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41.发明授权Crystalline (metallo) aluminophosphate composition MCM-40, its synthesis and usage in hydrocarbon conversion 失效结晶（金属）磷酸铝组合物MCM-40，其在烃转化中的合成和用途
公开(公告)号：US5104495A
公开(公告)日：1992-04-14
申请号：US625403
申请日：1990-12-11
摘要： This invention relates to a new crystalline composition MCM-40, to a method for synthesizing said crystalline composition using diaminocyclohexane as a directing agent and to use of said crystalline composition as a catalyst component for organic compound, e.g. hydrocarbon compound, conversion.
摘要翻译： 本发明涉及一种新的结晶组合物MCM-40，涉及使用二氨基环己烷作为引导剂合成所述结晶组合物的方法，以及使用所述结晶组合物作为有机化合物的催化剂组分，例如， 烃化合物，转化。
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公开(公告)号：US5001094A
公开(公告)日：1991-03-19
申请号：US282534
申请日：1988-12-12
摘要： A spent acidic zeolite catalyst, e.g., ZSM-5 obtained from a hydrocarbon conversion process such as a catalytic dewaxing operation, is reactivated by contacting the spent catalyst with aqueous alkali metal carbonate and/or alkaline earth metal carbonate.
摘要翻译： 通过使废催化剂与碱金属碳酸盐水溶液和/或碱土金属碳酸盐接触，将废酸性沸石催化剂，例如由烃转化方法如催化脱蜡操作获得的ZSM-5再活化。
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公开(公告)号：US4871702A
公开(公告)日：1989-10-03
申请号：US246391
申请日：1988-09-19
CPC分类号： B01J29/90 , B01J29/40 , C10G11/05 , C10G3/49 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/65 , B01J29/70 , C10G2300/703 , C10G2300/807 , C10G2400/30 , Y02P30/20
摘要： Alumina-composited zeolite catalysts are activated by contact with an aqueous ammonium solution under ammonia gas pressure such that a pH of at least about 10 is maintained in the solution. The treated zeolite may thereafter be calcined without prior ammonium-exchange to provide the zeolite in the hydrogen form.
摘要翻译： 通过在氨气压力下与铵水溶液接触来活化氧化铝复合沸石催化剂，使得溶液中保持至少约10的pH。 然后处理的沸石可以在没有先前的铵交换的情况下煅烧以提供氢形式的沸石。
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公开(公告)号：US4870192A
公开(公告)日：1989-09-26
申请号：US918683
申请日：1986-10-14
IPC分类号： C07C51/285 , C07D315/00
CPC分类号： C07D315/00 , C07C51/285
摘要： This invention provides process embodiments for shape-selective oxidation of cyclic ketones to lactone and/or omega-hydroxycarboxylic acid products in the presence of a zeolite catalyst composition such as ZSM-5 or zeolite Beta.Cyclohexanone can be converted to epsilon-caprolactone or 6-hydroxycaproic acid as a main product under selected conditions.
摘要翻译： 本发明提供了在沸石催化剂组合物如ZSM-5或沸石ββ存在下将环酮形式选择性氧化成内酯和/或ω-羟基羧酸产物的方法实施方案。 环己酮可以在选定的条件下转化为ε-己内酯或6-羟基己酸作为主要产物。
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公开(公告)号：US4837398A
公开(公告)日：1989-06-06
申请号：US140359
申请日：1988-01-04
申请人： Clarence D. Chang , Cynthia T. Chu , Carol S. Lee
发明人： Clarence D. Chang , Cynthia T. Chu , Carol S. Lee
IPC分类号： B01J29/65 , B01J29/40 , B01J29/70 , B01J29/90 , C07C1/00 , C07C1/20 , C07C1/24 , C07C67/00 , C10G3/00 , C10G11/05 , C10G73/38
CPC分类号： B01J29/40 , B01J29/90 , C10G11/05 , C10G3/48 , C10G3/49 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/65 , B01J29/70 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/703 , C10G2300/807 , C10G2400/20 , C10G2400/30 , Y02P30/20
摘要： Alumina-composited zeolite catalysts are activated by contact with an aqueous ammonium solution under ammonia gas pressure such that a pH of at least about 8 is maintained in the solution. The treated zeolite may thereafter be calcined without prior ammonium-exchange to provide the zeolite in the hydrogen form.
