Catalyst systems for the cationic polymerization of isobutylene
    41.
    发明授权
    Catalyst systems for the cationic polymerization of isobutylene 失效
    用于异丁烯阳离子聚合的催化剂体系

    公开(公告)号:US4663406A

    公开(公告)日:1987-05-05

    申请号:US836649

    申请日:1986-03-05

    IPC分类号: C08F4/00 C08F4/14 C08F10/10

    CPC分类号: C08F10/10

    摘要: Isobutylene polymers are prepared by polymerizing the monomers at from 0.2 to 20 bar and from -130.degree. and +60.degree. C. in the presence of from 0.01 to 20 mmol of a boron halide catalyst system which contains as cocatalyst a carboxylic anhydride or carbonyl halide, preferably an aliphatic or aromatic, unsubstituted or halogen-substituted C.sub.4 -C.sub.18 -carboxylic anhydride of C.sub.2 -C.sub.12 -carbonyl halide and where appropriate also a customary polymerization accelerant in customary amounts, in the presence or absence of an inert solvent with dissipation of the heat of reaction.

    摘要翻译: 异丁烯聚合物通过在0.01至20巴和-130℃和+ 60℃下聚合单体制备,在0.01至20mmol卤化硼催化剂体系的存在下,其含有作为助催化剂的羧酸酐或羰基卤化物 ,优选C 2 -C 12 - 羰基卤化物的脂族或芳族未取代或卤素取代的C 4 -C 18羧酸酐,并且在适当的情况下,在常规量的情况下,在惰性溶剂存在或不存在下, 反应热。

    Preparation of telechelic structures
    44.
    发明授权
    Preparation of telechelic structures 失效
    遥爪结构的制备

    公开(公告)号:US5625008A

    公开(公告)日:1997-04-29

    申请号:US314954

    申请日:1994-09-29

    摘要: Telecheles are prepared by reacting, preferably, polyfunctional, living polymers obtained by anionic polymerization with a functionalizing agent by a process in which the reaction is carried out while stirring with a stirrer having knife-like blades as stirring elements, the latter being inclined relative to their plane of movement and passing over essentially the complete space occupied by the reaction mixture.

    摘要翻译: 通过使通过阴离子聚合获得的多官能活性聚合物与官能化剂反应,通过使用具有刀状叶片作为搅拌元件的搅拌器一边搅拌一边进行反应的方法,将后者相对于 它们的运动平面基本上超过了反应混合物占据的完整空间。

    Alkadiene/vinylaromatic copolymers containing side groups, and their use
    45.
    发明授权
    Alkadiene/vinylaromatic copolymers containing side groups, and their use 失效
    含有侧基的二烯/乙烯基芳族共聚物及其用途

    公开(公告)号:US5290874A

    公开(公告)日:1994-03-01

    申请号:US854386

    申请日:1992-03-19

    摘要: The novel alkadiene/vinyl-aromatic copolymers which contain side groups and have a random, block-like or star-like structure and whose polymerized alkadiene comonomer units are partially or completely selectively hydrogenated, and which contain one or more side groups having one or more radicals capable of (4+2) cycloaddition (Diels-Alder reaction) with dienophiles are suitable as such as viscosity index (VI) improvers or can be used for the preparation of dispersant VI improvers. For this purpose, they are reacted with one or more dienophiles which are capable of a Diels-Alder (4+2) cycloaddition reaction and preferably contain strongly polar functional groups. The resulting selectively hydrogenated alkadiene/vinylaromatic copolymers having one or more side groups which constitute a (4+2) cycloadduct or a Diels-Alder adduct can be modified in their performance characteristics by further reaction with ammonia, an organic amine, an alkylene oxide, a polyalkylene oxide and/or a condensate of ammonia and/or an organic amine with an alkylene oxide.

    摘要翻译: 含有侧基且具有无规,嵌段状或星形结构且其聚合的链烯二
    烯共聚单体部分或全部被选择性氢化的新型链二烯/乙烯基 - 芳族共聚物,其含有一个或多个具有一个或多个 具有双亲性的(4 + 2)环加成(Diels-Alder反应)的基团是适合的,如粘度指数(VI)改进剂或可用于制备分散剂VI改进剂。 为此,它们与一种或多种能够进行狄尔斯 - 阿尔德(4 + 2)环加成反应并且优选含有极性极性官能团的亲二烯体反应。 可以通过与氨,有机胺,环氧烷烃等进一步反应,将具有构成(4 + 2)环加成物或狄尔斯 - 阿尔德加合物的一个或多个侧基的所得选择性氢化的二烯烃/乙烯基芳族共聚物的性能特性改性, 聚氧化烯和/或氨和/或有机胺与烯化氧的缩合物。

