公开(公告)号：US20100249467A1

公开(公告)日：2010-09-30

申请号：US12744110

申请日：2008-11-13

Applicant: Gunnar Heydrich ,  Gabriele Gralla ,  Matthias Rauls ,  Joachim Schmidt-Leithoff ,  Klaus Ebel ,  Wolfgang Krause ,  Steffen Oehlenschläger ,  Christoph Jäkel ,  Marko Friedrich ,  Eike Johannes Bergner ,  Nawid Kashani-Shirazi ,  Rocco Paciello

Inventor： Gunnar Heydrich ,  Gabriele Gralla ,  Matthias Rauls ,  Joachim Schmidt-Leithoff ,  Klaus Ebel ,  Wolfgang Krause ,  Steffen Oehlenschläger ,  Christoph Jäkel ,  Marko Friedrich ,  Eike Johannes Bergner ,  Nawid Kashani-Shirazi ,  Rocco Paciello

IPC: C07C35/12

CPC classification number: C07C29/56 ,  C07B2200/07 ,  C07C29/172 ,  C07C29/78 ,  C07C45/62 ,  C07C45/82 ,  C07C2601/14 ,  C07C2601/16 ,  C07C47/21 ,  C07C35/12 ,  C07C35/17

Abstract: The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method comprises the following stepsa.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.

Abstract translation: 本发明涉及一种特别经济的制备薄荷醇的总体方法，特别用于制备光学活性的，基本上是对映异构体和非对映异构体纯的L-薄荷醇和外消旋薄荷醇，其原料柠檬醛以工业规模廉价地得到。 该方法包括以下步骤a.1）在酸性催化剂的存在下，将柠檬醛和/或香叶醇进行催化氢化以产生香茅醛，b.1）将香茅醛环化成异胡仑醇，c.1）通过结晶和d进行异丙醇的纯化 .1）异丙醇的催化氢化得到薄荷醇。

公开(公告)号：US20100222612A1

公开(公告)日：2010-09-02

申请号：US12086491

申请日：2006-11-27

Applicant: Tristan Erich Hahn ,  Jochemus Gildenhuys Johannes ,  Braam Van Dyk ,  James Christoffel Crause ,  Paranjothi Moodliar

Inventor： Tristan Erich Hahn ,  Jochemus Gildenhuys Johannes ,  Braam Van Dyk ,  James Christoffel Crause ,  Paranjothi Moodliar

IPC: C07C45/82 ,  B01D3/14

CPC classification number: C07C45/73 ,  B01D3/146 ,  B01J8/06 ,  B01J2219/00038 ,  C07C45/82 ,  Y02P20/132 ,  C07C49/04

Abstract: This invention relates to a method of producing purified methyl isobutyl ketone (MIBK) comprising subjecting a feed stream containing MIBK and impurities to a first distillation procedure from which acetone is recovered and a bottom product containing MIBK and impurities is withdrawn. This bottom product is fed to a second distillation column, where a vapour overhead product is withdrawn, condensed and fed to an overhead liquid-liquid separator. Part of an organic phase from the overhead liquid-liquid separator is fed to the second distillation column and part is fed to a third distillation column. A vapour overhead product is withdrawn from the third column which is condensed in the same said condensor. The condensed product is fed to the same said overhead liquid-liquid separator, and purified MIBK is withdrawn from the third distillation column. This invention also relates to an apparatus used in such a method.

Abstract translation: 本发明涉及一种生产纯化甲基异丁基酮（MIBK）的方法，包括使含有MIBK和杂质的进料流经历回收丙酮的第一蒸馏步骤，并且收集含有MIBK和杂质的底部产物。 将该底部产物进料至第二蒸馏塔，蒸馏塔顶产物被抽出，冷凝并送入塔顶液 - 液分离器。 将来自塔顶液 - 液分离器的有机相的一部分进料到第二蒸馏塔，并将一部分进料到第三蒸馏塔。 从第三塔取出蒸气塔顶产物，其在相同的所述冷凝器中冷凝。 将冷凝产物加入到相同的塔顶液 - 液分离器中，从第三蒸馏塔中取出纯化的MIBK。 本发明还涉及在这种方法中使用的装置。

