Organosilicon nanocapsules
    43.
    发明授权
    Organosilicon nanocapsules 失效
    有机硅纳米胶囊

    公开(公告)号:US06689468B2

    公开(公告)日:2004-02-10

    申请号:US09971146

    申请日:2001-10-05

    IPC分类号: C08K900

    摘要: The present invention provides an organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle including at least one oxide or mixed oxide, KA—O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R  (Ia) wherein R is a linear, branched, cyclic or substituted alkyl group having from 1 to 50 carbon atoms; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA—O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA—O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.

    摘要翻译: 本发明提供了一种有机硅纳米胶囊,其包括:纳米级芯A,其包括:至少一种包含至少一种选自包括主要基团的金属或半金属的金属或半金属的氧化物或混合氧化物KA-O的颗粒 周期表的2至6,周期表的过渡组1至8,镧系元素及其混合物; 和有机硅壳B,其包括:至少一种具有式(Ia)的有机硅化合物:其中R是具有1至50个碳原子的直链,支链,环状或取代的烷基;其中x是0至20的数 ;其中Si的剩余游离价分别独立地为(KA-O) - ,SiO-或-Z;其中Si'的剩余游离价各自独立地为(KA-O) - , - SiO-,-R或-Z; 其中Z各自独立地为羟基或烷氧基; 并且其中壳体B中的每个Si和Si'具有不多于一个R基团。

    Cross-linkable polymers, method for the production thereof, and shaped bodies made of cross-linked polymers
    44.
    发明授权
    Cross-linkable polymers, method for the production thereof, and shaped bodies made of cross-linked polymers 失效
    可交联聚合物,其制备方法和由交联聚合物制成的成型体

    公开(公告)号:US06528585B1

    公开(公告)日:2003-03-04

    申请号:US09830157

    申请日:2001-07-19

    IPC分类号: C08F800

    CPC分类号: C08F255/02 C08F291/00

    摘要: The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is carried out in the presence of (a) an alkylsilane of the formula I, R1(SiR2nX3−n)m,  (I)  where R1 is a monovalent hydrocarbon radical having from 1 to 33 carbon atoms or a divalent hydrocarbon radical having from 4 to 24 carbon atoms, R2 is a hydrocarbon radical having from 1 to 10 carbon atoms, X are identical or different hydrolyzable radicals, n is 0, 1 or 2 and m is 1 or 2 and/or (b) a fluoroalkylsilane of the formula R3xSiR4yXz,  (II)  where R3 is a fluoroalkyl radical, R4 is an alkyl radical and X is a hydrolyzable radical, x is an integer from 1 to 3, y is 0, 1 or 2 and z is an integer from 1 to 3,  with the proviso that the sum x+y+z=4.

    摘要翻译: 本发明涉及制备具有至少一个可水解基团的可交联聚合物的交联聚合物的方法,所述硅烷基团具有至少一个可水解基团的烯属不饱和硅烷通过自由基引发接枝基础聚合物,其中接枝在 存在(a)式I的烷基硅烷,其中R 1是具有1至33个碳原子的一价烃基或具有4至24个碳原子的二价烃基,R 2是具有1至10个碳原子的烃基 X为相同或不同的可水解基团,n为0,1或2,m为1或2,和/或(b)下式的氟代烷基硅烷,其中R 3为氟代烷基,R 4为烷基,X为可水解基团,x为 是1至3的整数,y是0,1或2,z是1至3的整数,条件是和x + y + z = 4。