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31.发明授权Methods and apparatuses for producing aromatic hydrocarbon-rich effluent from lignocellulosic material 有权从木质纤维素材料生产富含芳烃的流出物的方法和装置公开(公告)号：US08754275B2
公开(公告)日：2014-06-17
申请号：US13191211
申请日：2011-07-26
申请人： Timothy A. Brandvold , Mark Koch
发明人： Timothy A. Brandvold , Mark Koch
IPC分类号： C10G1/00
CPC分类号： C10G1/065 , B01J8/22 , B01J21/12 , B01J23/888 , B01J37/20 , B01J2208/00283 , C10G1/083 , C10G1/086 , C10G2300/1014 , C10G2300/1096 , C10G2300/44 , C10G2400/30 , Y02P30/20
摘要： Embodiments of methods and apparatuses for producing and aromatic hydrocarbon-rich effluent from a lignocellulosic material are provided herein. The method comprises the step of combining the lignocellulosic material and an aromatic hydrocarbon-rich diluent to form a slurry. Hydrogen in the presence of a catalyst is contacted with the slurry at reaction conditions to form the aromatic hydrocarbon-rich effluent.
摘要翻译： 本文提供了用于生产木质纤维素材料的富含芳烃的流出物的方法和装置的实施方案。 该方法包括将木质纤维素材料和富含芳烃的稀释剂混合以形成浆料的步骤。 在催化剂存在下的氢气在反应条件下与浆料接触以形成富含芳烃的流出物。
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公开(公告)号：US20130152454A1
公开(公告)日：2013-06-20
申请号：US13326050
申请日：2011-12-14
CPC分类号： C10G3/42 , C10G3/45 , C10G3/50 , C10G2300/1011 , C10G2300/4006 , C10G2300/4081 , Y02E50/10 , Y02E50/14 , Y02P30/20
摘要： Methods for deoxygenating a biomass-derived pyrolysis oil are provided. In an embodiment, a method for deoxygenating a biomass-derived pyrolysis oil comprises the steps of combining a biomass-derived pyrolysis oil stream with a heated low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream has a feed temperature of about 150° C. or greater. The heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.
摘要翻译： 提供了用于脱氧生物质的热解油的方法。 在一个实施方案中，用于使生物质衍生的热解油脱氧的方法包括以下步骤：将生物质衍生的热解油流与加热的低氧 - 稀土稀释剂再循环流组合以形成加热的稀释的原料流。 加热的稀释的原料流具有约150℃或更高的进料温度。 在有效形成低氧生物质衍生的裂解油流出物的第一加氢处理条件下，将加热的稀释的原料流与第一脱氧催化剂在氢的存在下接触。
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33.发明授权Production of blended gasoline aviation and diesel fuels from renewable feedstocks 有权从可再生原料生产混合汽油航空和柴油燃料公开(公告)号：US08329968B2
公开(公告)日：2012-12-11
申请号：US12418971
申请日：2009-04-06
CPC分类号： C10L1/06 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/52 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/42 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , Y02P30/20
摘要： A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.
摘要翻译： 提出了一种从富含链烷烃的组分和富含氟的组分制备至少一种混合燃料的方法，其中每种组分由可再生原料生成。 富含石蜡的组分由原料如植物油和动物油中的甘油酯和游离脂肪酸产生。 循环富成分由生物质衍生的热解油产生。 动物或植物油和生物质的来源可能是相同的可再生能源。
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34.发明申请METHODS FOR PRODUCING PHASE STABLE, REDUCED ACID BIOMASS-DERIVED PYROLYSIS OILS 审中-公开生产相稳定，降低酸的生物质衍生的热解油的方法公开(公告)号：US20120023809A1
公开(公告)日：2012-02-02
申请号：US12845519
申请日：2010-07-28
申请人： Mark B. Koch , Timothy A. Brandvold
发明人： Mark B. Koch , Timothy A. Brandvold
IPC分类号： C10L1/10
摘要： Methods for producing phase stable, reduced acid biomass-derived pyrolysis oils are provided. Biomass-derived pyrolysis oil having a determined water content no greater than about 30% by weight is provided. A base is mixed with the biomass-derived pyrolysis oil to produce reduced acid biomass-derived pyrolysis oil. A base is selected from an inorganic base or a nitrogen-containing base.
摘要翻译： 提供了生产相稳定，减少的酸生物质衍生的热解油的方法。 提供具有不超过约30重量％的测定水含量的生物质衍生的热解油。 将碱与生物质衍生的热解油混合以产生降低的酸生物质衍生的热解油。 碱选自无机碱或含氮碱。
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公开(公告)号：US20120017494A1
公开(公告)日：2012-01-26
申请号：US12843668
申请日：2010-07-26
IPC分类号： C10L1/19
摘要： Processes for producing a low acid biomass-derived pyrolysis oil are provided that include pre-treating a biomass-derived pyrolysis oil to form a treated acid-containing biomass-derived pyrolysis oil. The processes also include esterifying the treated acid-containing biomass-derived pyrolysis oil in the presence of supercritical alcohol and a catalyst composition to form the low-acid biomass-derived pyrolysis oil, the catalyst composition comprising a material selected from the group consisting of an unsupported solid acid catalyst, an unsupported solid base catalyst, and a catalytic metal dispersed on a metal oxide support.
