FCC catalysts for feeds containing nickel and vanadium
    43.
    发明授权
    FCC catalysts for feeds containing nickel and vanadium 有权
    用于含镍和钒的饲料的FCC催化剂

    公开(公告)号:US06716338B2

    公开(公告)日:2004-04-06

    申请号:US10190992

    申请日:2002-07-08

    IPC分类号: B01J2908

    摘要: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

    摘要翻译: 由微球制成的流化催化裂化催化剂,其最初含有高岭土,可分散勃姆石氧化铝和硅酸钠或硅溶胶粘结剂。 高岭土部分含有水合高岭土和任选的尖晶石或莫来石,或通过其特征放热煅烧的高岭土制成的尖晶石和莫来石两者。 通过用硅酸钠处理将含水粘土煅烧成偏高岭土并形成原位沸石产生含有Y型八面沸石的催化剂,并将可分散的勃姆石转变为过渡型氧化铝。 该催化剂可用于裂解残渣或渣油进料,因为由可分散勃姆石形成的氧化铝相钝化镍和钒污染物。