公开(公告)号：US20090029043A1

公开(公告)日：2009-01-29

申请号：US12194834

申请日：2008-08-20

Applicant: Haitao RONG ,  Jurgen GROLL ,  Peter GREIWE ,  Gallus SCHECHNER ,  Christine MOHR ,  Martin MOLLER

Inventor： Haitao RONG ,  Jurgen GROLL ,  Peter GREIWE ,  Gallus SCHECHNER ,  Christine MOHR ,  Martin MOLLER

IPC: B05D1/12 ,  B05D3/02 ,  B05D3/12 ,  C08G77/14 ,  C08G77/26 ,  C08L83/06

CPC classification number: C08G65/336 ,  A61K8/91 ,  A61K2800/544 ,  A61K2800/94 ,  A61Q5/12 ,  C08F8/42 ,  C08G18/10 ,  C08G18/485 ,  C08G18/5045 ,  C08G18/5096 ,  C08G18/718 ,  C08G2210/00 ,  C09D171/02 ,  C09D201/10 ,  C11D3/373 ,  C08G18/302

Abstract: The present invention relates to coatings that possess a dynamic contact angle hysteresis in water, measured by means of a Wilhelmy balance according to DIN EN 14370, of at most 15°, and are can be manufactured from star-shaped prepolymers and/or star-shaped prepolymer-nanoparticle complexes that are cross-linkable with one another and with the surface of the substrate to be coated, the star-shaped prepolymers and/or star-shaped prepolymer-nanoparticle complexes possessing, before being cross-linked, at least three hydrophilic polymer arms that, considered of themselves, are soluble in water, and that carry on all or on some of their free ends R1 silyl terminal groups of the following general formula (I): R1 is —CRa2—Si(ORb)r(Rc)3-r, where Ra denotes hydrogen or a linear or branched alkyl group having 1 to 6 carbon atoms, ORb denotes a hydrolyzable group, Rc denotes a linear or branched alkyl group having 1 to 6 carbon atoms, and r denotes a number from 1 to 3, and that carry, on the optionally present ends not carrying silyl terminal groups, reactive groups that are reactive with respect to themselves, the substrate to be coated, entities optionally introduced into the coating, and/or with the silyl terminal groups. The present invention furthermore relates to a method for manufacturing such coatings, and to star-shaped prepolymers that are used in the coatings. The invention moreover relates to use of the star-shaped prepolymers as additives to various agents for temporary or permanent anti-soiling finishing of surfaces.

Abstract translation: 本发明涉及在水中具有动态接触角滞后的涂层，其通过根据DIN EN 14370的Wilhelmy平衡测量为至多15°，并且可以由星形预聚物和/或星形预制物制造， 形状预聚物 - 纳米颗粒复合物，其彼此可交联并与待涂覆的基底的表面，星形预聚物和/或星形预聚物 - 纳米颗粒络合物在交联之前具有至少三个 亲水性聚合物臂，其本身可以溶于水，并且在其一部分自由端上进行。其中R 1是-CR a 2 -Si（OR b）r（OR b）r Rc）3-r，其中Ra表示氢或具有1至6个碳原子的直链或支链烷基，ORb表示可水解基团，Rc表示具有1至6个碳原子的直链或支链烷基，r表示数 从1到3，并携带，在 任选地存在不携带甲硅烷基端基的末端，对其自身具有反应性的反应性基团，待涂布的基材，任选地引入涂层中的实体和/或甲硅烷基末端基团。 本发明还涉及制造这种涂层的方法以及用于涂层中的星形预聚物。 此外，本发明涉及使用星形预聚物作为各种试剂的添加剂用于表面的临时或永久性防污整理。

公开(公告)号：US20060251902A1

公开(公告)日：2006-11-09

申请号：US11124077

申请日：2005-05-09

Applicant: Alex Botrie ,  Yuan Deng ,  Daniel Foucher ,  Jeffrey Cooke

Inventor： Alex Botrie ,  Yuan Deng ,  Daniel Foucher ,  Jeffrey Cooke

IPC: B32B27/40

CPC classification number: C08G18/10 ,  C08G18/718 ,  C08G18/758 ,  C08L75/04 ,  C09D163/00 ,  C09D175/04 ,  C09D201/10 ,  Y10T428/31551 ,  C08G18/48 ,  C08G18/289 ,  C08L2666/02 ,  C08L2666/20

Abstract: A one component, moisture-cure, colorless or colored, protective or decorative high-build lensing or doming resin system is described. Use of these polymer systems have the advantage of eliminating the mixing, handling, and high toxicity associated with standard two-component epoxy or polyurethane lensing resins, or one-component ultraviolet cured systems.