公开(公告)号：US20100197977A1

公开(公告)日：2010-08-05

申请号：US12322650

申请日：2009-02-05

Applicant: Stephen H. Harris

Inventor： Stephen H. Harris

IPC: C07C29/09 ,  C09K3/00

CPC classification number: C07C67/055 ,  C07C29/095 ,  C07C45/54 ,  C07C45/82 ,  C07C51/09 ,  C07C67/60 ,  C07C47/22 ,  C07C53/08 ,  C07C69/007 ,  C07C69/155 ,  C07C33/03

Abstract: A process for purifying an acetoxylation mixture is disclosed. Allyl acetate, water, acetic acid, and from 0.1 to 10 wt. % allyl diacetate are contacted in the vapor phase with a solid acidic catalyst under conditions effective to decompose the allyl diacetate and generate an intermediate stream comprising allyl acetate, water, acetic acid, and acrolein. Acrolein is then removed from the intermediate stream, preferably by distillation, to give an allyl acetate-containing product stream. Usually, this product stream is then hydrolyzed to produce allyl alcohol. The invention includes processes in which propylene first reacts with oxygen and acetic acid in the presence of a noble metal catalyst to generate the acetoxylation mixture.

Abstract translation: 公开了一种纯化乙酰氧基化混合物的方法。 乙酸烯丙酯，水，乙酸，和0.1-10wt。 在有效分解烯丙基二乙酸酯的条件下，将％乙烯基二乙酸烯丙酯在气相中与固体酸性催化剂接触，并产生包含乙酸烯丙酯，水，乙酸和丙烯醛的中间料流。 然后优选通过蒸馏从中间物流中除去丙烯醛，得到含乙酸烯丙酯的产物流。 通常，将该产物流水解，生成烯丙醇。 本发明包括丙烯首先在贵金属催化剂存在下与氧和乙酸反应以产生乙酰氧基化混合物的方法。

公开(公告)号：US20100191018A1

公开(公告)日：2010-07-29

申请号：US12694815

申请日：2010-01-27

Applicant: Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Anton Meier ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus ,  Rolf Pinkos ,  Gerd-Dieter Tebben

Inventor： Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Anton Meier ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus ,  Rolf Pinkos ,  Gerd-Dieter Tebben

IPC: C07C45/27

CPC classification number: C07C45/82 ,  C07C45/28 ,  C07C45/62 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

Abstract: The present invention relates to a process for preparing at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group, at least comprising the stages: (a1) oxidation of a composition (A), at least comprising one cyclic olefin with Z cycles and 7 to 16 carbon atoms and at least two C—C double bonds, by means of dinitrogen monoxide to give a composition (A1), (a2) separating off the at least one cyclic olefin with Z cycles and 7 to 16 carbon atoms with at least two C—C double bonds from the composition (A1) in order to obtain a composition (A2), and (b) distillative treatment of the composition (A2) from step (a2) in order to obtain a composition (B), comprising the at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group and less than 1.0% by weight of the at least one compound with Z−1 cycles and 7 to 16 carbon atoms with at least one aldehyde group, where Z can be 1, 2, 3 or 4.

Abstract translation: 本发明涉及一种制备具有Z环和至少具有7至16个碳原子的酮基的至少一种环状化合物的方法，至少包括以下步骤：（a1）组合物（A）的氧化，至少包含一个环状 烯烃，Z循环和7至16个碳原子和至少两个C-C双键，借助于一氧化二氮，得到组合物（A1），（a2）以Z循环分离至少一种环状烯烃， 16个碳原子与来自组合物（A1）的至少两个C-C双键，以获得组合物（A2），和（b）从步骤（a2）中的组合物（A2）的蒸馏处理，以获得 组合物（B），其包含至少一种Z循环的环状化合物和具有酮基的7至16个碳原子和小于1.0重量％的至少一种具有Z-1循环和7至16个碳原子的化合物， 至少一个醛基，其中Z可以是1,2,3或4个。

