Method for low bake repair of composite color-plus-clear coatings, and
compositions for use therein
    32.
    发明授权
    Method for low bake repair of composite color-plus-clear coatings, and compositions for use therein 失效
    复合彩色透明涂层的低烘烤修复方法及其中使用的组合物

    公开(公告)号:US5972422A

    公开(公告)日:1999-10-26

    申请号:US71083

    申请日:1998-05-01

    CPC classification number: C09D133/062 B05D5/005 C09D201/02

    Abstract: The invention provides a method for providing a low bake repair to a cured coating, especially a composite coating and low bake repair compositions for use therein. The method of the invention involves the provision of a cured coated surface and the application of a low bake repair coating to at least a portion of the cured coated surface. The low bake repair coating of the invention has (A) a film forming component comprising (a) a first component comprising a compound having appended thereto at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group, and (b) a second component comprising a compound reactive with said carbamate or urea groups on component (a), and (B) a catalyst comprising a compound selected from the group consisting of Al(ClO.sub.4).sub.2, Zr(ClO.sub.4).sub.2, and Al(NO.sub.3).sub.2. The low bake repair coating is cured at a temperature of less than 200.degree. F. for a time sufficient to cure the low bake repair coating.

    Abstract translation: 本发明提供了一种为固化涂层提供低烘烤修复的方法,特别是用于其中的复合涂层和低烘烤修复组合物。 本发明的方法包括提供固化的涂覆表面和将低烘烤修复涂层施加到固化的涂覆表面的至少一部分上。 本发明的低烘烤修复涂层具有(A)成膜组分,其包含(a)第一组分,其包含附有至少一个氨基甲酸酯或脲官能团的化合物或可转化为氨基甲酸酯或脲基的基团,以及 (b)第二组分,其包含与组分(a)上的所述氨基甲酸酯或脲基反应的化合物,和(B)包含选自Al(ClO 4)2,Zr(ClO 4)2和 Al(NO3)2。 低温烘烤修复涂层在低于200°F的温度下固化足够固化低温修复涂层的时间。

    Coating composition having extended storage stability and method for
producing wear resistant coatings therefrom
    33.
    发明授权
    Coating composition having extended storage stability and method for producing wear resistant coatings therefrom 失效
    具有延长储存稳定性的涂料组合物及其制备耐磨涂料的方法

    公开(公告)号:US5939514A

    公开(公告)日:1999-08-17

    申请号:US906538

    申请日:1997-08-05

    Abstract: The present invention relates to the preparation of water based coating compositions having extended storage stability. The composition includes separately stored polymeric binder component and a crosslinking component.These components are mixed prior to application over surfaces, such as, road surfaces. The polymeric binder component includes an anionically stabilized binder polymer having at least one reactive functional pendent moiety, or a blend of the binder polymer with a polyfunctional amine. The pot mix of the coating composition has extended storage stability. The waterborne road marking paints of the present invention exhibit improved wear resistance on road surfaces in terms of paint remaining on the road longer than waterborne road marking paints based on the storage stable component alone. The present invention provides road marking paints that can be applied by conventional road striping equipment and do not require special two component spray equipment.

    Abstract translation: 本发明涉及具有延长储存稳定性的水基涂料组合物的制备。 组合物包括单独存储的聚合物粘合剂组分和交联组分。 这些组分在施加在诸如路面之类的表面之前被混合。 聚合物粘合剂组分包括具有至少一个反应性官能侧基部分的阴离子稳定的粘合剂聚合物,或粘合剂聚合物与多官能胺的共混物。 涂料组合物的罐混合物具有延长的储存稳定性。 基于仅存储稳定组分,本发明的水性道路标线涂料在路面上保留的油漆表现出比水性道路标线漆更好的耐磨性。 本发明提供了可以通过常规路线设备应用的道路标线涂料,并且不需要特殊的双组分喷涂设备。