Abstract translation: 描述了一种组分，湿度固化，无色或有色，保护或装饰的高成型透镜或拱形树脂体系。 使用这些聚合物体系具有消除与标准双组分环氧树脂或聚氨酯透镜树脂或单组分紫外线固化体系相关的混合，处理和高毒性的优点。

公开(公告)号：US20050074617A1

公开(公告)日：2005-04-07

申请号：US10677513

申请日：2003-10-02

Applicant: Jun Lin ,  John Crowther ,  Donald Paquet ,  David Zukowski

Inventor： Jun Lin ,  John Crowther ,  Donald Paquet ,  David Zukowski

IPC: C08G18/62 ,  C09D143/04 ,  C09D201/02 ,  C09D201/10 ,  B32B9/04

CPC classification number: C09D143/04 ,  C08G18/6295 ,  C09D201/025 ,  C09D201/10 ,  Y10T428/31663

Abstract: A film-forming coating composition, typically a topcoat, having improved adhesion. The composition includes a film-forming binder comprising a carbamate material, a curing agent, typically a melamine curing agent, and a hydroxy functional silane component. When used as a clearcoat over a standard pigmented basecoat, the resulting coating provides excellent adhesion to both windshield sealants and additional repair coatings.

Abstract translation: 一种成膜涂料组合物，通常是顶涂层，具有改善的粘合性。 组合物包括含有氨基甲酸酯材料，固化剂，通常为三聚氰胺固化剂和羟基官能的硅烷组分的成膜粘合剂。 当用作标准着色底漆的透明涂层时，所得到的涂层对挡风玻璃密封剂和附加的修补涂层提供极好的附着力。

公开(公告)号：US06451439B2

公开(公告)日：2002-09-17

申请号：US09820701

申请日：2001-03-30

Applicant: Toshihiko Okamoto ,  Makoto Chiba ,  Junji Takase

Inventor： Toshihiko Okamoto ,  Makoto Chiba ,  Junji Takase

IPC: B32B904

CPC classification number: C09J5/02 ,  C08L83/04 ,  C09D201/10 ,  C09J2483/00 ,  Y10T428/31663

Abstract: A primer composition showing good adhesion to the surface of a substrate, such as a glass substrate, and excellent in weather resistance and water resistance as well as a method of effecting adhesion is provided. The primer composition is characterized by comprising a saturated hydrocarbon polymer having at least one silicon-containing group which has hydroxyl or hydrolyzable group bound to the silicon atom and capable of crosslinking under formation of a siloxane bond.

Abstract translation: 提供了对玻璃基板等基板的表面具有良好的粘合性，耐候性和耐水性优异的底漆组合物以及附着的方法。 底漆组合物的特征在于包含具有至少一个含硅基团的饱和烃聚合物，其具有与硅原子结合的羟基或可水解基团，并且能够在形成硅氧烷键的情况下交联。

公开(公告)号：US20020051889A1

公开(公告)日：2002-05-02

申请号：US09822418

申请日：2001-04-02

Applicant: JSR CORPORATION

Inventor： Tarou Kanamori ,  Kouji Kawahara ,  Yuichi Hashiguchi

IPC: B32B009/04 ,  C08F008/00

CPC classification number: C09D201/10 ,  C08J7/047 ,  C08J2483/00 ,  C09D183/04 ,  Y10T428/31663 ,  C08L2666/04

Abstract: A coating composition excellent in storage stability, excellent in coating appearance, adhesion and weather resistance, high in hardness, having ultraviolet absorbing ability, and capable of preventing deterioration of a ground or a substrate, which comprises (A) a polymer containing (a1) a silyl group having a silicon atom bound to a hydrolytic group and/or a hydroxyl group, (a2) a group having ultraviolet absorbing ability and (a3) a group having ultraviolet stability in the same polymer chain, and further optionally comprises (B) at least one component selected from the group consisting of an organosilane represented by (R1)nSi(OR2)4-n, a hydrolyzate of the organosilane and a condensate of the organosilane; and a cured product thereof.

