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    Olefin polymers prepared with substituted indenyl containing metal complexes
    37.
    发明授权
    Olefin polymers prepared with substituted indenyl containing metal complexes 失效
    用含有取代茚基的金属络合物制备的烯烃聚合物

    公开(公告)号：US06420507B1

    公开(公告)日：2002-07-16

    申请号：US09070957

    申请日：1998-05-01

    申请人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    发明人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    IPC分类号： C08F1000

    CPC分类号： C08F210/18 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/19 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/20

    摘要： The subject invention is directed to an olefin polymer produced by polymerizing at least one &agr;-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utility in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.

    摘要翻译： 本发明涉及通过在包含在2或3位被取代的茚基的第4族金属络合物与至少一种选自烃基，全氟取代基的基团的存在下聚合至少一种α-烯烃制备的烯烃聚合物 烃基，甲硅烷基，甲基和其混合物，所述茚基还通过二价配体基团与金属共价结合，其中二价配体包含具有通过伯或仲二价共价键合的脂族或脂环族烃基的氮或磷 碳。 本发明优选的烯烃聚合物的特征在于具有高分子量，窄分子量分布，高乙烯基含量和双峰DSC熔解曲线或解卷积的ATREF或GPC曲线，其显示出至少两个不同的窄峰。 烯烃聚合物可用于各种应用，包括但不限于薄膜，纤维，泡沫，模制部件，以及作为配方的组分，例如粘合剂，密封剂，涂料，填缝剂和沥青。

    Zwitterionic catalyst activator
    38.
    发明授权
    Zwitterionic catalyst activator 有权
    两性离子催化剂活化剂

    公开(公告)号：US06344529B1

    公开(公告)日：2002-02-05

    申请号：US09445209

    申请日：1999-12-06

    申请人： Edmund M. Carnahan ,  Grant B. Jacobsen ,  Jerzy Klosin ,  Peter N. Nickias ,  David J. Schwartz ,  David R. Neithamer

    发明人： Edmund M. Carnahan ,  Grant B. Jacobsen ,  Jerzy Klosin ,  Peter N. Nickias ,  David J. Schwartz ,  David R. Neithamer

    IPC分类号： C08F452

    CPC分类号： C07F5/066 ,  C07F5/00 ,  C07F5/027 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  C08F4/65908

    摘要： Disclosed are compounds useful as catalyst activators for olefin polymerization, comprising structures of the following formulae: wherein: L+ is a protonated derivative of an element of Group 15 of the Periodic Table of the Elements, additionally bearing two hydrocarbyl substituents of from 1 to 50 carbons each, or a positively charged derivative of an element of Group 14 of the Periodic Table of the Elements, said Group 14 element being substituted with three hydrocarbyl substituents of from 1 to 50 carbons each; R1 is a divalent linking group of from 1 to 40 non-hydrogen atoms; R2 independently each occurrence is a ligand group of from 1 to 50 nonhydrogen atoms with the proviso that in a sufficient number of occurrences to balance charge in the compound, R2 is L+—R1—; M1 is boron, aluminum or gallium; Arf independently each occurrence is a monovalent, fluorinated organic group containing from 6 to 100 non-hydrogen atoms; Y is a Group 15 element; and Z is a Group 14 element.

    摘要翻译： 公开了可用作烯烃聚合的催化剂活化剂的化合物，其包含下式的结构：其中：L +是元素周期表第15族元素的质子化衍生物，另外带有1至50个碳的烃基取代基 每个元素或元素周期表第14族元素的带正电荷的衍生物，所述第14族元素被各自为1至50个碳的三个烃基取代基取代; R 1为1至40的二价连接基团 非氢原子; R2各自独立地为1至50个非氢原子的配体基团，条件是在足够数量的化合物中平衡电荷的情况下，R2为L + -R1-; M1为硼，铝或 镓; Arf各自独立地为含有6至100个非氢原子的单价氟化有机基团; Y为第15族元素; 而Z是第14组元素。