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公开(公告)号:US20200347192A1
公开(公告)日:2020-11-05
申请号:US16962659
申请日:2019-01-28
Applicant: BASF SE
Inventor: Stephan Bauer , Katrin Baumann , Markus Toennessen , Thomas Daniel , Hanno Rüdiger Wolf
Abstract: A method of pneumatically conveying superabsorbent particles, wherein the superabsorbent particles have been admixed with an aqueous wax dispersion prior to the pneumatic conveying, the wax has a glass transition temperature of at least 65° C. and, based on the untreated super-absorbent particles, from 0.020% to 0.20% by weight of wax has been used.
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公开(公告)号:US20170281425A1
公开(公告)日:2017-10-05
申请号:US15471835
申请日:2017-03-28
Applicant: BASF SE
Inventor: Norbert Herfert , Somjate Sonkaew , Thomas Daniel , Tanyatom Sitkhunthod
IPC: A61F13/535 , A61F13/539 , B01J20/26
CPC classification number: A61F13/535 , A61F13/534 , A61F13/539 , A61F2013/530481 , A61F2013/530489 , A61F2013/530591 , A61F2013/53908 , A61F2013/53991 , B01J20/261 , B01J20/267
Abstract: Absorbent core and an absorbent article respectively with improved properties, especially rewet performance, are disclosed. The absorbent core contains at least two layers, wherein each layer has from 0 to 10% by weight fibrous material and from 90 to 100% by weight water-absorbent polymer particles, based on the sum of water-absorbent polymer particles and fibrous material. The surface crosslinked water absorbent polymer particles within the upper layer have a sphericity of at least 0.89 and the absorbent core shows a CRCAP/TACAP ratio of at least 0.65.
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公开(公告)号:US20170281422A1
公开(公告)日:2017-10-05
申请号:US15471281
申请日:2017-03-28
Applicant: BASF SE
Inventor: Norbert Herfert , Somjate Sonkaew , Thomas Daniel , Tanyatorn Sitkhunthod
IPC: A61F13/53 , A61L15/58 , A61L15/60 , B32B5/02 , A61L15/22 , B32B37/12 , B32B7/12 , B32B38/00 , A61F13/15 , A61L15/24
Abstract: An absorbent core and an absorbent article respectively with improved properties, especially rewet performance, are disclosed. The absorbent core has at least two layers, wherein each layer comprising from 0 to 10% by weight fibrous material and from 90 to 100% by weight water-absorbent polymer particles, based on the sum of water-absorbent polymer particles and fibrous material. The surface-postcrosslinked water absorbent polymer particles within the upper layer have a sphericity of at least 0.89 and a CRC of at least 34 g/g. Preferably the water-absorbent polymer particles have a sphericity of at least 0.89 and the sum of the CRC and AUL (0.3 psi, 21 g cm−2) (EDANA 442.2-02) of the water absorbent polymer particles is at least 65 g/g.
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公开(公告)号:US09725827B2
公开(公告)日:2017-08-08
申请号:US14430932
申请日:2013-09-23
Applicant: BASF SE
Inventor: Thomas Daniel , Xiaomin Zhang , Kathleen H. Goebel
IPC: A61F13/53 , A61L15/24 , D01F6/16 , D06M10/00 , D01D5/00 , D01D10/00 , D01F6/02 , A61L15/60 , D01F6/26 , D06M101/18 , D06M101/26
CPC classification number: D01F6/16 , A61F2013/530613 , A61F2013/53062 , A61L15/24 , A61L15/60 , D01D5/0007 , D01D5/003 , D01D10/00 , D01F6/02 , D01F6/26 , D06M10/001 , D06M2101/18 , D06M2101/26 , D10B2321/08 , D10B2509/00 , D10B2509/02
Abstract: The invention relates to a process for producing water-absorbing crosslinked polymer fibers, especially micro- or nanofibers, by spinning process, especially electrospinning process and to fibers obtainable by this process.
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公开(公告)号:US20130256593A1
公开(公告)日:2013-10-03
申请号:US13853425
申请日:2013-03-29
Applicant: BASF SE
Inventor: Norbert Herfert , Thomas Daniel , Klaus Dieter Hörner
CPC classification number: B01J20/267 , A61L15/56 , A61L15/60 , B01J20/3021 , C08F8/40 , C08F220/06 , C08K5/0025 , C08K5/42 , C08K5/5317 , C08K5/5353
Abstract: A superabsorbent obtainable by a process for producing superabsorbents by polymerizing a monomer solution comprising a) at least one ethylenically unsaturated monomer which bears acid groups and is optionally present at least partly in salt form, b) at least one crosslinker, c) at least one initiator, d) optionally one or more ethylenically unsaturated monomers copolymerizable with the monomers mentioned under a), e) optionally one or more water-soluble polymers, the process further comprising drying of the resulting polymer and optionally grinding of the dried polymer and sieving of the ground polymer and optionally surface postcrosslinking of the dried and optionally ground and sieved polymer, wherein at least one sulfonic acid derivative is added to the monomer mixture and/or to the polymer prior to the drying, and at least one phosphonic acid derivative is added to the polymer after the drying or optionally after the surface postcrosslinking, exhibits improved stability to discoloration in the course of storage at elevated temperatures or under elevated air humidity.
