Methods and apparatuses for selective hydrogenation of olefins

    公开(公告)号:US09738572B2

    公开(公告)日:2017-08-22

    申请号:US14513764

    申请日:2014-10-14

    Applicant: UOP LLC

    CPC classification number: C07C5/03 B01J19/245 C07C5/02 C10G45/00

    Abstract: Methods and apparatuses for selective hydrogenation of olefins are provided. The method for selective hydrogenation of olefins comprises reacting a hydrocarbonaceous feedstock comprising olefins and aromatic compounds with hydrogen in a reaction zone. The reaction contains a catalyst producing a reaction zone product stream comprising aromatic compounds. The reaction zone product stream is passed to a flash vessel, recovering a first product stream and a second product stream from the flash vessel. The first product stream is passed to a liquid jet eductor, whereas the second product stream comprising aromatic compounds having a reduced concentration of olefins is subsequently recovered.

    VACUUM GAS OIL HYDROTREATING METHODS AND UNITS

    公开(公告)号:US20170096608A1

    公开(公告)日:2017-04-06

    申请号:US15282512

    申请日:2016-09-30

    Applicant: UOP LLC

    CPC classification number: C10G45/04 C10G2300/1059 C10G2300/202

    Abstract: The present invention relates to a hydrotreating process that includes providing a vacuum gas oil stream; heating the vacuum gas oil stream; passing the heated vacuum gas oil stream to a hydrotreating reactor; passing the hydrotreated effluent to a hot separator to form a gas stream and a liquid stream; passing the gas stream to a cold separator to form a heavy liquid stream, a light liquid stream and a vapor stream; and passing the vapor stream to an amine scrubber. Aspects of certain embodiments of the present invention also relate to a hydrotreating process in which the hydrotreating reactor is operated at a pressure within the range of approximately 35-50 kg/cm2g.

    PROCESSES AND APPARATUSES FOR ISOMERIZING HYDROCARBONS
    34.
    发明申请
    PROCESSES AND APPARATUSES FOR ISOMERIZING HYDROCARBONS 审中-公开
    用于同位素化的方法和装置

    公开(公告)号:US20160311732A1

    公开(公告)日:2016-10-27

    申请号:US14696799

    申请日:2015-04-27

    Applicant: UOP LLC

    Abstract: Processes and apparatuses for isomerizing hydrocarbons are provided. In an embodiment, a process for isomerizing hydrocarbons includes providing a first hydrocarbon feed that includes hydrocarbons having from 5 to 7 carbon atoms. The first hydrocarbon feed is fractionated to produce a first separated stream that includes hydrocarbons having from 5 to 6 carbon atoms and a second separated stream that includes hydrocarbons having 7 carbon atoms. The first separated stream is contacted with a benzene saturation catalyst at benzene saturation conditions to produce an intermediate stream and subsequently isomerized in the presence of a first isomerization catalyst and hydrogen under first isomerization conditions to produce a first isomerized stream. The second separated stream is isomerized in the presence of a second isomerization catalyst and hydrogen under second isomerization conditions that are different from the first isomerization conditions to produce a second isomerized stream.

    Abstract translation: 提供了烃类异构化的方法和装置。 在一个实施方案中,烃的异构化方法包括提供包含具有5至7个碳原子的烃的第一烃进料。 将第一烃进料分馏以产生包含具有5至6个碳原子的烃和包含具有7个碳原子的烃的第二分离流的第一分离流。 第一分离的物流在苯饱和条件下与苯饱和催化剂接触以产生中间物流,随后在第一异构化催化剂和氢存在下在第一异构化条件下异构化,以产生第一异构化物流。 在第二异构化催化剂和氢的存在下,第二分离的流在与第一异构化条件不同的第二异构化条件下异构化以产生第二异构化流。

    SHELL AND TUBE HEAT EXCHANGER WITH SPLIT SHELL AND METHOD OF USING
    35.
    发明申请
    SHELL AND TUBE HEAT EXCHANGER WITH SPLIT SHELL AND METHOD OF USING 审中-公开
    具有分离壳的壳和热交换器及其使用方法

    公开(公告)号:US20160258690A1

    公开(公告)日:2016-09-08

    申请号:US14635446

    申请日:2015-03-02

    Applicant: UOP LLC

    Abstract: A shell and tube heat exchanger is described. The shell and tube heat exchanger includes a shell side having a separation plate dividing the shell into at least two compartments, each of the compartments having a feed inlet and a feed outlet; and a tube side comprising a plurality of tubes in the shell, at least one tube in each compartment, and the tube side having an effluent inlet and an effluent outlet. A method of heating a feed stream for a reaction zone using reactor effluent using the shell and tube heat exchanger is also described.

