公开(公告)号：US4244839A

公开(公告)日：1981-01-13

申请号：US955526

申请日：1978-10-30

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  B01J31/12 ,  B01J23/28 ,  B01J23/88 ,  B01J27/04

CPC classification number: B01J37/086 ,  B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  Y10S208/951

Abstract: High surface area metal-containing catalysts are prepared by dispersing a thermally decomposable metal compound in a hydrocarbon oil having a Conradson carbon content of up to about 50 weight percent, the thermally decomposable metal compound being added in an amount sufficient to obtain a specified ratio of atoms of Conradson carbon of the oil chargestock to atoms of metal constituent of the thermally decomposable compound, heating the compound in the presence of a gas comprising either hydrogen or hydrogen sulfide or hydrogen and hydrogen sulfide to form a solid high surface area catalyst within the oil, and recovering the resulting high surface area catalyst. The metal constituent of the thermally decomposable metal compound may be a metal of Groups II, III, IV, V, VIB, VIIB, VIII or mixtures thereof. The high surface area solids are suitable as catalysts, catalyst supports or catalyst components for use in hydrocarbon treating processes and in chemical processes.

Abstract translation: 通过将可热分解的金属化合物分散在具有高达约50重量％的康拉逊碳含量的烃油中制备高表面积含金属的催化剂，所述可热分解的金属化合物的添加量足以获得规定的比例 将油料的康拉德森碳的原子与可热分解的化合物的金属成分的原子一起加热，在包含氢或硫化氢或氢气和硫化氢的气体存在下加热化合物，以在油中形成固体高表面积催化剂 ，并回收得到的高表面积催化剂。 可热分解的金属化合物的金属组分可以是II，III，IV，V，VIB，VIIB，VIII族的金属或其混合物。 高表面积固体适合用作催化剂，催化剂载体或用于烃处理方法和化学方法的催化剂组分。

公开(公告)号：US4178227A

公开(公告)日：1979-12-11

申请号：US913394

申请日：1978-06-07

Applicant: William J. Metrailer ,  Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： William J. Metrailer ,  Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: C10B55/10 ,  C10G1/00 ,  C10G1/08 ,  C10G47/20 ,  C10G69/06 ,  C10J3/54 ,  C10G37/00

CPC classification number: C10G47/20 ,  C10B55/10 ,  C10G1/002 ,  C10G1/08 ,  C10G1/086 ,  C10G69/06 ,  C10J3/482 ,  C10J3/54 ,  C10J3/721 ,  C10J3/78 ,  C10J3/84 ,  C10J2300/0906 ,  C10J2300/093 ,  C10J2300/0943 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1807 ,  C10J2300/1884 ,  C10J2300/1892

Abstract: A combination slurry hydroconversion, coking and coke gasification process is provided wherein solid fines having an average particle size of less than 10 microns in diameter or the ashes thereof recovered from a gaseous product derived from the coke gasification are used as a catalyst in the hydroconversion stage in combination with a catalyst produced from an oil soluble metal compound in situ in the chargestock of the hydroconversion zone.

Abstract translation: 提供了一种组合浆料加氢转化，焦化和焦炭气化方法，其中直径小于10微米的固体细粉或其衍生自焦炭气化的气态产物回收的灰分在加氢转化阶段用作催化剂 与在加氢转化区的原料中原位由油溶性金属化合物制备的催化剂组合。

公开(公告)号：US4134825A

公开(公告)日：1979-01-16

申请号：US847898

申请日：1977-11-02

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J37/00 ,  C10G45/16 ,  C10G13/06 ,  B01J27/04

CPC classification number: B01J37/00 ,  C10G45/16

Abstract: A catalytic hydroconversion process for a hydrocarbonaceous oil is effected by dissolving an oil-soluble metal compound in the oil, converting the compound to a solid, non-colloidal catalyst within the oil and reacting the oil containing the catalyst with hydrogen. Preferred compounds are molybdenum compounds.

公开(公告)号：US4067799A

公开(公告)日：1978-01-10

申请号：US702238

申请日：1976-07-02

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J31/18 ,  B01J31/28 ,  C10G47/26 ,  C10G13/06 ,  B01J27/04

CPC classification number: C10G47/26 ,  B01J31/183 ,  B01J31/28 ,  B01J2531/025 ,  B01J2531/845 ,  B01J2531/847

Abstract: A heavy hydrocarbonaceous oil is converted to lower boiling hydrocarbon products by treatment with hydrogen in the presence of a catalyst comprising a metal phthalocyanine and a particulate iron component.

