摘要:
The present invention relates to an improved method for preparing a fluorinated silane having the formulaR.sup.1.sub.4 Si (I)or the formulaR.sup.2.sub.3 Si(R.sup.3 SiR.sup.4.sub.2).sub.z R.sup.3 SiR.sup.2.sub.3(II)said method comprising reacting the corresponding halide-functional or alkoxy-functional silane with lithium aluminum hydride or sodium borohydride to form a hydride-functional silane and then reacting the latter with a vinyl-terminated fluorotelomer or an allyl-terminated fluorotelomer, wherein at least three R.sub.1 of said silane (I), at least two of the R.sup.2 and at least one R.sup.4 of said silane (II) are selected from derivatives of fluorotelomers or fluorocotelomers, z has an average value of 0 to 4 and R.sup.3 is a derivative of an alkylene-terminated telechelic divalent telomer or cotelomer.
摘要翻译:本发明涉及制备具有式R 14 Si(I)或式R 23 Si(R 3 SiR 42)z R 3 SiR 23(II)的氟化硅烷的改进方法,所述方法包括使相应的卤化物官能或烷氧基官能的硅烷与氢化铝锂或 硼氢化钠以形成氢化物官能的硅烷,然后使其与乙烯基封端的荧光调聚物或烯丙基封端的荧光调聚物反应,其中所述硅烷(I)的至少三个R1,R2和至少一个R 4 的所述硅烷(II)选自荧光酮或氟代托他物的衍生物,z的平均值为0至4,并且R 3为亚烷基封端的远电子二价调聚物或聚苯乙烯的衍生物。
摘要:
(Meth)acrylic/glutarimide copolymers, well suited, e.g., for optical applications, having enhanced glass transition temperatures (Tg), are prepared by salifying the acid functions of (meth)acrylic ester/(meth)acrylic acid copolymers, and then imidifying such "intermediate" salified copolymers into the subject (meth)acrylic/glutarimide polymers.
摘要:
The present application relates to a method for preparing epoxy resins from a mixture of epoxidized phenolic compounds, wherein said epoxidized phenolic compounds are obtained by the epoxidation of natural phenolic compounds selected from the group comprising simple phenol, acid-phenol, coumarin, naphthoquinone, stillbenoid, flavonoid, isoflavanoid, anthocyanin, condensed tannin and hydrolyzable tannin.
摘要:
A method for forming polymer carbon nanotube composites, the method comprising: contacting carbon nanotubes with ozone to functionalize the sidewalls of the carbon nanotubes with at least one oxygen moiety; and reacting the functionalized carbon nanotubes with at least one monomer or at least one polymer or copolymer to attach polymer chains to the sidewalls of the carbon nanotubes.
摘要:
A method for encapsulating an active principle by dispersing the active principle in a supercritical fluid by adding a surfactant to the fluid. The surfactant is a block copolymer having at least one CO2-philic block and at least one nonionic hydrophilic block.
摘要:
Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (01) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (Ml) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CeF26+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with RI being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.
摘要:
Novel biodegradable polymers consisting of a biodegradable core bound to at least two carboxylic polyacid-based branches via a bond capable of being broken by hydrolysis or by oxidation are described. Biodegradable detergent compositions containing such polymers are also described.
摘要:
A method of continuous application of a graded index plastics optical fiber in which the refractive index is highest in the center and decreases progressively towards the periphery, said fiber having a plurality of layers of resin deposited concentrically, the method comprising making a plurality of mixtures, each mixture comprising at least one polymer P and a reactive diluting agent including at least two monomers, then depositing said mixtures in the form of coaxial layers, allowing interdiffusing to take place between the layers, and finally crosslinking the polymer P and/or the reactive diluting agent.
摘要:
The invention relates to a process comprising a stage of polymerization or copolymerization of at least one polymerizable or copolymerizable monomer by a radical mechanism in the presence of a stable free radical and of an initiator of formula: R1—O—O—R2 wherein R1 and R2, which can be identical or different, represent an alkyl, aryl, alkylaryl or aralkyl radical comprising, for example, from 1 to 20 carbon atoms. The process is fast, allows the initiator to act more efficiently and results in polymers or copolymers exhibiting a low yellowing index.
摘要:
This invention relates to copolymers of molecular mass of between 5,000 and 300,000, consisting of a hydrophilic central portion, for example a polyacrylamide chain, and of hydrophobic ends the hydrophobicity of which is comparable with that of alkyl groups containing 4-20 carbons. They are produced by polymerization of hydrophilic monomers with the aid of initiators, for example of azo type, the hydrophobic residues of which will constitute the hydrophobic ends of the final copolymer. These copolymers are useful for rheological control of aqueous and/or pigmented compositions, like paints.