    Abstract translation: 描述了壳管式热交换器。 壳管式热交换器包括具有分隔板的壳侧,壳体分隔成至少两个隔室,每个隔室具有进料入口和进料出口; 以及管侧,其包括壳中的多个管,每个隔室中的至少一个管,并且管侧具有流出物入口和流出物出口。 还描述了使用壳管式热交换器使用反应器流出物加热用于反应区的进料流的方法。

    CONTAMINANT REMOVAL FROM KEROSENE STREAMS WITH LACTAMIUM BASED IONIC LIQUIDS
    36.
    发明申请
    CONTAMINANT REMOVAL FROM KEROSENE STREAMS WITH LACTAMIUM BASED IONIC LIQUIDS 审中-公开
    用基于LACTAMIUM的离子液体从KEROSENE STREAMS中去除污染物

    公开(公告)号:US20160168483A1

    公开(公告)日:2016-06-16

    申请号:US14566058

    申请日:2014-12-10

    Applicant: UOP LLC

    CPC classification number: C10G17/07 C10G21/20

    Abstract: A process for removing a contaminant from a kerosene stream using a lactamium based ionic liquid is described. The process includes contacting the kerosene stream comprising the contaminant with a lean kerosene-immiscible lactamium ionic liquid to produce a mixture comprising the kerosene and a rich kerosene-immiscible lactamium ionic liquid comprising at least a portion of the removed contaminant; and separating the mixture to produce a kerosene effluent and a rich kerosene-immiscible lactamium ionic liquid effluent comprising the rich kerosene-immiscible lactamium ionic liquid.

    Abstract translation: 描述了使用基于内酰胺的离子液体从煤油流中除去污染物的方法。 该方法包括使包含污染物的煤油流与贫煤油不混溶的内酰胺离子液体接触,以产生包含煤油和富含不溶于煤油的内酰胺离子液体的混合物,其包含至少一部分去除的污染物; 并分离混合物以产生煤油流出物和富含煤油不混溶的内酰胺离子液体流出物,其包含富含煤油不混溶的内酰胺离子液体。

    PROCESS FOR HYDROTREATING A HYDROCARBONS STREAM
    37.
    发明申请
    PROCESS FOR HYDROTREATING A HYDROCARBONS STREAM 审中-公开
    氢化烃类流程的方法

    公开(公告)号:US20160115399A1

    公开(公告)日:2016-04-28

    申请号:US14524796

    申请日:2014-10-27

    Applicant: UOP LLC

    Abstract: Processes for hydrotreating a hydrocarbon stream in which a separation zone and a stripping zone is disposed between two hydrotreating reactors. The stripping zone may comprise a portion of the second hydrotreating reactor. The separation zone may comprise two separator vessels. A separator vessel may include the scrubbing zone to receive a scrubbing fluid, for example, steam, hydrogen, or heated effluent, and remove H2S and NH3. A divided wall separator may be used. Vapor from the separator vessels can be recycled in the system.

    Abstract translation: 加氢处理烃流的方法,其中分离区和汽提区设置在两个加氢处理反应器之间。 汽提区可以包括第二加氢处理反应器的一部分。 分离区可以包括两个分离器容器。 分离器容器可以包括洗涤区以接收洗涤流体,例如蒸汽,氢气或加热的流出物,并除去H 2 S和NH 3。 可以使用分隔壁分离器。 来自分离器容器的蒸气可以在系统中循环使用。

    PROCESS AND APPARATUS FOR REMOVING HYDROGEN SULFIDE
    39.
    发明申请
    PROCESS AND APPARATUS FOR REMOVING HYDROGEN SULFIDE 审中-公开
    去除硫化氢的工艺和装置

    公开(公告)号:US20140091010A1

    公开(公告)日:2014-04-03

    申请号:US13630701

    申请日:2012-09-28

    Applicant: UOP, LLC

    Abstract: One exemplary embodiment can be a process for removing hydrogen sulfide from a fractionated hydroprocessed effluent. The process can include stripping a hydroprocessed effluent from a hydroprocessing zone, fractionating the stripped hydroprocessed effluent to obtain a naphtha cut, and sending the naphtha cut to a hydrogen sulfide removal zone. The hydrogen sulfide removal zone can include an amine wash settler, an amine contacting column, or a steam stripper.

    Abstract translation: 一个示例性实施方案可以是从分馏的加氢处理流出物中除去硫化氢的方法。 该方法可以包括从加氢处理区中除去加氢处理的流出物,对汽提的加氢处理流出物进行分馏以获得石脑油馏分,并将石脑油馏分送入硫化氢去除区。 硫化氢去除区可以包括胺洗涤沉淀器,胺接触塔或蒸汽汽提器。

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