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61 条记录 (耗时 0.028 秒)

    Oligomer mixtures derived from cyclopentene; method for the production and use thereof
    42.
    发明授权
    Oligomer mixtures derived from cyclopentene; method for the production and use thereof 失效
    衍生自环戊烯的低聚物混合物; 生产和使用方法

    公开(公告)号：US06677495B1

    公开(公告)日：2004-01-13

    申请号：US09331417

    申请日：1999-06-21

    申请人： Peter Schwab ,  Martin Schäfer ,  Arthur Höhn

    发明人： Peter Schwab ,  Martin Schäfer ,  Arthur Höhn

    IPC分类号： C07C606

    CPC分类号： C07C6/06 ,  C07C2531/22 ,  C07C2531/24

    摘要： A process for preparing cyclopentene oligomer mixtures of the formula I comprises reacting in a homogeneously or heterogeneously catalyzed metathesis reaction a hydrocarbon mixture which contains cyclopentene and acyclic monoolefins and which originates from petroleum processing by cracking (C5 fraction); cyclopentene oligomers of the formula I obtainable by this process and their use are also described.

    摘要翻译： 制备式I的环戊烯低聚物混合物的方法包括在均匀或不均匀催化的复分解反应中反应含有环戊烯和非环状单烯烃的烃混合物，其通过裂化（C5馏分）来源于石油加工;式I的环戊烯低聚物可通过 还描述了该过程及其用途。

    Cationic ruthenium complexes, their production and their use
    43.
    发明授权
    Cationic ruthenium complexes, their production and their use 有权
    阳离子钌络合物，它们的生产和使用

    公开(公告)号：US06500975B1

    公开(公告)日：2002-12-31

    申请号：US09674536

    申请日：2000-11-02

    申请人： Peter Schwab ,  Michael Schulz ,  Justin Wolf ,  Wolfram Stuer ,  Helmut Werner

    发明人： Peter Schwab ,  Michael Schulz ,  Justin Wolf ,  Wolfram Stuer ,  Helmut Werner

    IPC分类号： C07F1500

    CPC分类号： B01J31/00 ,  B01J31/22 ,  C07B61/00 ,  C07C6/04 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80

    摘要： Cationic ruthenium complexes of the formula A or B or mixtures containing them, where B may be stabilized by a further ligand L4 and X is an anion which does not coordinate or coordinates weakly to the metal center, Y is a monodentate or multidentate anionic ligand, R and R′ are each, independently of one another, hydrogen or a substituted or unsubstituted C1-C20-alkyl, C6-C20-aryl or C7-C20-alkylaryl radical and L1, L2, L3 and L4 are, independently of one another, uncharged electron donor ligands, are described.

    摘要翻译： 式A或B的阳离子钌络合物或含有它们的混合物，其中B可以通过另外的配体L4稳定，X是不与金属中心配位或弱配位的阴离子，Y是单齿或多齿阴离子配体，R 和R'彼此独立地为氢或取代或未取代的C 1 -C 20 - 烷基，C 6 -C 20 - 芳基或C 7 -C 20烷基芳基，且L 1，L 2，L 3和L 4彼此独立地为不带电 电子给体配体。

    High metathesis activity ruthenium and osmium metal carbene complexes
    44.
    发明授权
    High metathesis activity ruthenium and osmium metal carbene complexes 有权
    高复分解活性钌和锇金属卡宾络合物

    公开(公告)号：US06211391B1

    公开(公告)日：2001-04-03

    申请号：US09399963

    申请日：1999-09-20

    申请人： Robert H. Grubbs ,  Peter Schwab ,  Sonbinh T. Nguyen

    发明人： Robert H. Grubbs ,  Peter Schwab ,  Sonbinh T. Nguyen

    IPC分类号： C07F1500

    CPC分类号： C08F4/80 ,  B01J31/18 ,  B01J31/2265 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07F15/002 ,  C07F15/0046 ,  C08F32/00 ,  C08G61/08

    摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.

    摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物是M为Os或Ru的化合物; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。