公开(公告)号：US07291406B2

公开(公告)日：2007-11-06

申请号：US11233605

申请日：2005-09-22

Applicant: Mark E. Thompson ,  Peter Djurovic ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

Inventor： Mark E. Thompson ,  Peter Djurovic ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC: H01L51/54

CPC classification number: H01L51/0085 ,  C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917

Abstract: Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

Abstract translation: 描述了有机发光器件，其中发射层包含含有发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光有机金属络合物，包括环金属化 铂，铱和锇络合物。 有机发光器件任选地包含激子阻挡层。 此外，通过具有式L 2 MX的过渡金属的有机金属络合物的发射极层获得有机发光器件中的电致发光效率的提高，其中L和X是不同的二齿配位体。 该配方的化合物可以比先前的方法更容易合成，并且合成选项允许将荧光分子插入磷光复合物，配体以微调发光的颜色，以及配体捕获载体。

公开(公告)号：US07285907B2

公开(公告)日：2007-10-23

申请号：US11211385

申请日：2005-08-24

Applicant: Brian D'Andrade ,  Mark E. Thompson ,  Stephen R. Forrest

Inventor： Brian D'Andrade ,  Mark E. Thompson ,  Stephen R. Forrest

IPC: H01L51/50 ,  H01L51/54 ,  H05B33/14

CPC classification number: C09K11/06 ,  C09K2211/1029 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/5016 ,  H01L51/5036 ,  H01L51/5088 ,  H01L51/5096 ,  Y10S428/917 ,  Y10T428/24942

Abstract: The present invention relates to efficient organic light emitting devices (OLEDs) doped with multiple light-emitting dopants, at least one dopant comprising a phosphorescent emitter, in a thin film emissive layer or layers. The present invention is directed to an efficient phosphorescent organic light emitting device utilizing a plurality of emissive dopants in an emissive region, wherein at least one of the dopants is a phosphorescent material. Thus, the present invention provides an organic light emitting device comprising an emissive region, wherein the emissive region comprises a host material, and a plurality of emissive dopants, wherein the emissive region is comprised of a plurality of bands and each emissive dopant is doped into a separate band within the emissive region, and wherein at least one of the emissive dopants emits light by phosphorescence.

Abstract translation: 本发明涉及掺杂有多个发光掺杂剂的有效的有机发光器件（OLED），至少一种包含磷光发射体的掺杂剂在薄膜发射层或多层中。 本发明涉及在发射区域中利用多个发射掺杂剂的有效磷光有机发光器件，其中至少一种掺杂剂是磷光材料。 因此，本发明提供了一种包括发射区域的有机发光器件，其中发射区域包括主体材料和多个发射掺杂剂，其中发射区域由多个带组成，并且每个发光掺杂剂被掺杂到 发射区域内的单独的带，并且其中至少一个发射掺杂剂通过磷光发光。

公开(公告)号：US07173369B2

公开(公告)日：2007-02-06

申请号：US10460024

申请日：2003-06-11

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

IPC: H01L51/50 ,  H05B33/26 ,  H05B33/00

CPC classification number: H01L51/5234 ,  C09K11/06 ,  H01L27/156 ,  H01L27/3209 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0042 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/5048 ,  H01L51/5243 ,  H01L51/5246 ,  H01L51/5253 ,  H01L2224/24145 ,  H01L2251/5323 ,  H01L2924/01021 ,  H01L2924/01068 ,  H01L2924/12041 ,  H01L2924/12044 ,  H01L2924/00

Abstract: An organic light emitting device structure includes a substrate, a first electrically conductive layer formed over the substrate wherein the first electrically conductive layer has a positive polarity, and a transparent organic light emitting device formed over the first electrically conductive layer. The structure also includes a transparent electrically conductive metal layer formed over the transparent organic light emitting device wherein the metal has a work function less than 4 eV, and a second electrically conductive layer formed over the transparent electrically conductive metal layer, wherein the second electrically conductive layer has a negative polarity, and wherein the second electrically conductive layer comprises a material selected from the group consisting of a transparent electrically conductive oxide and a transparent electrically conductive polymer.

