摘要:
A non-friable support, e.g., sand, coated with a polymer is prepared by contacting the support containing a polymerization catalyst with a monomer which is at least one multi-functional olefin, e.g., a diene, under monomer polymerization conditions. The product of the polymerization process is a highly cross-linked coating which engulfs the support, thereby rendering it hydrolytically and thermally stable. The support can be used as a sand pack in enhanced oil recovery operations, wherein it is resistant to deterioration due to high temperature, pressure and alkaline conditions existing in the subterranean formations.
摘要:
This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a ctalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table. The metal can be, for example, rhodium, cobalt, or ruthenium. The olefin can contain more than one carbon-to-carbon double bond, may be an open chain or a cyclic olefin, and may be substituted. Further, the olefin may be contained in a refinery stream such as a cracked gasoline. The reaction may be carried out in the presence of a polar solvent.
摘要:
A process for continuously or semi-continuously producing and collecting highly oriented graphite crystals by diffusing carbon atoms through a heated Group VIII metal artifact such that they precipitate as graphite on a surface of the artifact. Diffusion of carbon atoms through the artifact is driven by maintaining a temperature differential across the artifact.
摘要:
Conversion of carbon monoxide, hydrogen, alcohol and olefin containing mixtures in the presence of a new class of heterogeneous catalyst is provided. Said new class of heterogeneous catalyst comprises a substrate having a minimum surface area of about 10 m.sup.2 /g and having pores with a minimum pore diameter of about 5 Angstrom Units, said substrate being modified by at least one amine functional member coordinated to a metal function, said amine functional member acting as a bridging member between said substrate and said metal function.
摘要:
Conversion of carbon monoxide, hydrogen, and alcohol containing mixtures in the presence of a new class of heterogeneous catalyst is provided. Said new class of heterogeneous catalyst comprises a substrate having a minimum surface area of about 10 m.sup.2 /g and having pores with a minimum pore diameter of about 5 Angstrom Units, said substrate being modified by at least one amine functional member coordinated to a metal function, said amine functional member acting as a bridging member between said substrate and said metal function.
摘要:
This invention provides an integrated process for upgrading a combination of crude petroleum residua, refractory bottoms from catalytic cracking operations, and coal to gasoline and middle distillate products.The process involves dense-gas solvent extraction under supercritical conditions, cracking, and hydroconversion stages.
摘要:
A method is described to improve a coal liquefaction process by the use of a recycle solvent comprised of two fractions: the first, a lower boiling fraction, is obtained by an atmospheric distillation and is subsequently hydrotreated to enrich its hydrogen donor capacity; the second is a higher boiling fraction that is enriched in desirable hydrogen transfer agents by a solvent extraction process. The combined recycle solvent thus obtained is more efficient in transferring gas phase H.sub.2 to the coal and enables other significant process improvements.
摘要:
Hydrogenation-dehydrogenation of suitable feedstock is provided wherein such feedstock is subjected to hydrogenation-dehydrogenation conditions in the presence of a catalytic amount of a solid containing, at least in part, a synthetic amorphous solid prepared by hydrolyzing and polymerizing in the presence of water a silane having the formula R(Si)X.sub.3, wherein R is a nonhydrolyzable organic group, X is a hydrolyzable group and (Si) is selected from the group consisting of ##STR1## and calcining the polymerized product, said silane being admixed with a second compound, R'.sub.n MY.sub.m, wherein R' is selected from the group consisting of the same groups as R, Y is selected from the group consisting of the same groups as X and oxygen, M is at least one member selected from the group consisting of the elements of Groups IIIA, IVA, VA, IVB, VB, VIB, VIIB and VIII of the Periodic Table, m is any number greater than 0 and up to 8 and n is from 0 to any number less than 8.
摘要:
A cross-linked polystyrene resin modified by the presence therein of chemically bound sulfur provides a highly selective sorbent for removal of heavy metal contaminants from liquids containing the same.
摘要:
This specification discloses a process for the production of an alcohol by reacting an aldehyde or an acetal with hydrogen in the presence of carbon monoxide, and as a catalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table.