Abstract translation: 一种涂料组合物，其具有优异的保存稳定性，优异的涂装外观，粘合性和耐候性，硬度高，具有紫外线吸收能力，并且能够防止磨碎或底物变质，其包含（A）含有（a1） 具有与水解基团和/或羟基键合的硅原子的甲硅烷基，（a2）具有紫外线吸收能力的基团和（a3）在同一聚合物链中具有紫外线稳定性的基团，进一步任选包含（B） 选自由（R1）nSi（OR2）4-n表示的有机硅烷，有机硅烷的水解产物和有机硅烷的缩合物组成的组中的至少一种; 及其固化物。

公开(公告)号：US20010037002A1

公开(公告)日：2001-11-01

申请号：US09815464

申请日：2001-03-23

Inventor： Mladen Ladika ,  Gene D. Rose

IPC: C08F008/30

CPC classification number: C09D201/10 ,  C08F8/42 ,  C08F8/44 ,  C09D133/068 ,  C08L2666/44

Abstract: A shelf-stable water-borne dispersion or solution that cures rapidly and at low temperatures when coated onto a substrate can be prepared with an aqueous-based solution or stable aqueous dispersion of a polymer having a backbone containing pendant silanol groups which are sufficiently neutralized to inhibit silanol condensation.

公开(公告)号：US06268456B1

公开(公告)日：2001-07-31

申请号：US08973383

申请日：1997-12-03

Applicant: Basil V. Gregorovich ,  Isidor Hazan ,  Robert Rudolph Matheson ,  Lech Wilczek

Inventor： Basil V. Gregorovich ,  Isidor Hazan ,  Robert Rudolph Matheson ,  Lech Wilczek

IPC: C08G7760

CPC classification number: C09D4/00 ,  C09D201/10 ,  C08F230/00 ,  C08G77/04 ,  C08G77/00 ,  C08L2666/02

Abstract: A sprayable coating composition that contains at least one soluble film-forming silicon-containing compound having, on average, more than one fuctionalized silicon group, a volatile organic carrier, a polymer microparticle component, and a catalyst; a substrate coated with the composition; a process for coating the substrate to provide a protective finish; the finish-protected substrate; certain oligomeric compounds and a process therefor.

Abstract translation: 一种可喷涂的涂料组合物，其含有至少一种平均具有多于一个功能硅基团的可溶性成膜含硅化合物，挥发性有机载体，聚合物微粒组分和催化剂; 涂有组合物的基材; 用于涂覆基材以提供保护性整理剂的方法; 保护底材; 某些寡聚化合物及其制备方法。

公开(公告)号：US6080816A

公开(公告)日：2000-06-27

申请号：US969198

申请日：1997-11-10

Applicant: Basil V. Gregorovich ,  Isidor Hazan ,  Lech Wilczek

Inventor： Basil V. Gregorovich ,  Isidor Hazan ,  Lech Wilczek

IPC: C08F8/42 ,  C08G18/38 ,  C08G18/67 ,  C08G18/71 ,  C08G65/336 ,  C08G77/60 ,  C08K5/5465 ,  C08L61/20 ,  C09D133/00 ,  C09D133/06 ,  C09D143/04 ,  C09D151/00 ,  C09D161/28 ,  C09D171/02 ,  C09D175/04 ,  C09D183/04 ,  C09D183/10 ,  C09D201/02 ,  C09D201/10 ,  C08G77/00 ,  C08G77/16 ,  C08G77/48

CPC classification number: C09D201/025 ,  C08F8/42 ,  C08G18/3893 ,  C08G18/677 ,  C08G18/718 ,  C08G65/336 ,  C09D133/066 ,  C09D151/003 ,  C09D171/02 ,  C09D183/10 ,  C09D201/10 ,  C08K5/5465 ,  C08L61/20

Abstract: A coating comprising the silated reaction product of R.sup.1 (OH).sub.m and OCN(CH.sub.2).sub.t SiR.sup.4 (OR.sup.5).sub.2 and/or R.sup.2 --(SiYX.sub.2).sub.n ; a graft copolymer having an acrylic polymer based backbone and stabilizing arms comprising ethylenically unsaturated monomer, the backbone being insoluble and the arms being soluble in the composition; a melamine crosslinker; and an acrylic polyol; m, n, t, R.sup.1, R.sup.2 R.sup.4, R.sup.5, X and Y being defined in the text.

