摘要:
The present invention relates to an air-drying silane coating composition containing an epoxy or acrylic resin, an optional silicic ester or alkyl silicate, an aminoalkylsilane component, an optional organoalkyoxysilane, and possible auxiliaries; methods of use thereof, and articles and substrates coated accordingly.
摘要:
An apparatus for continuously preparing substantially halogen-free, in particular chlorine-free, trialkoxysilanes of the general formula I (RO)3SiH (I) in which R is an alkyl group having from 1 to 6 carbon atoms, has a main reactor unit (1), at least one metering unit (2, 3, 4) for liquids and/or suspensions, located upstream of the main reactor, and at least one metering unit (5) for gaseous and/or vaporous substances, and also a product workup unit (6) located downstream of the main reactor. A process for preparing substantially halogen-free trialkoxysilanes of the general formula I in which silicon is reacted with alcohols in an inert solvent utilizes at least one organocopper compound catalyst.
摘要:
The present invention provides an organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle including at least one oxide or mixed oxide, KA—O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a linear, branched, cyclic or substituted alkyl group having from 1 to 50 carbon atoms; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA—O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA—O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.
摘要:
The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is carried out in the presence of (a) an alkylsilane of the formula I, R1(SiR2nX3−n)m, (I) where R1 is a monovalent hydrocarbon radical having from 1 to 33 carbon atoms or a divalent hydrocarbon radical having from 4 to 24 carbon atoms, R2 is a hydrocarbon radical having from 1 to 10 carbon atoms, X are identical or different hydrolyzable radicals, n is 0, 1 or 2 and m is 1 or 2 and/or (b) a fluoroalkylsilane of the formula R3xSiR4yXz, (II) where R3 is a fluoroalkyl radical, R4 is an alkyl radical and X is a hydrolyzable radical, x is an integer from 1 to 3, y is 0, 1 or 2 and z is an integer from 1 to 3, with the proviso that the sum x+y+z=4.
摘要翻译:本发明涉及制备具有至少一个可水解基团的可交联聚合物的交联聚合物的方法,所述硅烷基团具有至少一个可水解基团的烯属不饱和硅烷通过自由基引发接枝基础聚合物,其中接枝在 存在(a)式I的烷基硅烷,其中R 1是具有1至33个碳原子的一价烃基或具有4至24个碳原子的二价烃基,R 2是具有1至10个碳原子的烃基 X为相同或不同的可水解基团,n为0,1或2,m为1或2,和/或(b)下式的氟代烷基硅烷,其中R 3为氟代烷基,R 4为烷基,X为可水解基团,x为 是1至3的整数,y是0,1或2,z是1至3的整数,条件是和x + y + z = 4。
摘要:
An aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO [Si(A)(CH3)z(OH)1−zO]a[Si(B)(R2)y(OH)1−yO]b[Si(C)(CH3)O]c[Si(D)(OH)O]dH.(HX)e (I), wherein A is an aminoalkyl group of formula II: H2N (CH2)f(NH)g(CH2)hSi(OR)3−z(CH3)z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R1—Y—(CH2)2Si(R2)Y(OR)3−y (III) wherein R1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms, or a mono-, oligo- or perfluorinated aryl group, Y is a CH2, O or S group, R2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R3—Si(CH3)(OR)2 (IV), and D is an alkyl group of formula V: R3—Si(OR)3 (V) wherein R3, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and HX is an acid, in which X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.
摘要翻译:含有机聚硅氧烷的组合物包含式I的有机聚硅氧烷:其中A是式II的氨基烷基:其中0≤f≤6,如果f = 0,则g = 0,如果f> 0,则g = = h <= 6且0 <= z <= 1; B是式III的氟烷基:其中R1是具有1-9个C原子的单,低聚或全氟化烷基,或单 - 或全氟化芳基,Y为CH 2,O或S基团,R 2为具有1-8个碳原子或芳基且0 <= y <1的直链,支链或环状烷基; C为 式Ⅳ:和D是式Ⅴ的烷基:其中R 3在每种情况下是相同或不同的,并且是具有1-8个C原子的直链,支链或环状的烷基,R在每种情况下是相同的或 不同的是具有1-8个碳原子或芳基的直链,支链或环状的烷基; HX是酸,其中X是无机或有机酸基,0 <= y <= 1,0 <= z <= 1,a> 0,b> 0,c> = 0,d> = 0,e> = 0,(a + b + c + d)> = 2, 有机溶剂,闪点高于70℃,在用水稀释时通过水解基本上不释放醇。
摘要:
A process for the purification of crude N,N'-diphenyl-p-phenylenediamine (DPPD), which comprises extracting crude DPPD with a hydrocarbon or hydrocarbon mixtures thereby forming an extract solution containing DPPD, passing the extract solution over an adsorption layer, and recovering purified DPPD from the solution.
摘要:
A mixture of oligomers of alkylalkoxysilanes condensed in the chain and/or cyclic form, said mixture of oligomers containing less than 2% by weight of free alcohols and the condensed alkoxysilanes satisfying formula I: ##STR1## wherein R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen, or is (iii) ethyl or hydrogen, the degree of oligomerization being in the range 2.ltoreq.x.ltoreq.20 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1; and/orsatisfying formula II: ##STR2## in which R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen or is (iii) ethyl or hydrogen, the degree of oligomerization being x.gtoreq.3 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1.
摘要:
Organocarbonoyloxysilanes are prepared by reacting an organochlorosilane with a carboxylic acid in a first step which liberates HCl, removing the HCl which is formed, reacting the reaction mixture from the first step with a carboxylic acid anhydride in a second reaction step, the first and/or second reaction steps being conducted in the presence of a catalyst, and isolating the resulting organocarbonoyloxysilane product from the reaction mixture.
摘要:
3-Halo- and pseudohalo-alkylsilane esters are prepared by reacting an allyl X compound or a compound containing an allyl X structure with a hydridosilane ester in the presence of an iridium catalyst prepared under specific conditions and/or the reaction medium containing a 0.01-100 mol % excess of the allyl X compound or compound containing the allyl X unit relative to the amount of hydridosilane ester reactant.
摘要:
Hydrogenalkoxysilanes are prepared by direct reaction of finely divided metallic silicon with alcohols in the presence of copper-containing catalysts in a heat-transfer oil comprising tritoluenes, tetratoluenes or mixtures thereof at from 100.degree. to 350.degree. C.