Extending the life of an aromatization catalyst
    41.
    发明授权
    Extending the life of an aromatization catalyst 有权
    延长芳构化催化剂的使用寿命

    公开(公告)号:US08288603B2

    公开(公告)日:2012-10-16

    申请号:US12962250

    申请日:2010-12-07

    Abstract: A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of characterizing an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.

    Abstract translation: 延长芳构化催化剂寿命的方法,包括鉴定催化剂的快速失活阈值(RDT),并在达到RDT之前氧化催化剂。 一种芳构化烃的方法,包括鉴定用于芳族化催化剂的快速失活阈值(RDT),以及操作包含催化剂的芳构化反应器以在达到RDT之前延长反应器上的时间。 表征芳构化催化剂的方法包括鉴定催化剂的快速失活阈值(RDT)。 一种延长芳构化催化剂的寿命的方法,包括通过在加速结垢条件下在反应器系统中使用催化剂来预测芳构化反应器的快速失活阈值(RDT),以鉴定测试快速失活阈值(t-RDT),预测 基于t-RDT的芳构化反应器的RDT,以及在预测的RDT之前氧化催化剂以延长芳构化催化剂的时间。

    Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base
    42.
    发明授权
    Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base 有权
    在氢和碱的存在下还原催化剂使二甲苯异构化的方法

    公开(公告)号:US08097764B2

    公开(公告)日:2012-01-17

    申请号:US12940291

    申请日:2010-11-05

    Abstract: A xylene isomerization process includes introducing gas comprising hydrogen and a base to a reaction zone in which a catalyst comprising a Group VIII metal and a zeolite support resides. In one embodiment, the base may be formed in situ within the reaction zone from nitrogen and hydrogen that are introduced to the reaction zone. In another embodiment, the base is introduced directly to the reaction zone. The conditions in the reaction zone are effective to reduce the catalyst. A stream comprising C8 aromatics, e.g., xylenes and ethylbenzene may then be fed to the reaction zone containing the reduced catalyst. The reaction zone may be operated at conditions effective to isomerize the xylenes and hydrodealkylate the ethylbenzene. The xylene loss during the isomerization of the xylenes is lowered as a result of using the catalyst reduced in the presence of the gas comprising a base and hydrogen.

    Abstract translation: 二甲苯异构化方法包括将包含氢和碱的气体引入到其中包含第VIII族金属和沸石载体的催化剂所在的反应区。 在一个实施方案中,碱可以在反应区内从引入到反应区的氮和氢原位形成。 在另一个实施方案中,将碱直接引入反应区。 反应区中的条件对减少催化剂是有效的。 然后可以将包含C8芳族化合物(例如二甲苯和乙苯)的料流进料至含有还原催化剂的反应区。 反应区可以在有效地异构化二甲苯和加氢脱烷基化乙苯的条件下操作。 二甲苯异构化过程中二甲苯损失降低,因为使用在包含碱和氢的气体存在下还原的催化剂。

    Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base
    44.
    发明授权
    Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base 有权
    在氢和碱的存在下还原催化剂使二甲苯异构化的方法

    公开(公告)号:US07851664B2

    公开(公告)日:2010-12-14

    申请号:US11959872

    申请日:2007-12-19

    Abstract: A xylene isomerization process includes introducing gas comprising hydrogen and a base to a reaction zone in which a catalyst comprising a Group VIII metal and a zeolite support resides. In one embodiment, the base may be formed in situ within the reaction zone from nitrogen and hydrogen that are introduced to the reaction zone. In another embodiment, the base is introduced directly to the reaction zone. The conditions in the reaction zone are effective to reduce the catalyst. A stream comprising C8 aromatics, e.g., xylenes and ethylbenzene may then be fed to the reaction zone containing the reduced catalyst. The reaction zone may be operated at conditions effective to isomerize the xylenes and hydrodealkylate the ethylbenzene. The xylene loss during the isomerization of the xylenes is lowered as a result of using the catalyst reduced in the presence of the gas comprising a base and hydrogen.

    Abstract translation: 二甲苯异构化方法包括将包含氢和碱的气体引入到其中包含第VIII族金属和沸石载体的催化剂所在的反应区。 在一个实施方案中,碱可以在反应区内从引入到反应区的氮和氢原位形成。 在另一个实施方案中,将碱直接引入反应区。 反应区中的条件对减少催化剂是有效的。 然后可以将包含C8芳族化合物(例如二甲苯和乙苯)的料流进料至含有还原催化剂的反应区。 反应区可以在有效地异构化二甲苯和加氢脱烷基化乙苯的条件下操作。 二甲苯异构化过程中二甲苯损失降低,因为使用在包含碱和氢的气体存在下还原的催化剂。

    Methods of making and using a selective hydrogenation catalyst
    46.
    发明授权
    Methods of making and using a selective hydrogenation catalyst 有权
    制备和使用选择性氢化催化剂的方法

    公开(公告)号:US07199076B2

    公开(公告)日:2007-04-03

    申请号:US10741800

    申请日:2003-12-19

    CPC classification number: C07C5/05 C07C5/09 C07C2523/66

    Abstract: In an embodiment, a method of hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon includes contacting the highly unsaturated hydrocarbon with a catalyst in the presence of hydrogen. The catalyst comprises palladium and an inorganic support having a surface area of from about 4.5 to about 20 m2/g, or alternatively 5 to 14.5 m2/g. The inorganic support may comprise α-alumina treated with a fluoride source. The palladium may be primarily disposed near the surface of the support. In addition, the catalyst may comprise silver distributed throughout the support. In another embodiment, a method of making the foregoing selective hydrogenation catalyst includes contacting a fluorine-containing compound with an inorganic support, heating the support, and adding palladium to the inorganic support. After adding palladium to the support, the support can then be heated again, followed by adding silver to and then heating the support once again.