Abstract translation: 包含R1（OH）m和OCN（CH2）tSiR4（OR5）2和/或R2-（SiYX2）n的硅烷化反应产物的涂层; 具有基于丙烯酸聚合物的主链和包含烯键式不饱和单体的稳定臂的接枝共聚物，所述骨架是不溶的，并且所述臂可溶于所述组合物中; 三聚氰胺交联剂; 和丙烯酸多元醇; m，n，t，R1，R2 R4，R5，X和Y在文中定义。

公开(公告)号：US6069200A

公开(公告)日：2000-05-30

申请号：US935003

申请日：1997-09-22

Applicant: Ming J. Chen ,  Frederick D. Osterholtz

Inventor： Ming J. Chen ,  Frederick D. Osterholtz

IPC: C08L101/10 ,  C09D201/10 ,  C08L43/00

CPC classification number: C08L101/10 ,  C09D201/10

Abstract: Curable compositions comprising stable, water dispersible, curable polymers containing sterically hindered alkoxylated silane groups and acid groups blocked by fugitive bases at 0.1 to 75 weight percent of the total composition and water at 99.9 to 25 weight percent of the total composition are taught herein, as well as methods for the use and manufacture thereof. Additional components, such as emulsifiers, buffers and thickeners are also taught. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance.

Abstract translation: 包含稳定的水分散性固化性聚合物，其含有空间位阻烷氧基化硅烷基团和酸性基团，以总组合物的0.1至75重量％和水为总组合物的99.9至25重量％ 以及其使用和制造方法。 还教导了其它组分，如乳化剂，缓冲剂和增稠剂。 这些组合物可用作粘合剂，密封剂和油漆。 该组合物具有改进的性能，包括耐溶剂性，粘合性，硬度，耐磨性和耐擦伤性。

公开(公告)号：US5658988A

公开(公告)日：1997-08-19

申请号：US496481

申请日：1995-06-29

Applicant: Shinichi Ogino ,  Nobushige Numa ,  Shinji Tomita ,  Hajime Sukejima

Inventor： Shinichi Ogino ,  Nobushige Numa ,  Shinji Tomita ,  Hajime Sukejima

IPC: C08F230/08 ,  C08G18/62 ,  C08G18/72 ,  C09D201/10 ,  C08L43/04 ,  C08L83/06

CPC classification number: C08G18/6295 ,  C08F230/08 ,  C08G18/728 ,  C09D201/10 ,  Y10T428/31547 ,  Y10T428/31663 ,  Y10T428/31855

Abstract: A one-package resinous coating composition, especially for automobile finishes (A) a resin having a siloxy group, and (B) a catalyst for dissociating the siloxy group. Resinous mixture (A) contains one or more of the following (A-1) through (A-4). (A-1) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule; (A-2) a mixture of (a) a resin that contains at least one siloxy group and one alkoxysilyl group respectively in the one molecule, and (c) a compound or a resin that contains at least two isocyanate groups in the one molecule; (A-3) a mixture of (b) a resin that contains at least one isocyanate group and one alkoxysilyl group respectively in the one molecule, and (d) a compound or a resin that contains at least two siloxy groups in the one molecule; and (A-4) (e) a resin that contains at least one siloxy group, one isocyanate group and one alkoxysilyl group respectively in the one molecule.

Abstract translation: 一种单组分树脂涂料组合物，特别是用于汽车涂料（A）具有甲硅烷氧基的树脂，和（B）用于解离甲硅烷氧基的催化剂。 树脂混合物（A）含有以下（A-1）〜（A-4）中的一种以上。 （A-1）分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物，和（b）分别含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂 一分子 （A-2）（a）在一个分子中分别含有至少一个甲硅烷氧基和一个烷氧基甲硅烷基的树脂的混合物，和（c）在一个分子中含有至少两个异氰酸酯基团的化合物或树脂 ; （A-3）分子中的（b）分子中含有至少一个异氰酸酯基和一个烷氧基甲硅烷基的树脂的混合物，和（d）在一个分子中含有至少两个甲硅烷氧基的化合物或树脂 ; 和（A-4）（e）分子中含有至少一个甲硅烷氧基，一个异氰酸酯基和一个烷氧基甲硅烷基的树脂。