    Thermal latent acid catalyst
    35.
    发明授权
    Thermal latent acid catalyst 失效
    热潜酸催化剂

    公开(公告)号:US5922633A

    公开(公告)日:1999-07-13

    申请号:US844050

    申请日:1997-04-18

    CPC classification number: C08L101/02 C09D133/062 C09D157/04 C09D201/02

    Abstract: A thermal latent acid catalyst which comprises (i) a compound having an epoxy group, (ii) a compound having a sulfur atom of the following formula: R.sup.5 --S--R.sup.6, wherein R.sup.5 and R.sup.6 are the same or different from each other and are a hydrogen atom or an organic group of 1 to 40 carbon atoms, R.sup.5 and R.sup.6 optionally are bonded with each other to form a cyclic structure; and (iii) a Lewis acid of the following formula: (X.sup.1).sub.n1 --M.sup.1 --(R.sup.7).sub.n2, wherein M.sup.1 is a boron atom, an aluminium atom, a tin atom, a lead atom or a transition element, X.sup.1 is one or more halogen atoms, R.sup.7 is one or more organic groups of 1 to 40 carbon atoms, R.sup.7 optionally forms a chelate ring by coordinating to the M.sup.1 atom, n1 and n2 are each an integer of 0 through 6, and n1 plus n2 equals an integer of 1 to 6. The ratio of the epoxy group of the epoxy compound (i) to the M.sup.1 atom of the Lewis acid is 0.2 to 10 and the ratio of the sulfur atom of the compound (ii) to the M.sup.1 atom of the Lewis acid is 0.2 to 10.

    Abstract translation: 一种热潜潜酸催化剂,其包含(i)具有环氧基的化合物,(ii)具有下式的硫原子的化合物:R5-S-R6,其中R5和R6彼此相同或不同, 是氢原子或1〜40个碳原子的有机基团,R5和R6任选地相互结合形成环状结构; 和(iii)下式的路易斯酸:(X1)n1-M1-(R7)n2,其中M1是硼原子,铝原子,锡原子,引线原子或过渡元素,X1是一个 或更多的卤素原子,R7是一个或多个1至40个碳原子的有机基团,R7任选地通过与M1原子配位形成螯合环,n1和n2各自为0至6的整数,n1加上n2等于 环氧化合物(i)的环氧基与路易斯酸的M1原子的比例为0.2〜10,化合物(ii)的硫原子与M1原子的比例 路易斯酸为0.2〜10。

    High solids thermosetting compositions with dual cure mechanism
    38.
    发明授权
    High solids thermosetting compositions with dual cure mechanism 失效
    具有双重固化机理的高固含量热固性组合物

    公开(公告)号:US5907024A

    公开(公告)日:1999-05-25

    申请号:US968387

    申请日:1997-11-12

    Abstract: Disclosed is a curable coating composition that includes a compound having both hydroxy functionality and carbamate functionality of the structure ##STR1## wherein R is H or alkyl, a polyisocyanate crosslinking agents and an aminoplast crosslinking agent. The effective equivalents of the aminoplast crosslinking agent is equal to or less than the equivalents of carbamate functionality and the effective equivalents of polyisocyanate crosslinker is equal to or less than the equivalents of hydroxyl functionality. The carbamate-functional resin and the aminoplast crosslinking agent provide rheology control during the early part of the bake to cure an applied coating of the coating composition.

    Abstract translation: 公开了一种可固化涂料组合物,其包含具有羟基官能度的化合物和具有其中R为H或烷基的结构的氨基甲酸酯官能团,多异氰酸酯交联剂和氨基塑料交联剂。 氨基塑料交联剂的有效当量等于或小于氨基甲酸酯官能度的当量,多异氰酸酯交联剂的有效当量等于或小于羟基官能度的当量。 氨基甲酸酯官能树脂和氨基塑料交联剂在烘烤的早期部分提供流变控制,以固化涂料组合物的涂覆涂层。

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