公开(公告)号：US20100069583A1

公开(公告)日：2010-03-18

申请号：US12312202

申请日：2007-09-20

Applicant: Hiroto Kasuga ,  Etsushige Matsunami ,  Tsukasa Takahashi

Inventor： Hiroto Kasuga ,  Etsushige Matsunami ,  Tsukasa Takahashi

IPC: C07C51/16 ,  B01J19/00 ,  C08F20/06

CPC classification number: C07C45/82 ,  C07C45/52 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

Abstract: There are provided a process, an apparatus, and an acrolein-containing composition, for producing acrylic acid from the acrolein-containing composition at a high yield. The process for producing acrylic acid includes a refinement step of removing phenol and/or 1-hydroxyacetone from an acrolein-containing composition and an oxidation step of oxidizing acrolein in the acrolein-containing composition after the refinement step to produce acrylic acid, and the apparatus to be used in the process includes a refiner to be used in the refinement step and an oxidation reactor for oxidizing acrolein to produce acrylic acid. The acrolein-containing composition is a composition having a (mass of phenol)/(mass of acrolein) ratio of 0.020 or lower and a (mass of 1-hydroxyacetone)/(mass of acrolein) ratio of 0.020 or lower.

Abstract translation: 提供了一种用于以高产率从含丙烯醛的组合物制备丙烯酸的方法，装置和含丙烯醛的组合物。 制备丙烯酸的方法包括从含丙烯醛的组合物中除去苯酚和/或1-羟基丙酮的精制步骤和在精制步骤之后在含丙烯醛的组合物中氧化丙烯醛以生产丙烯酸的氧化步骤，并且该装置 在该方法中使用的方法包括在精制步骤中使用的精制机和用于氧化丙烯醛以产生丙烯酸的氧化反应器。 含丙烯醛的组合物是具有（质量的苯酚）/（丙烯醛的质量）比为0.020以下和（质量的1-羟基丙酮）/（丙烯醛的质量）比为0.020以下的组合物。

公开(公告)号：US20090326277A1

公开(公告)日：2009-12-31

申请号：US12306807

申请日：2007-06-27

Applicant: Rolf Pinkos ,  Gerd Tebben ,  Alexander Hauk ,  Christian Müller ,  Harald Rust

Inventor： Rolf Pinkos ,  Gerd Tebben ,  Alexander Hauk ,  Christian Müller ,  Harald Rust

IPC: C07C45/00

CPC classification number: C07C45/85 ,  C07C45/33 ,  C07C45/34 ,  C07C45/58 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C49/413 ,  C07C49/607

Abstract: The present invention relates to a process for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms, which comprises thermal treatment of the composition (I) with at least one acid and further purification by means of a process selected from the group consisting of distillation, extraction and crystallization, Furthermore, the present invention relates to a process for preparing cyclododecanone, which comprises such a purification, and the use of at least one acid for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms by thermal treatment of the composition (I) with the acid.

Abstract translation: 本发明涉及一种纯化包含至少一种具有7至16个碳原子的环酮的组合物（I）的方法，其包括用至少一种酸对组合物（I）进行热处理，并进一步通过 选自蒸馏，萃取和结晶的方法。此外，本发明涉及一种制备环十二烷酮的方法，其包括这种纯化，以及使用至少一种酸来纯化至少包含（I）的组合物 一种具有7-16个碳原子的环酮，通过组合物（I）与酸的热处理。

公开(公告)号：US20090326276A1

公开(公告)日：2009-12-31

申请号：US12306827

申请日：2007-06-27

Applicant: Joaquim Henrique Teles ,  Beatrice Rößler ,  Rolf Pinkos ,  Gerd Tebben ,  Christian Müller ,  Harald Rust

Inventor： Joaquim Henrique Teles ,  Beatrice Rößler ,  Rolf Pinkos ,  Gerd Tebben ,  Christian Müller ,  Harald Rust

