摘要:
A methanol oxidation catalyst comprises a material of composition: PtxMzTau in which Pt is platinum, Ta is tantalum, M is an element includes at least one selected from the group consisting of V (vanadium), W (tungsten), Ni (nickel) and Mo (molybdenum), x is 40 to 98 at. %, z is 1.5 to 55 at. %, and u is 0.5 to 40 at. %. To maximize catalytic activity the material is preferably in the form of nanoparticles. The values of x, z and u are selected such that the element exhibits X-ray photoelectron spectroscopy peaks derived from an oxygen bond and a metal bond in which a peak area derived from the oxygen bond is twice or less of a peak area derived from the metal bond.
摘要:
A proton conductive inorganic material includes oxide particles containing at least one element X selected from the group consisting of W, Mo, Cr, B and V, an oxide carrier carrying the oxide particles and containing at least one element Y selected from the group consisting of Sn, Hf, Ge, Ga, In, Ce and Nb.
摘要:
A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula 1: PtxRuyTzQu formula 1 In the formula 1, the T-element is at least one selected from a group consisting of Mo, W and V and the Q-element is at least one selected from a group consisting of Nb, Cr, Zr and Ti, x is 40 to 90 at. %, y is 0 to 9.9 at. %, z is 3 to 70 at. % and u is 0.5 to 40 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.
摘要:
This invention provides a fuel cell catalyst material containing catalyst particles having a composition substantially represented by ATxNu (1) wherein A contains Pt or Pt and at least one noble metal element selected from the group consisting of Ru, Pd, Au, and Ag, T contains at least one element selected from the group consisting of Fe, Co, Ni, Sn, Mn, Cr, V, Ti, Mo, Nb, Zr, W, Ta, and Hf, and atomic ratios x and u fall within the ranges 0≦x≦4 and 0.005≦u≦1, respectively.
摘要:
The present invention provides a supported catalyst excellent both in catalytic performance and in stability against concentrated methanol. The supported catalyst is used for an electrode of a fuel cell, and comprises catalytic metal particles supported on supports. The supports have hydrophilicity. On at least one part of the surface of the hydrophilic supports, particles of metal oxide super-strong acid are also supported. The metal oxide super-strong acid particles promote proton conduction.
摘要:
A sputtering apparatus includes: a supporting member that accommodates a base material; a first sputtering source containing platinum and having a rectangular shape; a second sputtering source containing an element different from that contained in the first sputtering source; a first magnet that is disposed to face the supporting member, the first magnet applying a first magnetic field near a surface of the first sputtering source in a first magnetic flux density; and a second magnet that is disposed to face the supporting member, the second magnet applying a second magnetic field near a surface of the second sputtering source in a second magnetic flux density, wherein at least one of the first magnetic flux density and the second magnetic flux density is configured to be variable.
摘要:
This invention provides a process for producing a membrane electrode assembly which has high and stable catalytic activity, and suppressed deterioration in catalytic activity during operation, and can prevent a deterioration in performance attributable to a structural factor of the membrane electrode assembly. The process comprises the step of, after the washing/removing step, drying the catalyst electrode in an atmosphere having a lower oxygen partial pressure than the air. The anode/cathode is a covered catalyst electrode having a structure formed by supporting/depositing a catalytically active material composed mainly of platinum/ruthenium subjected to the potential holding step, the washing/removing step, and the drying step, on a porous electroconductive carrier to cover at least a part of the porous electroconductive carrier with the ion conductive material.
摘要:
A method is for causing, within a decompression device, a particulate base material to carry an alloy particle having a particle size smaller than that of the particulate base material, the alloy particle containing at least two elements, the method including: forming the particulate base material by a chemical deposition; causing, in the decompression device, the particulate base material to carry a microparticle element; and forming the alloy particle by alloying the particulate base material and the microparticle element.
摘要:
There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.
摘要翻译:提供了一种用于燃料电池的催化剂,其同时实现优异的催化活性和催化稳定性。 用于燃料电池的催化剂包括由下式表示的金属微粒:<?in-line-formula description =“In-line Formulas”end =“lead”?> Pt “in-line-formula description =”In-line Formulas“end =”tail“?>其中,T1表示(x,y,y,y) 选自镍(Ni),钨(W),钒(V)和钼(Mo))中的至少一种元素。 x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% 并且u = 0.5〜40原子%,或者包含由式表示的金属的微粒:<?in-line-formula description =“In-line Formulas”end =“lead”?> Pt β-in-line-formula description =“In-line Formulas”end =“tail”?????? 其中,T2表示选自铪(Hf),锡(Sn),锆(Zr),铌(Nb),钛(Ti),钽(Ta),铬(Cr) 铝(Al); x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% u = 0.5〜40原子%。
摘要:
A solid electrolyte membrane includes: a porous material layer and an inorganic material layer. The porous material layer has a through-hole that is filled with an electrolyte. The inorganic material layer is provided so as to face to at least either side of a principal surface of the porous material layer and has an opening that is filled with an electrolyte. A solid electrolyte membrane alternatively includes: a first porous layer and a second porous layer. The first porous layer has a through-hole that is filled with an electrolyte. The second porous layer is provided so as to face to at least either side of a principal surface of the first porous layer and has an opening that is filled with an electrolyte. The average diameter of the opening is smaller than the average diameter of the through-hole.