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    Tetrahydropyridines
    42.
    发明授权
    Tetrahydropyridines 失效

    公开(公告)号：US06989394B2

    公开(公告)日：2006-01-24

    申请号：US10651688

    申请日：2003-08-29

    申请人： Stephan Trah

    发明人： Stephan Trah

    IPC分类号： A01N43/40 ,  C07D401/10

    CPC分类号： C07D401/10 ,  A01N43/40 ,  A01N43/58 ,  A01N43/713 ,  A01N47/20 ,  C07D211/70 ,  C07D211/94

    摘要： Compounds of formula are described, wherein R1 and R2 are for example, independently of each other, halogen, C1-C6-alkyl, C3-C6-cycloalkyl, halogen-C1-C6-alkyl, halogen-C3-C6-cycloalkyl, C2-C4-alkenyl, C2-C4-alkinyl, halogen-C2-C4-alkenyl and halogen-C2-C4-alkinyl; R3 is hydrogen, OH, halogen, C1-C6-alkoxy, or —O—C(═O)—C1-C6-alkyl; R4 is for example phenyl, benzyl, phenoxy or benzyloxy, which is substituted by substituents selected from the group consisting of halogen, cyano, NO2, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C8-cyclalkyl-C1-C6-alkyl, halogen-C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C8-cycloalkoxy-C1-C6-alkyl, C3-C8-cycloalkoxy-C1-C6-alkoxy, halogen-C1-C6-alkoxy, C2-C4-alkenyl, C2-C4-alkinyl, halogen-C2-C4-alkenyl, halogen-C2-C4-alkinyl, C2-C6-alkenyloxy, C2-C6-alkinyloxy, halogen-C2-C6-alkenyloxy, halogen-C2-C6-alkinyloxy, —NR6—C(═O)—O—C1-C6-alkyl, —NR6—C(═O)—O-halogen-C1-C6-alkyl, —C(R7)═N—W—R8, phenyl, benzyl, phenoxy, benzyloxy, heterocycyl and heterocyclyoxy; the two R5 independently of one another, are hydrogen or C1-C6-alkyl; R6 is hydrogen, C1-C6-alkyl or benzyl; R7 is for example halogen or C1-C6-alkyl; R8 is for example hydrogen or C1-C6-alkyl; m is 0, 1, 2, 3, 4 or 5; n is 0, 1, 2, 3, 4 or 5; p is 0, 1 or 2; q is 0 or 1; W is O or NH or N—C1-C6-alkyl; a method of producing and the use of these compounds, pesticides whose active ingredient is selected from these compounds or from an agrochemically employable salt thereof, a method of producing and the use of these compositions, plant propagating material that has been treated with these compositions and a method of controlling pests.

    N-substituted tetrahydropyridines and their use as pesticides
    43.
    发明授权
    N-substituted tetrahydropyridines and their use as pesticides 失效
    N-取代四氢吡啶类及其作为农药的用途

    公开(公告)号：US06953811B2

    公开(公告)日：2005-10-11

    申请号：US10470790

    申请日：2002-02-04

    申请人： Stephan Trah ,  Josef Ehrenfreund ,  Peter Maienfisch ,  André Jeanguenat ,  Saleem Farooq

    发明人： Stephan Trah ,  Josef Ehrenfreund ,  Peter Maienfisch ,  André Jeanguenat ,  Saleem Farooq

    IPC分类号： A01N43/40 ,  C07D211/70 ,  C07D211/94 ,  C07D401/06

    CPC分类号： C07D401/06 ,  C07D211/70 ,  C07D211/94

    摘要： A description is given of compounds of the formula in which R1 and R2 independently of one another are halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy, or SF5, R3 is hydrogen, OH, halogen, C1-C6alkoxy or —O—C(═O)—C1-C6alkyl, R4 is for example hydrogen, halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy or SCN; R5 and R6 independently of one another are for example hydrogen, C1-C12alkyl, halo-C1-C12alkyl, C2-C12alkenyl, halo-C2-C12alkenyl or C2-C12alkynyl; and q is 0 or 1; and, where appropriate, E/Z isomers, E/Z isomer mixtures and/or tautomers, each in free form or in salt form; a process for the preparation of these compounds and their use, pesticide compositions whose active ingredient is selected from these compounds, or an agrochemically useable salt thereof, a process for preparing these compositions, and their use, plant propagation material treated with these compositions, and a method of combating pests.