IPC: C07C45/27

CPC classification number: C07C45/28 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C45/85 ,  C07C2601/18 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

Abstract: The present invention relates to a process for preparing a cyclic ketone having from 7 to 16 carbon atoms, which comprises at least the steps(a) oxidation of a composition (I) comprising at least one cyclic alkene which has from 7 to 16 carbon atoms and at least one C—C double bond by means of dinitrogen monoxide to give a composition (A),(b) treatment of the composition (A) with at least one base to give a composition (B),(c) hydrogenation of the composition (B) in the presence of at least one catalyst to give a composition (C),(d) purification of the composition (C), comprising at least the steps(di) thermal treatment of the composition (C) with at least one acid or at least one catalyst comprising at least one transition metal,(dii) further purification by a method selected from the group consisting of distillation, extraction and crystallization.

Abstract translation: 本发明涉及一种制备具有7至16个碳原子的环酮的方法，其至少包括步骤（a）氧化包含至少一个具有7至16个碳原子的环烯烃的组合物（I） 和至少一个CC双键，得到组合物（A），（b）用至少一种碱处理组合物（A），得到组合物（B），（c）组合物的氢化 （B）在至少一种催化剂的存在下，得到组合物（C），（d）组合物（C）的纯化，至少包括步骤（ii）组合物（C）的热处理至少一种 酸或至少一种包含至少一种过渡金属的催化剂，（dii）通过选自蒸馏，萃取和结晶的方法进一步纯化。

公开(公告)号：US07531066B2

公开(公告)日：2009-05-12

申请号：US10500715

申请日：2003-02-12

Applicant: Georges Gros ,  Patrick Rey ,  Michel Garrait

Inventor： Georges Gros ,  Patrick Rey ,  Michel Garrait

IPC: B01D3/00 ,  C07C47/22 ,  C07C45/82

CPC classification number: C07C319/18 ,  C07C45/35 ,  C07C45/783 ,  C07C45/82 ,  C07C47/22 ,  C07C323/22

Abstract: A process for purifying an aqueous solution to obtain purified gaseous acrolein by introducing the aqueous solution into a distillation column equipped at its base with at least one boiler and at its top with at least one condenser, withdrawing a liquid mixture essentially containing water at the base of the distillation column, withdrawing a gas essentially containing acrolein and water at the top of the distillation column, cooling the gas mixture withdrawn at the top of the distillation column in the condenser, to a temperature which makes it possible to obtain, on the one hand, an aqueous condensate and, on the other hand, an acrolein-rich gas mixture, and withdrawing the acrolein-rich gas mixture.

Abstract translation: 通过将水溶液引入到其底部装备有至少一个锅炉的蒸馏塔中并且在其顶部具有至少一个冷凝器来提纯水溶液以获得纯化的气态丙烯醛的方法，将基本上含有水的液体混合物 在蒸馏塔的顶部排出基本上含有丙烯醛和水的气体，将冷凝器中蒸馏塔顶部排出的气体混合物冷却到一个温度，从而可以在一个温度下获得 另一方面，富含丙烯醛的气体混合物，并且抽出富含丙烯醛的气体混合物。

公开(公告)号：US07498451B2

公开(公告)日：2009-03-03

申请号：US10536900

申请日：2003-11-27

Applicant: Gerd Haderlein ,  Hans-Georg Göbbel ,  Wolfgang Siegel

Inventor： Gerd Haderlein ,  Hans-Georg Göbbel ,  Wolfgang Siegel

IPC: C07D317/26 ,  C07C45/64

CPC classification number: C07D317/26 ,  B01D1/22 ,  B01D3/141 ,  B01D3/148 ,  B01D3/322 ,  C07C45/60 ,  C07C45/71 ,  C07C45/82 ,  C07C47/198

Abstract: The invention relates to a process for obtaining a pure aliphatic dialdehyde monoacetal by reaction of the corresponding aliphatic dialdehyde or a precursor of the corresponding aliphatic dialdehyde with one or more aliphatic mono- or polyhydric alcohols while distillatively removing water to obtain a reaction mixture which is separated distillatively, which comprises carrying out the distillative separation continuously in a dividing wall column to obtain pure aliphatic dialdehyde monoacetal as a sidestream from the dividing wall column, or in two distillation columns to obtain crude aliphatic dialdehyde monoacetal as a sidestream in the first distillation column, feed the crude aliphatic dialdehyde monoacetal to the second distillation column and obtain pure aliphatic dialdehyde monoacetal as the sidestream from the second distillation column.