Abstract translation: 在包含金属酞菁和颗粒状铁组分的催化剂存在下，通过用氢处理将重质烃油转化为低沸点烃产物。

公开(公告)号：US4066530A

公开(公告)日：1978-01-03

申请号：US745394

申请日：1976-11-26

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: B01J37/00 ,  C10G45/16 ,  C10G13/06 ,  B01J27/04

CPC classification number: B01J37/00 ,  C10G45/16

Abstract: A catalytic hydroconversion process is effected by reacting with hydrogen a heavy hydrocarbonaceous oil containing a catalyst comprising an iron component and a catalytically active other metal component prepared by dissolving an oil soluble metal compound in the oil and converting the metal compound in the oil to the corresponding catalytically active metal component. Preferred oil soluble compounds are molybdenum compounds.

Abstract translation: 烃油的催化加氢转化方法是通过将油溶性金属化合物溶解在油中，将化合物转化成油中的固体非胶态催化剂并使含有催化剂的油与氢反应。 优选的化合物是钼化合物。

公开(公告)号：US6013598A

公开(公告)日：2000-01-11

申请号：US991221

申请日：1997-12-12

Applicant: Mark P. Lapinski ,  Kenneth L. Riley ,  Clyde L. Aldridge ,  Michele S. Touvelle

Inventor： Mark P. Lapinski ,  Kenneth L. Riley ,  Clyde L. Aldridge ,  Michele S. Touvelle

IPC: B01J23/882 ,  B01J35/00 ,  B01J35/10 ,  C10G45/08 ,  B01J23/28 ,  B01J23/75

CPC classification number: C10G45/08 ,  B01J23/882 ,  B01J35/10 ,  B01J35/002 ,  B01J35/1061 ,  C10G2400/02

Abstract: The present invention relates to catalysts for hydrodesulfurizing naphtha streams. The catalysts are comprised of a suitable support material, and about 1 to about 10 wt. % MoO.sub.3, about 0.1 to about 5 wt. % CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 .ANG. to 200 .ANG., a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO.sub.3 surface concentration of about 0.5.times.10.sup.-4 to about 3.0.times.10.sup.-4 g MoO.sub.3 /m.sup.2, and an average particle size of less than about 2.0 mm in diameter.

Abstract translation: 本发明涉及用于加氢脱硫石脑油流的催化剂。 催化剂由合适的载体材料组成，约1至约10wt。 ％MoO 3，约0.1至约5wt。 ％CoO支持在合适的支撑材料上。 它们的特征还在于具有平均中等孔径从约60至200，Co / Mo原子比为约0.1至约1.0，MoO 3表面浓度为约0.5×10 -4至约3.0×10 -4 g MoO 3 / m2，平均颗粒直径小于约2.0mm。

公开(公告)号：US5198100A

公开(公告)日：1993-03-30

申请号：US632723

申请日：1990-12-24

Applicant: Clyde L. Aldridge ,  Kenneth L. Riley

Inventor： Clyde L. Aldridge ,  Kenneth L. Riley

IPC: B01J23/85 ,  B01J27/188 ,  C10G45/08

CPC classification number: B01J23/85 ,  B01J27/188 ,  C10G45/08

Abstract: A hydrotreating process using a sulfided catalyst composition comprised of at least one Group VIII metal and at least one Group VI metal on an inorganic oxide support, which sulfided catalyst is derived from a catalyst precursor comprised of salts and/or complexes of a Group VIII metal(s) with a Group VI metal heteropolyacid on an inorganic oxide support material, wherein the concentration of Group VIII metal ranges from about 2 to 20 wt. %, and the concentration of Group VI metal ranges from 5 to 50 wt. %, which percents are on support and which catalyst composition is substantially free of free water.

Abstract translation: 使用硫化催化剂组合物的加氢处理方法，所述硫化催化剂组合物由无机氧化物载体上的至少一种第Ⅷ族金属和至少一种第Ⅵ族金属组成，所述硫化催化剂衍生自由Ⅷ族金属的盐和/或络合物组成的催化剂前体 其中第Ⅵ族金属杂多酸在无机氧化物载体材料上，其中第Ⅷ族金属的浓度范围为约2-20wt。 ％，VI族金属的浓度为5〜50wt。 ％，哪个百分比是支持的，哪个催化剂组成基本上不含游离水。

公开(公告)号：US5164354A

公开(公告)日：1992-11-17

申请号：US632722

申请日：1990-12-24

Applicant: Clyde L. Aldridge ,  Kenneth L. Riley

Inventor： Clyde L. Aldridge ,  Kenneth L. Riley

IPC: B01J23/85 ,  B01J27/188 ,  C10G45/08

CPC classification number: B01J23/85 ,  B01J27/188 ,  C10G45/08

Abstract: A catalyst composition having superior hydrotreating activity which catalyst is comprised of salts and/or complexes of Group VIII metals with Group VI metal heteropolyacids on an inorganic oxide support material, wherein the concentration of Group VIII metal ranges from about 2 to 20 wt. %, and the concentration of Group VI metal ranges from 5 to 50 wt. %, which percents are on support and which catalyst composition is substantially free of free water.