    摘要翻译： 给出下式的化合物，其中R 1和R 2彼此独立地是卤素，C 1 -C 3 C 6 -C 6烷基，卤代C 1 -C 6烷基，C 1 -C 6烷基，C 1 -C 6烷基，C 1 -C 6烷基， 烷氧基，卤代-C 1 -C 6烷氧基或SF 5，R 3是氢，OH， 卤素，C 1 -C 6烷氧基或-OC（-O）-C 1 -C 6 -C 6烷基 R 4是例如氢，卤素，C 1 -C 6烷基，卤代C 1 -C 4烷基， C 1 -C 6烷基，C 1 -C 6烷氧基，卤代C 1 -C 6烷基，C 1 -C 6烷氧基，C 1 -C 6烷基， 烷氧基或SCN; R 5和R 6彼此独立地是例如氢，C 1 -C 12 - 烷基，卤代 C 1 -C 12烷基，C 2 -C 12链烯基，卤代-C 2烷基，C 1 -C 12烷基，C 2 -C 12 - C 12 -C 12链烯基或C 2 -C 12 - 炔基; q为0或1; 和/或互变异构体，各自为游离形式或盐形式的E / Z异构体，E / Z异构体混合物和/或互变异构体; 制备这些化合物及其用途的方法，其活性成分选自这些化合物的农药组合物或其农业上可用的盐，这些组合物的制备方法及其用途，用这些组合物处理的植物繁殖材料，以及 一种防治害虫的方法。

    Organic compounds
    44.
    发明授权
    Organic compounds 失效
    有机化合物

    公开(公告)号：US06313344B1

    公开(公告)日：2001-11-06

    申请号：US09085283

    申请日：1998-05-27

    申请人： Stephan Trah ,  Henry Szczepanski ,  Ottmar Franz Hüter ,  Roger Graham Hall ,  Saleem Farooq ,  Alfons Pascual

    发明人： Stephan Trah ,  Henry Szczepanski ,  Ottmar Franz Hüter ,  Roger Graham Hall ,  Saleem Farooq ,  Alfons Pascual

    IPC分类号： C07C32700

    CPC分类号： C07D261/20 ,  A01N37/38 ,  A01N37/50 ,  A01N43/80 ,  C07C251/60 ,  C07C323/12 ,  C07D261/08 ,  C07F9/4021

    摘要： Compounds of formula (I), wherein either X is CH or N, Y is OR1 and Z is O, or X is N, Y is NHR8 and Z is O, S or S(═O); R1, R2 and R3 are as defined according to the specification; m is 0, 1 or 2; R5 is, for example, halogen, C1-C6alkyl, halo-C1-C6alkyl or C3-C6cycloalkyl; n is 0, 1, 2, 3 or 4; R9 is methyl, fluoromethyl or difluoromethyl; A and R7 are as defined according to the specification; D is O, S, —S(═O) or S(═O)2; G is C1-C6aalkylene; T—R6 is R6, —C(═N—O—A1—R77)—R6; —SiR14(R15)—R6; —C(═O)—R6; —C(R16)═C(R17)—R6, —C≡C—R6 or —D—R6; R6 is C1-C4alkyl or unsubstituted or substituted aryl or heteroaryl; A1 and R77 are as defined above for A and R7; L is U—R18, P(OR)vR11R12, P(S)wR11R12 or N(aryl)R13; v and w are 0 or 1; U—R18 is —C(═O)—C(═O)—R18; —C(OH)—C(OH)—R18; —C(═N—O—A1—R7)—R18; a is 0 or 1; b is 0 or 1; R11, R12 and R13 are, for example, C1-C6alkyl, halo-C1-C6alkyl or C3-C6cycloalkyl; R14 and R15 are each independently of the other C1-C4alkyl; R16 and R17 are each independently of the other hydrogen, C1-C4alkyl or halogen and R18 is R5; and, where applicable, their possible E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form, a method of controlling pests, a process for the preparation of those compounds and their use are described.

    摘要翻译： 式（I）化合物，其中X是CH或N，Y是OR 1，Z是O，或X是N，Y是NHR 8，Z是O，S或S（= O）; R 1，R 2和R 3如上定义 根据规范; m为0,1或2; R 5为例如卤素，C 1 -C 6烷基，卤代-C 1 -C 6烷基或C 3 -C 6环烷基; n为0,1,2,3或4; R9是甲基，氟甲基或二氟甲基; A和R7如本说明书所定义; D是O，S，-S（= O）或S（= O）2; G是C1-C6亚烷基; T-R6是R6，-C（= N-O-A1-R77）-R6; -SiR14（R15）-R6; -C（= O）-R6; -C（R 16）= C（R 17）-R 6，-C = C-R6或-D-R6; R6是C1-C4烷基或未取代或取代的芳基或杂芳基; A1和R77如对于A和R7所定义; L是U-R18，P（OR）vR11R12，P（S）wR11R12或N（芳基）R13; v和w为0或1; U-R 18为-C（= O）-C（= O）-R 18; -C（OH）-C（OH）-R 18; -C（= N-O-Al-R 7）-R 18; a为0或1; b为0或1; R 11，R 12和R 13为例如C 1 -C 6烷基，卤代-C 1 -C 6烷基或C 3 -C 6环烷基; R 14和R 15各自独立地为C 1 -C 4烷基; R 16和R 17各自独立地为 另一个氢，C 1 -C 4烷基或卤素，R 18是R 5;并且在适用的情况下，它们可能的E / Z异构体，E / Z异构体和/或互变异构体的混合物，在每种情况下以游离形式或盐形式， 控制害虫，制备这些化合物的方法及其用途。

