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    Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane
    41.
    发明申请
    Process for improving prereforming and reforming of natural gas containing higher hydrocarbons along with methane 有权
    改善含甲烷高碳氢化合物天然气的预重整和改造方法

    公开(公告)号：US20050207970A1

    公开(公告)日：2005-09-22

    申请号：US10804536

    申请日：2004-03-19

    Applicant: Diwakar Garg ,  Shankar Nataraj ,  John Armor ,  John Repasky

    Inventor： Diwakar Garg ,  Shankar Nataraj ,  John Armor ,  John Repasky

    IPC: B01J23/78 ,  C01B3/38 ,  C01B3/24

    CPC classification number: C01B3/382 ,  B01J23/78 ,  C01B2203/0227 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/142 ,  Y02P20/52

    Abstract: A process for prereforming natural gas containing higher hydrocarbons and methane, includes providing a reactor having a nickel catalyst; providing steam, hydrogen, and natural gas containing higher hydrocarbons and methane to the reactor; adding an oxidant to the feedstock, wherein the oxidant provides oxygen in an amount less than the amount required to partially oxidize all higher hydrocarbons to a mixture of carbon monoxide and hydrogen; reacting the oxidant with higher hydrocarbons; and forming a gaseous mixture containing methane, carbon monoxide, carbon dioxide, steam and hydrogen substantially free of higher hydrocarbons and oxygen. The gaseous mixture can be reformed. An apparatus for performing the process includes a reactor; a feedstock source containing steam, hydrogen, and natural gas comprising higher hydrocarbons and methane; an oxidant source; valves and pipes connecting the natural gas source, the oxidant source and the reactor; and a nickel-containing catalyst within the reactor.

    Abstract translation: 一种用于预先重构含有高级烃和甲烷的天然气的方法，包括提供具有镍催化剂的反应器; 向反应器提供含有较高级烃和甲烷的蒸汽，氢气和天然气; 向原料中加入氧化剂，其中氧化剂提供的氧量小于将所有高级烃部分氧化成一氧化碳和氢气的混合物所需的量; 使氧化剂与高级烃反应; 并形成含有甲烷，一氧化碳，二氧化碳，蒸汽和氢气的气态混合物，其基本上不含高级烃和氧气。 气体混合物可以重整。 一种用于执行该方法的装置包括反应器; 含有蒸气，氢气和包含高级烃和甲烷的天然气的原料源; 氧化剂源; 连接天然气源，氧化剂源和反应器的阀门和管道; 和反应器内的含镍催化剂。

    Reforming with intermediate reactant injection
    42.
    发明授权
    Reforming with intermediate reactant injection 失效
    用中间体反应物注入改性

    公开(公告)号：US06527980B1

    公开(公告)日：2003-03-04

    申请号：US09689454

    申请日：2000-10-12

    Applicant: Thomas Michael Roden ,  Arthur Daniel Bixler ,  David Michael Nicholas ,  Shankar Nataraj

    Inventor： Thomas Michael Roden ,  Arthur Daniel Bixler ,  David Michael Nicholas ,  Shankar Nataraj

    IPC: C07C102

    CPC classification number: C01B3/384 ,  C01B2203/0233 ,  C01B2203/0816 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/142

    Abstract: According to the present invention, hydrogen/carbon monoxide synthesis gas (also called syngas) is produced by injection of a second reactant stream into a hydrocarbon reformer at a location between the entry and discharge ends of the reformer. The second reactant stream can contain: carbon dioxide; a mixture of carbon dioxide and hydrocarbon; a mixture of hydrocarbon and steam, a mixture of carbon dioxide and steam; or a mixture of carbon dioxide with hydrocarbon and steam. All or part of the mixtures containing hydrocarbon and steam can be prereformed hydrocarbon in steam.

    Abstract translation: 根据本发明，通过在重整器的入口端和出料端之间的位置将第二反应物流注入烃重整器来生产氢/一氧化碳合成气（也称为合成气）。 第二反应物流可以包含：二氧化碳; 二氧化碳和烃的混合物; 烃和蒸汽的混合物，二氧化碳和蒸汽的混合物; 或二氧化碳与烃和蒸汽的混合物。 含有烃和蒸汽的全部或部分混合物可以在蒸汽中预先形成烃。

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