Abstract translation: 有机发光器件结构包括：衬底，形成在衬底上的第一导电层，其中第一导电层具有正极性;以及透明有机发光器件，形成在第一导电层上。 该结构还包括在透明有机发光器件上形成的透明导电金属层，其中金属具有小于4eV的功函数，以及形成在透明导电金属层上的第二导电层，其中第二导电 层具有负极性，并且其中第二导电层包括选自透明导电氧化物和透明导电聚合物的材料。

公开(公告)号：US07022421B2

公开(公告)日：2006-04-04

申请号：US10226674

申请日：2002-08-23

Applicant: Mark E. Thompson ,  Xiaofan Ren ,  Vadim Adamovich ,  Steven Cordero ,  Brian Wendell D'Andrade ,  Bert Alleyne ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Xiaofan Ren ,  Vadim Adamovich ,  Steven Cordero ,  Brian Wendell D'Andrade ,  Bert Alleyne ,  Stephen R. Forrest

IPC: H05B33/12

CPC classification number: H01L51/5096 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/005 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/0082 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5048 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Light emitting devices having blocking layers comprising one or more metal complexes are provided. The blocking layers may serve to block electrons, holes, and/or excitons. Preferably, the devices further comprise a separate emissive layer in which charge and/or excitons are confined. Metal complexes suitable for blocking layers can be selected by comparison of HOMO and LUMO energy levels of materials comprising adjacent layers in devices of the present invention.

公开(公告)号：US06902830B2

公开(公告)日：2005-06-07

申请号：US10171235

申请日：2002-06-13

Applicant: Mark E. Thompson ,  Peter Djurovic ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

Inventor： Mark E. Thompson ,  Peter Djurovic ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC: C07D209/86 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14

CPC classification number: C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

Abstract: Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

Abstract translation: 描述了有机发光器件，其中发射层包含含有发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光有机金属络合物，包括环金属化 铂，铱和锇络合物。 有机发光器件任选地包含激子阻挡层。 此外，通过具有式L 2 MX的过渡金属的有机金属络合物的发射极层获得有机发光器件中的电致发光效率的提高，其中L和X是不同的二齿配位体。 该配方的化合物可以比先前的方法更容易合成，并且合成选项允许将荧光分子插入磷光复合物，配体以微调发光的颜色，以及配体捕获载体。

公开(公告)号：US06894307B2

公开(公告)日：2005-05-17

申请号：US10355316

申请日：2003-01-31

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Marc A. Baldo

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Marc A. Baldo

IPC: C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50

CPC classification number: H01L51/5096 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0088 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5028 ,  H01L2251/308

Abstract: Organic light emitting devices are described wherein the emissive layer comprises a host material containing a fluorescent or phosphorescent emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, wherein an intersystem crossing molecule of optical absorption spectrum matched to the emission spectrum of the emissive molecule enhances emission efficiency.

Abstract translation: 描述了有机发光器件，其中发射层包括含有荧光或磷光发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，其中光学吸收光谱的跨系统交叉分子与发射 发射分子的光谱提高了发射效率。

公开(公告)号：US06596134B2

公开(公告)日：2003-07-22

申请号：US09468986

申请日：1999-12-21

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

IPC: C23C1400

CPC classification number: H01L51/5234 ,  C09K11/06 ,  H01L27/156 ,  H01L27/3209 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0042 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/5048 ,  H01L51/5243 ,  H01L51/5246 ,  H01L51/5253 ,  H01L2224/24145 ,  H01L2251/5323 ,  H01L2924/01021 ,  H01L2924/01068 ,  H01L2924/12041 ,  H01L2924/12044 ,  H01L2924/00

Abstract: A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias. The devices are substantially transparent when de-energized, making them useful for heads-up display applications.