    O-benzyl oxime ether derivatives and their use as pesticides
    45.
    发明授权
    O-benzyl oxime ether derivatives and their use as pesticides 失效
    O-苄基肟醚衍生物及其作为农药的用途

    公开(公告)号：US5977182A

    公开(公告)日：1999-11-02

    申请号：US836176

    申请日：1997-05-01

    申请人： Rene Zurfluh ,  Hugo Ziegler ,  Stephan Trah

    发明人： Rene Zurfluh ,  Hugo Ziegler ,  Stephan Trah

    IPC分类号： A01C1/08 ,  A01N35/10 ,  A01N37/34 ,  A01N37/50 ,  A01N37/52 ,  A01N55/10 ,  C07C251/38 ,  C07C251/48 ,  C07C251/52 ,  C07C251/54 ,  C07C251/60 ,  C07C255/62 ,  C07C255/64 ,  C07C257/06 ,  C07C257/14 ,  C07C257/22 ,  C07C317/32 ,  C07C323/47 ,  C07C327/40 ,  C07C327/58 ,  C07D213/76 ,  C07D277/10 ,  C07D277/12 ,  C07D277/28 ,  C07D295/185 ,  C07D295/30 ,  C07D521/00 ,  A01N33/24 ,  A01N43/40

    CPC分类号： C07D295/185 ,  A01N37/50 ,  A01N37/52 ,  C07C251/38 ,  C07C251/48 ,  C07C255/64 ,  C07C257/06 ,  C07C257/14 ,  C07C257/22 ,  C07D295/30 ,  C07C2101/02

    摘要： Compounds of formula (I), wherein Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, OH, CN, NO.sub.2, Si(CH.sub.3).sub.3, CF.sub.3 or halogen, and T is a group (a) or (b), and wherein the remaining substituents have the following definitions: X is O, S or NR.sub.13 ; A is O or NR.sub.4 ; R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, cyclopropyl, C.sub.1 -C.sub.4 alkoxymethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio or cyano; R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, cyano unsubstituted or substituted C.sub.1 -C.sub.6 alkoxycarbonyl, unsubstituted or substituted di(C.sub.1 -C.sub.6 alkyl)aminocarbonyl, unsubstituted or substituted C.sub.1 -C.sub.6 alkyl-S(O).sub.q, unsubstituted or substituted aryl-S(O).sub.q, unsubstituted or substituted heteroaryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted heterocyclylcarbonyl or unsubstituted or substituted phenyl; and R.sub.3 is hydrogen, unsubstituted or substituted alkyl, unsubstituted or substituted C.sub.3 -C.sub.6 cycloalkyl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl; and wherein the remaining substituents are as defined herein, are pesticidal active ingredients. They can be used in pest control, especially as microbicides, insecticides and acaricides in agriculture, in horticulture and in the hygiene sector. ##STR1##

    摘要翻译： PCT No.PCT / EP95 / 04357 Sec。 371日期1997年5月1日 102（e）日期1997年5月1日PCT提交1995年11月6日PCT公布。 公开号WO96 / 16026 日期：5月30日，式（I）的化合物，其中Y为氢，C1-C4烷基，C1-C4烷氧基，OH，CN，NO2，Si（CH3）3，CF3或卤素，T为（a）或 b），其中其余取代基具有以下定义：X是O，S或NR 13; A为O或NR4; R 1是氢，C 1 -C 4烷基，卤代C 1 -C 4烷基，环丙基，C 1 -C 4烷氧基甲基，C 1 -C 4烷氧基，C 1 -C 4烷硫基或氰基; 未取代或取代的二（C 1 -C 6烷基）氨基羰基，未取代或取代的C 1 -C 6烷基-S（O）q，未取代或取代的芳基-S（O）q，C 1 -C 6烷基，C 3 -C 6环烷基，氰基未取代或取代的C 1 -C 6烷氧基羰基， （O）q，未取代或取代的杂芳基，未取代或取代的杂环基，未取代或取代的杂环基羰基或未取代或取代的苯基; 未取代或取代的烷基，未取代或取代的C 3 -C 6环烷基，未取代或取代的苯基或未取代或取代的吡啶基; 并且其中剩余的取代基如本文所定义，是杀虫活性成分。 它们可用于病虫害防治，特别是作为农业，园艺和卫生领域的杀菌剂，杀虫剂和杀螨剂。

