Heterocyclic substituted thio and sulfonyl glyoxylinitrileoxime
phosphates and phosphonates
    44.
    发明授权
    Heterocyclic substituted thio and sulfonyl glyoxylinitrileoxime phosphates and phosphonates 失效
    杂环取代的硫代和磺酰基乙醛酰肟磷酸酯和膦酸酯

    公开(公告)号:US4006154A

    公开(公告)日:1977-02-01

    申请号:US605587

    申请日:1975-08-18

    Inventor: Arnold D. Gutman

    CPC classification number: C07F9/4096 C07D277/74 C07F9/1657 C07F9/4075

    Abstract: Compounds of the formula ##STR1## in which R is lower alkyl; R.sub.1 is lower alkyl or lower alkoxy; X is thio or sulfonyl; R.sub.2 is alkyl, benzothiazol-2-yl, benzyl, naphthyl, benzimidazol-2-yl, thiazol-2-yl, phenyl or substituted phenyl wherein said substituents are chloro, bromo, methyl or methoxy and the use of these compounds as insecticides.

    Abstract translation: 其中R为低级烷基的式“IMAGE”的化合物; R1是低级烷基或低级烷氧基; X是硫代或磺酰基; R2是烷基,苯并噻唑-2-基,苄基,萘基,苯并咪唑-2-基,噻唑-2-基,苯基或取代的苯基,其中所述取代基是氯,溴,甲基或甲氧基,以及这些化合物作为杀虫剂。

    Process for oxidizing 2-mercaptobenzothiazole
    47.
    发明授权
    Process for oxidizing 2-mercaptobenzothiazole 失效
    氧化2-巯基苯并噻唑的方法

    公开(公告)号:US3654297A

    公开(公告)日:1972-04-04

    申请号:US3654297D

    申请日:1969-02-10

    CPC classification number: C07D277/74 C07D277/78

    Abstract: A PROCESS FOR OXIDIZING 2-MERCAPTOBENZOTHIAZOLE BY HEATING AN ORGANIC SOLUTION THEREOF, CONTAINING LESS THAN 15% WATER IN THE PRESENCE OF A FREE-OXYGEN CONTAINING GAS AND A CATALYTIC AMOUNT OF A COBALT PHTHALOCYANINE SULFONATE AT A TEMPERATURE BETWEEN 25* C. AND 200 C. THE PRODUCT 2.2''-DITHIOBISBENZOTHIAZOLE IS PRODUCED IN SIGNIFICANT AMOUNTS BY CONDUCTING THE REACTION AT A TEMPERATURE OF FROM ABOUT 50* C. TO 80* C., WHILE THE PRODUCT 2.2''-THIOBISBENZOTHIAZOLE IS PRODUCED IN SIGNIFICANT AMOUNTS WHEN THE REACTION TEMPERATURE IS FROM ABOUT 130* C. TO 180* C.

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