STABILIZATION OF POLYAMIDE WITH COPPER-BASED METAL ORGANIC FRAMEWORKS
    41.
    发明申请
    STABILIZATION OF POLYAMIDE WITH COPPER-BASED METAL ORGANIC FRAMEWORKS 审中-公开
    聚合物与铜基金属有机骨架的稳定性

    公开(公告)号:US20160060434A1

    公开(公告)日:2016-03-03

    申请号:US14783531

    申请日:2014-04-07

    Applicant: BASF SE

    Abstract: The invention relates to a method for manufacturing of a stabilized polyamide-containing composition, which contains at least 20% by weight of polyamide, which comprises the steps of incorporating of a metal organic framework, which is a copper-based metal organic framework comprising metal ions, which are copper(II)-ions, and a C6-C24 aromatic hydrocarbon, which is substituted with at least two carboxylate groups, wherein two of the at least two carboxylate groups are forming coordinative bonds to the metal ions, into a polyamide-containing composition, which contains at least 20% by weight of polyamide, to obtain a mixture for molding, which contains at least 20% by weight of polyamide; and heating of the obtained mixture for molding comprising the polyamide-containing composition and the metal organic framework to a temperature between 170° C. and 380° C.

    Abstract translation: 本发明涉及含有至少20重量%聚酰胺的含稳定的含有聚酰胺的组合物的制造方法,该方法包括以下步骤:引入金属有机骨架,其为包含金属的铜基金属有机骨架 离子(它们是铜(II))和被至少两个羧酸酯基团取代的C 6 -C 24芳族烃,其中两个至少两个羧酸酯基团与金属离子形成配位键,形成聚酰胺 含有至少20重量%的聚酰胺的组合物,以获得含有至少20重量%的聚酰胺的模塑混合物; 并将得到的含有聚酰胺的组合物和金属有机骨架的模塑混合物加热至170℃至380℃的温度。

    PROCESS FOR RECOVERING 3-METHYLBUT-3-EN-1-OL
    48.
    发明申请

    公开(公告)号:US20200239394A1

    公开(公告)日:2020-07-30

    申请号:US16636474

    申请日:2018-08-10

    Applicant: BASF SE

    Abstract: The present invention relates to a process for recovering 3-methylbut-3-en-1-ol from a feed stream F1 comprising 3-methylbut-3-en-1-ol, one or more solvents, water, and isobutene, wherein 3-methylbut-3-en-1-ol, the one or more solvents and water are separated from isobutene by distillation, the process comprising subjecting the feed stream F1 to distillation conditions in a distillation unit, obtaining a bottoms stream B1 which is enriched in -methylbut-3-en-1-ol, in the one or more solvents and in water compared to the feed stream F1 subjec The present invention relates to a process for recovering 3-methylbut-3-en-1-ol from a feed stream F1 comprising 3-methylbut-3-en-1-ol, one or more solvents, water, and isobutene, wherein 3-methylbut-3-en-1-ol, the one or more solvents and water are separated from isobutene by distillation, the process comprising subjecting the feed stream F1 to distillation conditions in a distillation unit, obtaining a bottoms stream B1 which is enriched in -methylbut-3-en-1-ol, in the one or more solvents and in water compared to the feed stream F1 subjected to distillation conditions, and a top stream T1 which is enriched in isobutene, further subjecting the bottoms stream B1 to distillation conditions in a second distillation unit and obtaining a bottoms stream B2 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B1 and a top stream T2 which is enriched in water compared to the bottoms stream B1, further subjecting the bottoms stream B2 to distillation conditions in a third distillation unit and obtaining a top stream T3 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B2 and a bottoms stream B3. ted to distillation conditions, and a top stream T1 which is enriched in isobutene, further subjecting the bot-toms stream B1 to distillation conditions in a second distillation unit and obtaining a bottoms stream B2 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B1 and a top stream T2 which is enriched in water compared to the bottoms stream B1, further subjecting the bottoms stream B2 to distillation conditions in a third distillation unit and obtaining a top stream T3 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B2 and a bottoms stream B3.

    SYNTHESIS OF A BORON-CONTAINING ZEOLITE WITH AN MWW FRAMEWORK STRUCTURE

    公开(公告)号:US20190177174A1

    公开(公告)日:2019-06-13

    申请号:US16202918

    申请日:2018-11-28

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises(a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material, (c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I) R1R2R3N  (I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

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