Optimized process for inert fluorinated silanes
    41.
    发明授权
    Optimized process for inert fluorinated silanes 失效
    惰性氟化硅烷的优化方法

    公开(公告)号:US5453528A

    公开(公告)日:1995-09-26

    申请号:US343322

    申请日:1994-11-21

    IPC分类号: C07F7/12 C07F7/08 C07F7/14

    摘要: The present invention relates to an improved method for preparing a fluorinated silane having the formulaR.sup.1.sub.4 Si (I)or the formulaR.sup.2.sub.3 Si(R.sup.3 SiR.sup.4.sub.2).sub.z R.sup.3 SiR.sup.2.sub.3(II)said method comprising reacting the corresponding halide-functional or alkoxy-functional silane with lithium aluminum hydride or sodium borohydride to form a hydride-functional silane and then reacting the latter with a vinyl-terminated fluorotelomer or an allyl-terminated fluorotelomer, wherein at least three R.sub.1 of said silane (I), at least two of the R.sup.2 and at least one R.sup.4 of said silane (II) are selected from derivatives of fluorotelomers or fluorocotelomers, z has an average value of 0 to 4 and R.sup.3 is a derivative of an alkylene-terminated telechelic divalent telomer or cotelomer.

    摘要翻译: 本发明涉及制备具有式R 14 Si(I)或式R 23 Si(R 3 SiR 42)z R 3 SiR 23(II)的氟化硅烷的改进方法,所述方法包括使相应的卤化物官能或烷氧基官能的硅烷与氢化铝锂或 硼氢化钠以形成氢化物官能的硅烷,然后使其与乙烯基封端的荧光调聚物或烯丙基封端的荧光调聚物反应,其中所述硅烷(I)的至少三个R1,R2和至少一个R 4 的所述硅烷(II)选自荧光酮或氟代托他物的衍生物,z的平均值为0至4,并且R 3为亚烷基封端的远电子二价调聚物或聚苯乙烯的衍生物。

    Polymer Composition
    46.
    发明申请
    Polymer Composition 有权
    聚合物组成

    公开(公告)号:US20070218207A1

    公开(公告)日:2007-09-20

    申请号:US10572944

    申请日:2004-09-22

    IPC分类号: C08L27/08 C09D127/08

    摘要: Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (01) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (Ml) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CeF26+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with RI being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.

    摘要翻译: 聚合物组合物包括:1)包含至少50重量%的衍生自烯属不饱和单体(M1)的单体单元的聚合物(P1),和2)至少包含至少一个共低聚物(01):a) 组分(A)包含至少一种与聚合物(P1)所基于的单体(M1)相同的单体单元,和b)包含至少一种单体单元(m2)的组分(B),衍生自 带有至少一个选自以下基团的烯键式不饱和单体:具有介于6和30之间的-C≡AH 2a + - (CH 2 - ) - - - - - - - - - - - - - (2)其中b在1和11之间,c更大 超过或等于5; - (CH 2)2 - (Si(CH 3)2-O) - (CH 2)2 - 其中d在1和11之间,e在1和1000之间; -COOH; -SO 3 H,以及R 1为氢原子或含有1至11个碳原子的烷基的膦酸酯基-PO(OH)(OR 1)。

    Polymerization in the presence of a stable free radical and of a free radical initiator
    49.
    发明授权
    Polymerization in the presence of a stable free radical and of a free radical initiator 失效
    在稳定的自由基和自由基引发剂的存在下进行聚合

    公开(公告)号:US06346589B1

    公开(公告)日:2002-02-12

    申请号:US08853240

    申请日:1997-05-09

    IPC分类号: C08F434

    CPC分类号: C08F4/38

    摘要: The invention relates to a process comprising a stage of polymerization or copolymerization of at least one polymerizable or copolymerizable monomer by a radical mechanism in the presence of a stable free radical and of an initiator of formula: R1—O—O—R2 wherein R1 and R2, which can be identical or different, represent an alkyl, aryl, alkylaryl or aralkyl radical comprising, for example, from 1 to 20 carbon atoms. The process is fast, allows the initiator to act more efficiently and results in polymers or copolymers exhibiting a low yellowing index.

    摘要翻译: 本发明涉及一种方法,其包括在稳定的自由基和下式的引发剂存在下,通过自由基机理聚合或共聚至少一种可聚合或可共聚的单体:其中R1和R2可以相同或相同, 不同的是,表示包括例如1至20个碳原子的烷基,芳基,烷基芳基或芳烷基。 该方法快速,允许引发剂更有效地起作用并导致显示低黄变指数的聚合物或共聚物。

    Water-soluble associative triblock copolymers
    50.
    发明授权
    Water-soluble associative triblock copolymers 失效
    水溶性缔合三嵌段共聚物

    公开(公告)号:US5798421A

    公开(公告)日:1998-08-25

    申请号:US728051

    申请日:1996-10-09

    CPC分类号: C08F293/00 C07C255/65

    摘要: This invention relates to copolymers of molecular mass of between 5,000 and 300,000, consisting of a hydrophilic central portion, for example a polyacrylamide chain, and of hydrophobic ends the hydrophobicity of which is comparable with that of alkyl groups containing 4-20 carbons. They are produced by polymerization of hydrophilic monomers with the aid of initiators, for example of azo type, the hydrophobic residues of which will constitute the hydrophobic ends of the final copolymer. These copolymers are useful for rheological control of aqueous and/or pigmented compositions, like paints.

    摘要翻译: 本发明涉及分子量为5,000至300,000的共聚物,由亲水中心部分(例如聚丙烯酰胺链)和疏水末端组成,其疏水性与含有4-20个碳的烷基相当。 它们通过借助于引发剂,例如偶氮型的亲水性单体的聚合制备,其疏水性残基将构成最终共聚物的疏水末端。 这些共聚物可用于水性和/或着色组合物(如油漆)的流变学控制。