告)号:US06358886B1

    公开(公告)日:2002-03-19

    申请号:US09623612

    申请日:2000-11-03

    IPC分类号: C07D25118

    摘要: The invention relates to novel substituted optically active aminotriazines having at least two asymmetrically substituted carbon atoms of the formula (I), in which A represents a single bond or represents in each case straight-chain or branched alkanediyl or oxaalkanediyl having in each case up to 6 carbon atoms, Z represents certain carbocyclic or heterocyclic radicals and the substituents R1, R2, R3, R4 and Y are as defined in the description,  with the proviso that in each individual case R2, R3 and Y are different from one another and that the substituents at the two carbon atoms to which R2 and R3 or R4 are attached are configured as follows: (a) R configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“R,R-diastereomers”), (b) R configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“R,S-diastereomers”), (c) S configuration at the carbon atom to which R2 and R3 are attached and R configuration at the carbon atom to which R4 is attached (“S,R-diastereomers”), (d) S configuration at the carbon atom to which R2 and R3 are attached and S configuration at the carbon atom to which R4 is attached (“S,S-diastereomers”), (e) R configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“R,racdiastereomers”), (f) S configuration at the carbon atom to which R2 and R3 are attached and racemic configuration at the carbon atom to which R4 is attached (“S,rac-diastereomers”), and to a process for preparing the compounds of the formula (I) and to their use as herbicides.

    摘要翻译: 本发明涉及具有式(I)的至少两个不对称取代的碳原子的新的取代的光学活性氨基三嗪,其中A表示单键或表示在每种情况下为直链或支链烷二基或氧杂烷二基,在每种情况下最多为6 碳原子,Z表示某些碳环或杂环基团,并且取代基R 1,R 2,R 3,R 4和Y如说明书中所定义,条件是在各个别情况下,R 2,R 3和Y彼此不同, R2和R3或R4连接的两个碳原子上的取代基配置如下:(a)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的R构型(“ R,R非对映异构体“),(b)R 2和R 3连接的碳原子上的R构型,R 4连接的碳原子上的S构型(”R,S-非对映异构体“),(c)S 配置在碳ato m与R 2相连的碳原子上的R构型(“S,R-非对映异构体”),(d)在R2和R3所连接的碳原子上的S构型, R 4连接的碳原子(“S,S-非对映异构体”),(e)R 2和R 3所连接的碳原子上的R构型,R 4连接的碳原子上的外消旋构型(“R” 外消旋异构体“),(f)R 2和R 3所连接的碳原子上的S构型以及与R4连接的碳原子上的外消旋构型(”S,外消旋 - 非对映体“),以及制备该化合物的方法 的式(I)和它们作为除草剂的用途。

    Substituted phenyluracils and their use as herbicides
    37.
    发明授权
    Substituted phenyluracils and their use as herbicides 失效
    取代苯尿嘧啶及其作为除草剂的用途

    公开(公告)号:US06815398B1

    公开(公告)日:2004-11-09

    申请号:US10129632

    申请日:2002-05-07

    IPC分类号: C07D23954

    摘要: Novel substituted phenyluracils of the general formula (I) in which n represents 0, 1 or 2, R1 represents hydrogen, amino or optionally substituted alkyl, R2 represents carboxyl, cyano, carbamoyl, thiocarbamoyl or in each case optionally substituted alkyl or alkoxycarbonyl, X represents hydroxyl, mercapto, amino, nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, dialkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylcarbonyloxy, alkoxycarbonyloxy, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, phenylcarbonyloxy, alkylcarbonylamino, alkoxycarbonylamino, alkylsulphonylamino, alkenyl, alkenyloxy, alkenyloxycarbonyl, alkinyl, alkinyloxy or alkinyloxycarbonyl, where in the case that n is greater than 1, X in the individual possible compounds may also have meanings other than those given.

    摘要翻译: 通式(I)的新型取代的苯基尿嘧啶,其中n代表0,1或2,R 1表示氢,氨基或任选取代的烷基,R 2表示羧基,氰基,氨基甲酰基,硫代氨基甲酰基,或在每种情况下任选取代 烷基或烷氧基羰基,X表示羟基,巯基,氨基,硝基,氰基,羧基,氨基甲酰基,硫代氨基甲酰基,卤素,或在每种情况下表示任选取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基氨基,二烷基氨基,烷基羰基,烷氧基羰基,烷基氨基羰基 二烷基氨基羰基,烷基羰基氧基,烷氧基羰基氧基,烷基氨基羰基氧基,二烷基氨基羰基氧基,苯基羰基氧基,烷基羰基氨基,烷氧基羰基氨基,烷基磺酰基氨基,烯基,烯氧基,烯氧基羰基,炔基,烷氧基或烷氧基羰基,其中在n大于1的情况下, 具有不同于给定的含义。