Abstract translation: 本发明涉及通过相应的脂族二醛或相应的脂族二醛的前体与一种或多种脂肪族一元醇或多元醇反应而获得纯的脂族二醛单缩醛的方法，同时蒸馏除去水，得到分离的反应混合物 蒸馏，其包括在分隔壁塔中连续进行蒸馏分离以获得作为来自分隔壁塔的侧流的纯脂族二醛单缩醛，或在两个蒸馏塔中，以在第一蒸馏塔中获得作为侧流的粗脂族二醛单缩醛， 将粗脂族二醛单缩醛进料至第二蒸馏塔，得到作为来自第二蒸馏塔的侧流的纯脂族二醛单缩醛。

公开(公告)号：US20080274334A1

公开(公告)日：2008-11-06

申请号：US11628014

申请日：2005-05-30

Applicant: Akira Sekiya ,  Tatsuya Sugimoto ,  Toshiro Yamada ,  Takanobu Mase

Inventor： Akira Sekiya ,  Tatsuya Sugimoto ,  Toshiro Yamada ,  Takanobu Mase

IPC: C09K13/00 ,  H01L21/306 ,  B32B3/00

CPC classification number: H01L21/31116 ,  C07C41/18 ,  C07C43/17 ,  C07C45/513 ,  C07C45/673 ,  C07C45/82 ,  C07C49/227 ,  C07C2601/04 ,  C07F9/5352 ,  Y10T428/24479 ,  C07C49/687

Abstract: A dry etching gas comprising a C4-6 fluorine compound which has an ether bond or carbonyl group and one or more fluorine atoms in the molecule and is constituted only of carbon, fluorine, and oxygen atoms and in which the ratio of the number of fluorine atoms to the number of carbon atoms (F/C) is 1.9 or lower (provided that the compound is neither a fluorine compound having one cyclic ether bond and one carbon-carbon double bond nor a saturated fluorine compound having one carbonyl group); a mixed dry etching gas comprising the dry etching gas and at least one gas selected from the group consisting of rare gases, O2, O3, CO, CO2, CHF3, CH2F2, CF4, C2F6, and C3F8; and a method of dry etching which comprises converting either of these dry etching gases into a plasma and processing a semiconductor material with the plasma. The dry etching gases can be safely used, are reduced in influence on the global environment, and can highly selectively dry-etch a semiconductor material at a high dry etching rate to form a satisfactory pattern shape. The dry etching method employs either of these dry etching gases.

Abstract translation: 一种干蚀刻气体，其包含在分子中具有醚键或羰基和一个或多个氟原子的C 4-6二氟化合物，其仅由碳，氟和氧原子构成，并且在 氟原子数与碳原子数的比例（F / C）为1.9以下（前提是该化合物既不是具有一个环醚键的氟化合物，也不是一个碳 - 碳双键，也不是饱和氟 具有一个羰基的化合物）; 包括干蚀刻气体和至少一种选自稀有气体O 2，O 3，CO，CO 2的气体的混合干蚀刻气体， CH 2，CH 2，CH 2，CH 2，CF 4，C 2， F 6，和C 3 F 8; 以及干蚀刻方法，其包括将这些干蚀刻气体中的任一种转化为等离子体并用等离子体处理半导体材料。 可以安全地使用干蚀刻气体，减小对全局环境的影响，并且可以以高干蚀刻速率高度选择性地干蚀刻半导体材料以形成令人满意的图案形状。 干蚀刻方法采用这些干蚀刻气体中的任一种。