Abstract translation: 多色有机发光器件采用由有机化合物制成的双异质结构器件的垂直层叠层。 垂直堆叠结构形成在具有ITO或类似金属的透明涂层的玻璃基底上以提供基底。 沉积在衬底上的是三个双异质结构器件的垂直堆叠布置，每个由异质结构器件制成，每个由合适的有机材料制成。 实施堆叠，使得具有最长波长的双异质结构位于堆叠的顶部。 这构成在顶部发射红光的装置，其中装置具有最短波长，即发射蓝光的装置，在堆叠的底部。 位于红色和蓝色的设备结构之间是绿色设备结构。 这些器件被配置为堆叠以提供阶梯轮廓，由此每个器件通过薄的透明导电接触层与另一个分离，以使来自每个器件的光能够透过半透明触点并通过下部器件结构，同时进一步启用 每个设备接收选择性偏差。 当断电时，这些器件基本上是透明的，使得它们对于平视显示器应用是有用的。

公开(公告)号：US06548956B2

公开(公告)日：2003-04-15

申请号：US09726482

申请日：2000-12-01

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

IPC: H01J162

CPC classification number: H01L27/3209 ,  C09K11/06 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0042 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/5048 ,  H01L51/5234 ,  H01L51/5253 ,  H01L2251/5323

Abstract: A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias. The devices are substantially transparent when de-energized, making them useful for heads-up display applications.

Abstract translation: 多色有机发光器件采用由有机化合物制成的双异质结构器件的垂直层叠层。 垂直堆叠结构形成在具有ITO或类似金属的透明涂层的玻璃基底上以提供基底。 沉积在衬底上的是三个双异质结构器件的垂直堆叠布置，每个由异质结构器件制成，每个由合适的有机材料制成。 实施堆叠，使得具有最长波长的双异质结构位于堆叠的顶部。 这构成在顶部发射红光的装置，其中装置具有最短波长，即发射蓝光的装置，在堆叠的底部。 位于红色和蓝色的设备结构之间是绿色设备结构。 这些器件被配置为堆叠以提供阶梯轮廓，由此每个器件通过薄的透明导电接触层与另一个分离，以使来自每个器件的光能够透过半透明触点并通过下部器件结构，同时进一步启用 每个设备接收选择性偏差。 当断电时，这些器件基本上是透明的，使得它们对于平视显示器应用是有用的。

公开(公告)号：US5986401A

公开(公告)日：1999-11-16

申请号：US821380

申请日：1997-03-20

Applicant: Mark E. Thompson ,  Stephen R. Forrest ,  Paul Burrows

Inventor： Mark E. Thompson ,  Stephen R. Forrest ,  Paul Burrows

IPC: H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H01L51/52 ,  H01J1/62

CPC classification number: H01L51/5284 ,  B82Y10/00 ,  H01L2251/5315 ,  H01L2251/5323 ,  H01L51/5206 ,  H01L51/5281

Abstract: A high contrast organic light emitting device (OLED) display utilizing a transparent (TOLED) display structure with a low-reflectance absorber arranged behind the display. The TOLED display allows substantially all light incident on the display to pass through the display and to be absorbed by the low-reflectance absorber With the amount of light reflected by the display thus substantially reduced, the contrast of images displayed by the display is thus improved.

Abstract translation: 利用布置在显示器背后的具有低反射率吸收体的透明（TOLED）显示结构的高对比度有机发光器件（OLED）显示器。 TOLED显示器允许入射到显示器上的基本上所有的光通过显示器并被低反射率吸收体吸收。由于显示器反射的光量大大降低，因此改善了由显示器显示的图像的对比度 。

公开(公告)号：US10074820B2

公开(公告)日：2018-09-11

申请号：US14429929

申请日：2013-09-26

Applicant: Stephen R. Forrest ,  Mark E. Thompson

Inventor： Stephen R. Forrest ,  Mark E. Thompson

IPC: H01L51/42

CPC classification number: H01L51/422 ,  H01L31/02322 ,  H01L31/055 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/0087 ,  H01L51/4213 ,  Y02E10/52 ,  Y02E10/549

Abstract: The present disclosure relates to a photosensitive optoelectronic device comprising two electrodes, an inorganic subcell positioned between the two electrodes, wherein the inorganic subcell comprises at least one inorganic semiconductor material having a band gap energy (EG), and an organic sensitizing window layer disposed on the inorganic subcell. In one aspect, the organic sensitizing window layer comprises a singlet fission material. In another aspect, the organic sensitizing window layer comprises a singlet fission host and a phosphorescent emitter dopant, where the singlet fission host exhibits an excitation triplet energy (ET-SF) greater than or equal to an excitation triplet energy (ET-PE) exhibited by the phosphorescent emitter dopant.