摘要翻译： 提供了用于生产低酸生物质衍生的热解油的方法，其包括预处理生物质衍生的热解油以形成经处理的含酸生物质衍生的热解油。 该方法还包括在超临界醇和催化剂组合物的存在下酯化经处理的含酸生物质衍生的热解油，以形成低酸生物质衍生的热解油，所述催化剂组合物包含选自以下的材料： 未负载的固体酸催化剂，未负载的固体碱催化剂和分散在金属氧化物载体上的催化金属。
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36.发明申请公开(公告)号：US20110146135A1
公开(公告)日：2011-06-23
申请号：US12646239
申请日：2009-12-23
申请人： Timothy A. Brandvold
发明人： Timothy A. Brandvold
IPC分类号： C10L1/00
CPC分类号： C07C7/12 , B01J39/05 , B01J49/60 , C10G25/02 , C10G2300/1011 , C10G2300/205 , C10G2300/4018 , C10G2300/44 , Y02E50/32 , Y02P30/20
摘要： Low metal biomass-derived pyrolysis oils and processes for producing the same are provided. Low metal biomass-derived pyrolysis oil is produced by a process of contacting metal-containing biomass-derived pyrolysis oil with an acidic ion-exchange resin having sulfonic acid groups. Low metal biomass-derived pyrolysis oil is removed from spent acidic ion-exchange resin after ion-exchange.
摘要翻译： 提供了低金属生物质衍生的热解油及其制备方法。 通过使含金属的生物质衍生的热解油与具有磺酸基的酸性离子交换树脂接触的方法制备低金属生物质衍生的热解油。 离子交换后从废酸性离子交换树脂中除去低金属生物质衍生的裂解油。
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公开(公告)号：US20100076238A1
公开(公告)日：2010-03-25
申请号：US12624999
申请日：2009-11-24
CPC分类号： C10L1/08 , C10G3/46 , C10G3/50 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/28 , C10L1/06 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for producing a fuel or fuel blending component from co-processing at least two different classes of renewable feedstocks, is presented. One feedstock comprises glycerides and free fatty acids in feedstocks such as plant and animal oils while the other feedstock comprises biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.
摘要翻译： 提出了一种从共同处理至少两种不同类别的可再生原料生产燃料或燃料调和组分的方法。 一种原料在原料如植物油和动物油中包含甘油酯和游离脂肪酸，而另一种原料包括生物质衍生的热解油。 动物或植物油和生物质的来源可能是相同的可再生能源。
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公开(公告)号：US20090287029A1
公开(公告)日：2009-11-19
申请号：US12402873
申请日：2009-03-12
IPC分类号： C10G3/00
CPC分类号： C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译： 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物，在预定条件下异构化和选择性氢化至少一部分链烷烃，并通过在预定分馏条件下分级分离以产生柴油范围烃产物和 航空范围烃产品。
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公开(公告)号：US20090283442A1
公开(公告)日：2009-11-19
申请号：US12402078
申请日：2009-03-11
申请人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
发明人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
CPC分类号： C10G3/47 , C10G3/46 , C10G3/49 , C10G3/52 , C10G45/02 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/08 , Y02P30/20
摘要： A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.
摘要翻译： 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂解原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例，或 具有氢化，脱氧，异构化和选择性加氢裂化功能的催化剂组。
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公开(公告)号：US20080249198A1
公开(公告)日：2008-10-09
申请号：US11697780
申请日：2007-04-09
IPC分类号： C07C27/06
CPC分类号： C07C29/095 , C07C67/035 , C12C11/02 , C07C31/04 , C07C69/63
摘要： A process for the oxidation of methane to methanol has been developed. The process involves contacting a gas stream, comprising methane, a solvent and an oxidizing agent with a bimetallic catalyst at oxidation conditions to produce a methyl ester. Finally, the methyl ester is hydrolyzed to yield a methanol product stream. The bimetallic catalyst comprises at least two transition metal components. One example of the catalytic component is a combination of cobalt and manganese.
摘要翻译： 已经开发了将甲烷氧化成甲醇的方法。 该方法包括在氧化条件下使包含甲烷，溶剂和氧化剂的气流与双金属催化剂接触以产生甲酯。 最后，将甲酯水解，得到甲醇产物流。 双金属催化剂包含至少两种过渡金属组分。 催化组分的一个实例是钴和锰的组合。
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