Abstract translation: 通过聚合单体溶液来生产超吸收剂的方法可获得的超吸收剂,该单体溶液包含:a)至少一种带有酸基并且任选以至少部分为盐形式存在的烯属不饱和单体,b)至少一种交联剂,c)至少一种 引发剂,d)任选的一种或多种烯属不饱和单体,其可与a),e)所述的单体共聚,e)任选的一种或多种水溶性聚合物,该方法还包括干燥所得聚合物和任选地研磨干燥聚合物和筛分 研磨的聚合物和任选地表面后干燥和任选研磨和筛分的聚合物的后交联,其中在干燥之前将至少一种磺酸衍生物加入到单体混合物和/或聚合物中,并加入至少一种膦酸衍生物 在干燥之后或任选地在表面后交联之后的聚合物表现出改善的变色稳定性 在高温或高空气湿度下储存过程中。
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公开(公告)号:US20130130895A1
公开(公告)日:2013-05-23
申请号:US13682897
申请日:2012-11-21
Applicant: BASF SE
Inventor: Norbert Herfert , Thomas Daniel
CPC classification number: B01J20/08 , A61L15/18 , A61L15/42 , A61L15/60 , B01J20/267 , B01J20/28059 , B01J20/28061 , B01J20/3085 , B01J20/3231 , B01J20/3265 , B01J2220/46 , B01J2220/68
Abstract: Superabsorbents comprising pyrogenic aluminum oxide exhibit a low caking tendency coupled with good absorption properties and rapid water absorption.
Abstract translation: 包含热解法氧化铝的超吸收剂表现出低结块趋势,并具有良好的吸收性能和快速吸水性。
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公开(公告)号:US12110351B2
公开(公告)日:2024-10-08
申请号:US17717598
申请日:2022-04-11
Applicant: BASF SE
Inventor: Kristine Hartnagel , Thomas Gieger , Thomas Daniel , Marcus Schroeder , Michelle Morano , Nathaniel Troy Greene
IPC: C08F2/22 , A61L15/60 , B01J20/26 , B01J20/28 , C08F2/01 , C08F2/44 , C08F6/14 , C08F220/06 , C08J3/12 , C08J3/24 , C08K3/011 , C08K3/30 , C08K5/5317
CPC classification number: C08F2/22 , A61L15/60 , B01J20/261 , B01J20/28047 , C08F2/01 , C08F2/44 , C08F6/14 , C08F220/06 , C08J3/12 , C08J3/245 , C08K3/011 , C08K3/30 , C08K5/5317 , B01J2220/68 , C08J2333/02 , C08K2003/3081
Abstract: A process for producing superabsorbents, comprising polymerization of a monomer solution and thermal surface postcrosslinking, wherein the monomer solution comprises at least 0.75% by weight of a hydroxyphosphonic acid or salts thereof, calculated on the basis of the total amount of monomer used, and at least 0.09% by weight of aluminum cations, calculated on the basis of the total amount of polymer particles used, is added to the polymer particles before, during or after the thermal surface postcrosslinking.
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公开(公告)号:US11911249B2
公开(公告)日:2024-02-27
申请号:US16483645
申请日:2018-01-29
Applicant: BASF SE
Inventor: Thomas Daniel , Christophe Bauduin , Katrin Baumann , Katarzyna Dobrosielska-Oura
IPC: A61F13/53 , A61F13/15 , A61F13/537
CPC classification number: A61F13/53 , A61F13/537 , A61F2013/15406 , A61F2013/1556 , A61F2013/15959 , A61F2013/15967 , A61F2013/15983 , A61F2013/530591 , A61F2013/530613 , A61F2013/5307 , A61F2013/530788
Abstract: Provided herein are fluid-absorbent articles, fluid absorbent cores, and fluid-absorbent mixtures with improved properties, especially rewet performance and liquid acquisition. The fluid-absorbent article includes (A) an upper liquid-pervious sheet, (B) a lower liquid-impervious sheet, (C) a fluid-absorbent core including from 60 to 20% by weight fibrous material and from 40 to 80% by weight of at least a first type of water-absorbent polymer particles, (G) and at least a second type of water-absorbent polymer particles (H) based on the sum of water-absorbent polymer particles and fibrous material, (D) an optional acquisition-distribution layer (D) between (A) and (C), (F) other optional components, wherein the first type of water absorbent polymer particles (G) of the fluid-absorbent core (C) have a SFC of at least 20×10−7 cm3·s/g, and wherein the at least second type of water-absorbent polymer particles (H) of the fluid-absorbent core have a sphericity of at least 0.80.
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公开(公告)号:US11859059B2
公开(公告)日:2024-01-02
申请号:US16962659
申请日:2019-01-28
Applicant: BASF SE
Inventor: Stephan Bauer , Katrin Baumann , Markus Toennessen , Thomas Daniel , Hanno Rüdiger Wolf
CPC classification number: C08J3/124 , A61L15/60 , B65G53/10 , C08J2391/06 , C08L23/0869
Abstract: A method of pneumatically conveying superabsorbent particles, wherein the superabsorbent particles have been admixed with an aqueous wax dispersion prior to the pneumatic conveying, the wax has a glass transition temperature of at least 65° C. and, based on the untreated superabsorbent particles, from 0.020% to 0.20% by weight of wax has been used.
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公开(公告)号:US20220317006A1
公开(公告)日:2022-10-06
申请号:US17616705
申请日:2020-06-24
Applicant: BASF SE
Inventor: Thomas Daniel , Markus Toennessen , Christophe Bauduin
Abstract: In a method of measuring parameters of superabsorbents, the absorption capacity of superabsorbents is determined under pressure, by reducing the pressure applied to a sample of the superabsorbent stepwise and determining the absorption capacity at each pressure. In addition, the rise in absorption capacity after a reduction in pressure is measured as a function of time and this is used to calculate the swelling constant k or the characteristic swelling time τ. Swelling constant or characteristic swelling time or the magnitude of the difference in absorption capacity at two different pressures are used to determine further parameters of the superabsorbent.
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