Abstract translation: 一种催化剂组合物，其具有优异的加氢处理活性，该催化剂由无机氧化物载体材料上的第Ⅷ族金属与第Ⅵ族金属杂多酸的盐和/或配合物组成，其中第Ⅷ族金属的浓度范围为约2-20wt。 ％，VI族金属的浓度为5〜50wt。 ％，哪个百分比是支持的，哪个催化剂组成基本上不含游离水。

公开(公告)号：US3974096A

公开(公告)日：1976-08-10

申请号：US526306

申请日：1974-11-22

Applicant: Marnell A. Segura ,  Clyde L. Aldridge ,  Kenneth L. Riley ,  Lloyd A. Pine

Inventor： Marnell A. Segura ,  Clyde L. Aldridge ,  Kenneth L. Riley ,  Lloyd A. Pine

IPC: B01J23/16 ,  B01J23/78 ,  B01J23/84 ,  B01J27/10 ,  C01B3/16 ,  B01J27/04

CPC classification number: C01B3/16 ,  B01J23/16 ,  B01J23/78 ,  B01J23/84 ,  B01J27/10 ,  Y02P20/52

Abstract: Hydrogen is produced by reacting carbon monoxide with steam at a temperature of at least 200.degree.F. in the presence of a supported catalyst containing: (1) at least one alkali metal compound derived from an acid having an ionization constant below 1 .times. 10.sup..sup.-3, (2) a metallic hydrogenation-dehydrogenation material, and (3) a halogen moiety. The ratio of metal component to alkali metal compound, each calculated on the basis of the oxide thereof, ranges from 0.0001 to about 10 parts by weight per part by weight of the alkali metal compound. The halide constituent is present in amounts in excess of about 0.01 weight %, based on total catalyst. A preferred catalyst composition comprises potassium carbonate, a mixture of cobalt and molybdenum oxides and combined chlorine contained on an alumina support.

Abstract translation: 氢气是在负载型催化剂存在下，在至少200°F的温度下使一氧化碳与蒸汽反应生成的，所述催化剂包含：（1）至少一种衍生自电离常数低于1×10 5的酸的碱金属化合物， - > 3，（2）金属氢化 - 脱氢材料，和（3）卤素部分。 基于其氧化物计算的金属组分与碱金属化合物的比率为每重量份碱金属化合物0.0001-约10重量份。 基于总催化剂，卤化物组分的存在量超过约0.01重量％。 优选的催化剂组合物包含碳酸钾，钴和钼氧化物的混合物以及氧化铝载体上所含的混合氯。

公开(公告)号：US5338717A

公开(公告)日：1994-08-16

申请号：US141839

申请日：1993-10-22

Applicant: Clyde L. Aldridge ,  Kenneth L. Riley

Inventor： Clyde L. Aldridge ,  Kenneth L. Riley

IPC: B01J23/85 ,  B01J27/188 ,  C10G45/08 ,  B01J37/02 ,  B01J27/19 ,  B01J37/16 ,  B01J37/20

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J27/188

Abstract: The present invention relates to the preparation of catalysts for heteroatom removal, particularly sulfur, from petroleum and synthetic fuel feedstocks. The catalyst is comprised of at least one Group VIII metal, and at least one Group VI metal, on a refractory support. The catalyst is prepared by: impregnating an inorganic oxide support material with a Group VI heteropolyacid; treating said impregnated support with an aqueous solution of a reducing agent which is capable of at least partially reducing the Group VI metal of the heteropolyacid; drying said treated support at a temperature from about 20.degree. C. to about 200.degree. C. at about atmospheric pressure; impregnating the treated support with a Group VIII metal salt of an acid having an acidity less than that of the Group VI heteropolyacid; drying said impregnated treated support at a temperature from about 20.degree. C. to about 200.degree. C. at about atmospheric pressure; and sulfiding said impregnated support, thereby forming the catalysts.

Abstract translation: 本发明涉及从石油和合成燃料原料制备用于杂原子去除的催化剂，特别是硫。 催化剂由至少一种第Ⅷ族金属和至少一种第Ⅵ族金属组成，在耐火载体上。 催化剂的制备方法是：用VI族杂多酸浸渍无机氧化物载体材料; 用能够至少部分还原杂多酸的第VI族金属的还原剂的水溶液处理所述浸渍的载体; 在约大气压下在约20℃至约200℃的温度下干燥所述经处理的载体; 用酸度小于第VI族杂多酸的酸的第VIII族金属盐浸渍经处理的载体; 在约大气压下在约20℃至约200℃的温度下干燥所述浸渍的处理过的载体; 并硫化所述浸渍的载体，从而形成催化剂。