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公开(公告)号：US4790928A
公开(公告)日：1988-12-13
申请号：US153395
申请日：1988-02-08
CPC分类号： B01J29/40 , C07C1/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/40
摘要： The acidity of a zeolite catalyst is reduced by calcination in an essentially water-free atmosphere at temperatures above 700.degree. C., preferably from 725.degree. to 800.degree. C., to reduce the alpha value to less than about 10 percent of its original value. The low acidity catalysts produced in this way may be used for conversions requiring low acidity, shape selective catalysis, including dewaxing. The calcined, low acidity catalysts exhibit improved dewaxing activity.
摘要翻译： 沸石催化剂的酸度通过在高于700℃，优选725℃至800℃的温度下在基本无水的气氛中煅烧而降低，以将α值降低到其原始值的约10％ 。 以这种方式生产的低酸性催化剂可用于需要低酸度，形状选择性催化（包括脱蜡）的转化。 煅烧的低酸度催化剂表现出改善的脱蜡活性。
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公开(公告)号：US4754096A
公开(公告)日：1988-06-28
申请号：US72319
申请日：1987-07-13
IPC分类号： C10M177/00 , B01J29/40 , C10G50/02 , C10M107/06 , C10M143/04 , C10N20/02 , C10N70/00 , C07C2/02 , C07C2/04
CPC分类号： C10G50/02
摘要： A process for the production of lubricant oil range hydrocarbon having increased viscosity index by oligomerization of lower olefins over medium pore shape selective acid zeolite catalyst. The preferred oligomerization process is conducted using 50 ppm to 5 weight percent of water vapor as cofeed, based on olefin and acid ZSM-5 zeolite.
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48.发明授权
公开(公告)号：US4665248A
公开(公告)日：1987-05-12
申请号：US787184
申请日：1985-10-15
申请人： Clarence D. Chang , Joseph N. Miale
发明人： Clarence D. Chang , Joseph N. Miale
CPC分类号： B01J29/40 , B01J29/7007 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and an inorganic oxide with water in the presence of an alkali metal cation.Specifically, the catalyst is prepared by contacting a mixture of a crystalline zeolite having a silica to alumina ratio above 12 and a Constraint Index between about 1 and about 12, and a solid source of aluminum with liquid water in the presence of an activating amount of an alkali metal cation and under a combination of conditions including a temperature up to about 370.degree. C. for less than about an hour to about 100 hours to induce increased activity to the zeolite.
摘要翻译： ZSM-5型沸石的离子交换能力和酸催化活性通过在碱金属阳离子存在下处理沸石和无机氧化物的物理混合物与水而增加。 具体地说，催化剂是通过使二氧化硅与氧化铝之比高于12的结晶沸石和约1至约12的约束指数的混合物与固体的铝水溶液接触而制备的， 碱金属阳离子，并且在包括温度高达约370℃的条件的组合下反应少于约1小时至约100小时以诱导沸石活性增加。
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公开(公告)号：US4605637A
公开(公告)日：1986-08-12
申请号：US693444
申请日：1985-01-22
申请人： Clarence D. Chang , Joseph N. Miale
发明人： Clarence D. Chang , Joseph N. Miale
CPC分类号： B01J29/40 , B01J29/7007 , B01J2229/26 , B01J2229/36 , B01J2229/42 , Y10S423/22 , Y10S423/27
摘要： There is provided a process for activating a zeolite with an aluminum phosphate material. The process comprises hydrothermally treating an intimate mixture of the zeolite and an effective amount of aluminum phosphate activating agent in contact with an aqueous liquid phase under reaction conditions to increase the cracking activity of the mixture. Examples of zeolites which may be activated include low acidity zeolites such as boron-containing ZSM-5, boron-containing zeolite Beta and high silica ZSM-5. The aluminum phosphate may be in the form of a microporous, crystalline framework material such as AlPO.sub.4 -5.
摘要翻译： 提供了用磷酸铝材料活化沸石的方法。 该方法包括在反应条件下水热处理沸石和有效量的磷酸铝活化剂与水性液相接触的紧密混合物，以增加混合物的裂解活性。 可以被活化的沸石的实例包括低酸性沸石，例如含硼的ZSM-5，含硼沸石β和高二氧化硅ZSM-5。 磷酸铝可以是微孔，结晶骨架材料如AlPO 4 -5的形式。
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公开(公告)号：US4594333A
公开(公告)日：1986-06-10
申请号：US646200
申请日：1984-08-31
CPC分类号： B01J29/40 , B01J20/186 , B01J2229/26 , B01J2229/42
摘要： The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and a solid source of aluminum with water in the presence of an alkali metal compound activating agent and an alkali metal salt of a mineral acid.
摘要翻译： ZSM-5型沸石的离子交换能力和酸催化活性通过在碱金属化合物活化剂和碱金属盐存在下，通过处理沸石和固体铝源的物理混合物与水而增加 的无机酸。
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