    Abstract translation: 在一个实施方案中,将高度不饱和烃氢化成不饱和烃的方法包括在氢的存在下使高度不饱和烃与催化剂接触。 催化剂包括钯和无机载体,其表面积为约4.5至约20m 2 / g,或者5至14.5m 2 / g。 无机载体可以包括用氟化物源处理的α-氧化铝。 钯可以主要设置在支撑体的表面附近。 此外,催化剂可以包含分布在整个载体上的银。 在另一个实施方案中,制备上述选择性氢化催化剂的方法包括使含氟化合物与无机载体接触,加热载体,并向无机载体中加入钯。 向载体中加入钯后,再次加热载体,然后再加入银,然后再次加热载体。

    Methods and systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons
    47.
    发明授权
    Methods and systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons 有权
    通过高度不饱和烃的提取氢化制备单烯烃的方法和系统

    公开(公告)号:US07141709B2

    公开(公告)日:2006-11-28

    申请号:US10712686

    申请日:2003-11-13

    CPC classification number: C07C5/09 C07C5/05 C07C7/10

    Abstract: In some embodiments, methods of producing monoolefins include contacting an olefin stream with a polar solvent to extract a highly unsaturated hydrocarbon from the olefin stream, followed by contacting the polar solvent with a hydrogenation catalyst in the presence of hydrogen at conditions effective to hydrogenate the highly unsaturated hydrocarbon to a monoolefin. The monoolefin then desorbs from the polar solvent and enters the purified olefin stream, allowing the polar solvent to be recycled. In other embodiments, monoolefin production systems include an extraction-hydrogenation zone for performing the extraction and hydrogenating steps in situ. In alternative embodiments, the hydrogenation zone is disposed downstream from the extraction zone.

    Abstract translation: 在一些实施方案中,制备单烯烃的方法包括使烯烃物流与极性溶剂接触以从烯烃物流中提取高度不饱和的烃,然后在氢气存在下使极性溶剂与氢化催化剂接触,以有效地氢化高度 不饱和烃与单烯烃。 然后单烯烃从极性溶剂中解吸并进入纯化的烯烃流,使极性溶剂再循环。 在其它实施方案中,单烯烃生产系统包括用于原位进行萃取和氢化步骤的萃取氢化区。 在替代实施方案中,氢化区位于提取区的下游。

    Hydrocarbon upgrading process
    48.
    发明授权
    Hydrocarbon upgrading process 有权
    碳氢化合物升级过程

    公开(公告)号:US06737557B2

    公开(公告)日:2004-05-18

    申请号:US09801558

    申请日:2001-03-08

    Abstract: A process for recovering DCPD from a hydrocarbon feedstock comprising introducing the hydrocarbon feedstock to a first column, recovering an overhead stream from the first column comprising C9− hydrocarbons, recovering a bottom stream from the first column comprising C10+ hydrocarbons, feeding the bottom stream from the first column to a second column, recovering an overhead stream from the second column comprising DCPD, and recovering a bottom stream from the second column comprising fuel oil, wherein the two columns are sized and operated at defined conditions such as pressures, temperatures, reflux rates, and reboil rates.

    Abstract translation: 一种从烃原料回收DCPD的方法,包括将烃原料引入第一塔,从包含C 9烃的第一塔回收塔顶物流,从包含C10 +烃的第一塔回收底部物流,将来自 从第一塔到第二塔,从包括DCPD的第二塔回收塔顶流,以及从包括燃料油的第二塔回收底部流,其中两个塔的尺寸和操作在限定的条件下,例如压力,温度,回流速率 ,并重新燃起利率。

    Hydrocarbon hydrogenation catalyst and process
    50.
    发明授权
    Hydrocarbon hydrogenation catalyst and process 有权
    烃氢化催化剂和工艺

    公开(公告)号:US06417136B2

    公开(公告)日:2002-07-09

    申请号:US09398664

    申请日:1999-09-17

    Abstract: A catalyst composition is provided which can be used for hydrogenating a highly unsaturated hydrocarbon such as an alkyne or a diolefin. The catalyst composition contains palladium, a catalyst component of either silver or an alkali metal compound, or both silver and an alkali metal compound, and a metal aluminate catalyst support. Such metal aluminate catalyst support is prepared by a process of incorporating alumina with a metal component, preferably impregnating alumina with a melted metal component, to thereby provide a metal-incorporated alumina followed by drying and high temperature calcining to thereby provide a metal aluminate catalyst support. The catalyst composition disclosed can be used for hydrogenating a highly unsaturated hydrocarbon to a less unsaturated hydrocarbon. The process involves contacting a highly unsaturated hydrocarbon with a catalyst composition in the presence of hydrogen under a hydrogenation condition sufficient to effect a hydrogenation of the highly unsaturated hydrocarbon.

    Abstract translation: 提供了可用于氢化高度不饱和烃如炔烃或二烯烃的催化剂组合物。 催化剂组合物包含钯,银或碱金属化合物的催化剂组分,或银和碱金属化合物两者以及金属铝酸盐催化剂载体。 这种金属铝酸盐催化剂载体是通过将氧化铝与金属组分掺入的方法制备的,优选用熔融的金属组分浸渍氧化铝,从而提供掺入金属的氧化铝,随后进行干燥和高温煅烧,从而提供金属铝酸盐催化剂载体 。 所公开的催化剂组合物可用于将高度不饱和烃氢化为较不饱和的烃。 该方法包括在氢气存在下使氢不饱和烃与催化剂组合物接触,氢化条件足以进行高度不饱和烃的氢化。

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