    Pyrazolyl acrylic acid derivatives, intermediates thereto, and in their use as microbicides
    47.
    发明授权
    Pyrazolyl acrylic acid derivatives, intermediates thereto, and in their use as microbicides 失效
    吡唑基丙烯酸衍生物，其中间体及其作为杀微生物剂的用途

    公开(公告)号：US5612338A

    公开(公告)日：1997-03-18

    申请号：US495532

    申请日：1995-07-28

    申请人： Stephan Trah

    发明人： Stephan Trah

    IPC分类号： C07D231/20 ,  A01N43/54 ,  A01N43/56 ,  A01N43/64 ,  A01N43/66 ,  C07D231/18 ,  C07D401/12 ,  C07D403/12

    CPC分类号： C07D401/12 ,  A01N43/56 ,  A01N43/66 ,  C07D231/18 ,  C07D403/12

    摘要： Compounds of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl,R.sub.2 is hydrogen, halogen, OCH.sub.3, SCH.sub.3 or CN,R.sub.3, R.sub.4, R.sub.5 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkoxycarbonyl, C.sub.1 -C.sub.5 alkanoyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, CN, NO.sub.2, or wherein two of those substituents are adjacent to each other and together are a methylenedioxy or difluoromethylenedioxy radical,K, L, M are each independently of one another CH or N (=nitrogen atom), but at least one of these three substituents is N, andY is oxygen or sulfur,are effective microbicides for controlling fungal diseases. They can be used for plant protection by themselves or as formulated compositions.

    摘要翻译： PCT No.PCT / EP94 / 00103 Sec。 371日期：1995年7月28日 102（e）日期1995年7月28日PCT 1994年1月17日PCT PCT。 公开号WO94 / 17060 PCT 日期：1994年8月4日化学式其中R 1为氢或甲基，R 2为氢，卤素，OCH 3，SCH 3或CN，R 3，R 4，R 5各自独立地为氢，卤素，C 1 -C 4烷基， C 1 -C 4烷氧基，C 2 -C 5烷氧基羰基，C 1 -C 5烷酰基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，CN，NO 2，或其中两个取代基彼此相邻并且一起是亚甲二氧基或二氟亚甲二氧基，K，L，M 各自独立地是CH或N（=氮原子），但这三个取代基中的至少一个是N，Y是氧或硫，是用于控制真菌疾病的有效的杀微生物剂。 它们可以自己或作为配制的组合物用于植物保护。

    2-aminooxymethylenephenylacetic acid derivatives
    48.
    发明授权
    2-aminooxymethylenephenylacetic acid derivatives 失效
    2-氨氧基亚甲基苯乙酸衍生物

    公开(公告)号：US5606095A

    公开(公告)日：1997-02-25

    申请号：US462259

    申请日：1995-06-05

    申请人： Albert Pfiffner ,  Stephan Trah ,  Hugo Ziegler

    发明人： Albert Pfiffner ,  Stephan Trah ,  Hugo Ziegler

    IPC分类号： C07C239/08 ,  C07C239/20 ,  C07C255/57 ,  C07C323/23 ,  C07F9/38 ,  C07F9/40 ,  C07C229/00

    CPC分类号： C07C239/20

    摘要： 2-Aminooxymethylenephenylacetic acid ester derivatives of the formula ##STR1## wherein Z.sub.1 and Z.sub.2 are hydrogen, halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylcarbonyl, phenoxy, nitro or cyano, or Z.sub.1 and Z.sub.2, together with the linking phenyl radical, are naphthalene or hydrogenated naphthalene, and R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl. The compounds of this invention may be used as the free base or as a protic acid salt and are important intermediates for the manufacture of microbicides for plant protection.

    摘要翻译： 式（I）的2-氨氧基亚甲基苯基乙酸酯衍生物其中Z 1和Z 2是氢，卤素，羟基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，C 1 -C 4烷基羰基，苯氧基，硝基或 氰基或Z 1和Z 2与连接的苯基一起是萘或氢化萘，并且R 3是氢或C 1 -C 12烷基。 本发明的化合物可以用作游离碱或质子酸盐，并且是制备用于植物保护的杀微生物剂的重要中间体。