    Polymers having terminal halogen atoms
    47.
    发明授权
    Polymers having terminal halogen atoms 失效
    具有末端卤素原子的聚合物

    公开(公告)号:US5166286A

    公开(公告)日:1992-11-24

    申请号:US668355

    申请日:1991-03-11

    IPC分类号: C08F2/38 C08F4/06

    CPC分类号: C08F2/38 C08F4/06

    摘要: Polymers having terminal halogen atoms and consisting of cationically polymerizable, olefinically unsaturated monomers are obtainable by polymerization using an initiator system comprising a halogen-containing Lewis acid and a 3-membered to 8-membered cyclic ether.

    摘要翻译: 具有末端卤素原子并由阳离子可聚合的烯属不饱和单体组成的聚合物可通过使用包含含卤素的路易斯酸和3元至8元环醚的引发剂体系的聚合获得。

    Thermoplastic molding materials based on polyphenylene ethers
    48.
    发明授权
    Thermoplastic molding materials based on polyphenylene ethers 失效
    基于聚苯乙烯的热塑性模塑材料

    公开(公告)号:US5059645A

    公开(公告)日:1991-10-22

    申请号:US525201

    申请日:1990-05-02

    IPC分类号: C08L71/12

    CPC分类号: C08L71/123 Y10S525/905

    摘要: Thermoplastic molding materials containa) from 20 to 80 parts by weight of a polyphenylene ether,b) from 1 to 20 parts by weight of a block copolymer of the general formula A--B--A' consisting of two polyvinylaromatic blocks A and A' and a partially hydrogenated rubber block B,c) from 0 to 70 parts by weight of a polyvinylaromatic andd) from 0 to 40 parts by weight of conventional additives, the sum of a) to d) being 100 parts by weight, wherethe mean molecular weights of A and A' differ by a factor of from 2 to 20,the shorter block A has a mean molecular weight of from 2,000 to 4,000 andthe blocks A and A' together account for from 35 to 50% by weight of b).

    摘要翻译: 热塑性成型材料含有a)20〜80重量份的聚苯醚,b)1〜20重量份由两个聚乙烯基芳族嵌段A和A'构成的通式ABA'的嵌段共聚物和部分氢化的 橡胶块B,c)0-70重量份聚乙烯基芳族化合物和d)0-40重量份常规添加剂,a)至d)之和为100重量份,其中平均分子量 A和A'的差异在2至20之间,较短的嵌段A的平均分子量为2,000至4,000,并且嵌段A和A'一起占b)的35至50重量%。

    Thermoplastic molding materials
    49.
    发明授权
    Thermoplastic molding materials 失效
    热塑性材料

    公开(公告)号:US5053458A

    公开(公告)日:1991-10-01

    申请号:US507086

    申请日:1990-04-05

    IPC分类号: C08L71/12 C08L77/00

    摘要: Thermoplastic molding materials contain, as essential components,A) from 5 to 94% by weight of a polyamide,B) from 5 to 94% by weight of a polyphenylene ether,C) from 1 to 20% by weight of a partially hydrogenated PQP' block copolymer, where.alpha.) the blocks P and P' consist of vinylaromatic monomers and the total amount of these blocks in the block copolymer is from 25 to 40% by weight,.beta.) the number average molecular weight of block P is not more than 8,000 and is smaller than the number average molecular weight of block P',.gamma.) block Q consists of conjugated diene monomers and accounts in total for from 60 to 75% by weight of the block copolymer and.delta.) from 5 to 30% by weight of the double bonds in block Q are not hydrogenated, andD) from 0 to 50% by weight of a vinylaromatic polymer.

    摘要翻译: 热塑性成型材料含有A)5至94重量%的聚酰胺,B)5至94重量%的聚苯醚,C)1至20重量%的部分氢化的PQP '嵌段共聚物,其中α)嵌段P和P'由乙烯基芳族单体组成,并且嵌段共聚物中这些嵌段的总量为25至40重量%,β)块P的数均分子量不多 小于块P'的数均分子量,γ)嵌段Q由共轭二烯单体构成,总共占嵌段共聚物的60〜75重量%,δ占5〜30重量% 嵌段Q中双键的重量不被氢化,D)为0至50重量%的乙烯基芳族聚合物。