Reinforced high polymers, process for preparing same and battery having
same
    42.
    发明授权
    Reinforced high polymers, process for preparing same and battery having same 失效
    增强高分子聚合物,其制备方法和具有相同的电池

    公开(公告)号:US4560633A

    公开(公告)日:1985-12-24

    申请号:US705861

    申请日:1985-02-27

    摘要: A reinforced acetylene high polymer shaped article is provided, which is comprised of an acetylene high polymer and 10 to 500 wt. parts, per 100 wt. parts of the acetylene high polymer, of a sheet-form product of a fibrous material. The reinforced acetylene high polymer shaped article is prepared by polymerizing acetylene in the presence of the sheet-form product coated or impregnated with a catalyst solution, or by superposing the acetylene high polymer upon the sheet-form product and then pressing or calendering the superposed assembly. The reinforced acetylene high polymer shaped article is useful particularly as an electrode of a battery.

    摘要翻译: 提供了一种加强的乙炔高聚物成型制品,其由乙炔高聚物和10至500重量% 份,每100重量份 乙炔高聚物的一部分,是纤维材料的片状产品。 通过在涂覆或浸渍催化剂溶液的片状产品的存在下,或者通过将乙炔高聚合物叠加在片状产品上,然后压制或压延叠加的组件来制备加强的乙炔高分子成型制品, 。 加强型乙炔高聚物成形制品特别用作电池的电极。

    Electrically conductive blends of an acetylene polymer and an elastomer
having low unsaturation
    45.
    发明授权
    Electrically conductive blends of an acetylene polymer and an elastomer having low unsaturation 失效
    乙炔聚合物和具有低不饱和度的弹性体的导电共混物

    公开(公告)号:US4510075A

    公开(公告)日:1985-04-09

    申请号:US554610

    申请日:1983-11-23

    CPC分类号: H01M4/60 C08L49/00 H01B1/125

    摘要: Electrically conductive polymer blends of an acetylene polymer and an elastomer having a low level of unsaturation are disclosed herein. The low level of unsaturation provides resistance to heat, light, oxygen and ozone and yet provides sufficient sites for crosslinking of the blend to provide increased stability. These blends exhibit high conductivity upon doping with electron donors or electron acceptors.

    摘要翻译: 本文公开了乙炔聚合物和具有低不饱和度水平的弹性体的导电聚合物共混物。 低的不饱和度提供对热,光,氧和臭氧的耐受性,并且提供足够的共混物交联位点以提供增加的稳定性。 这些共混物在掺杂电子给体或电子受体时表现出高的导电性。

    Carboxylated poly(arylacetylenes)
    49.
    发明授权
    Carboxylated poly(arylacetylenes) 失效
    羧基化聚(芳基乙炔)

    公开(公告)号:US3993711A

    公开(公告)日:1976-11-23

    申请号:US559867

    申请日:1975-03-19

    申请人: Aron S. Watson

    发明人: Aron S. Watson

    CPC分类号: C08L49/00 C08F8/06

    摘要: The invention relates to poly (arylacetylenes) which have been modified by oxidation to introduce carboxyl functionality into the polymer molecule. Representative of the poly (arylacetylenes) is the polymer prepared by aromatization of diethynylbenzene. The carboxylated polymers produced from these poly (arylacetylenes) are useful as coupling agents to improve the adhesion of the parent polymers to metal surfaces and inorganic substrates.

    摘要翻译: 本发明涉及通过氧化改性以将羧基官能团引入聚合物分子中的聚(芳基乙炔)。 聚(芳基乙炔)的代表是通过二乙炔基苯的芳构化制备的聚合物。 由这些聚(芳基乙炔)生产的羧化聚合物可用作偶联剂,以改善母体聚合物与金属表面和无机基材的粘合性。

    Process for producing shaped articles from an acetylenic polymer
    50.
    发明授权
    Process for producing shaped articles from an acetylenic polymer 失效
    从炔属聚合物生产成型制品的方法

    公开(公告)号:US3933957A

    公开(公告)日:1976-01-20

    申请号:US394168

    申请日:1973-09-04

    申请人: Dwain M. White

    发明人: Dwain M. White

    摘要: When a hot, homogeneous solution containing at least 4 percent by weight of a copolymer of a diethynylbenzene and a dipropargyl ether of a dihydric phenol in nitrobenzene or a liquid halobenzene solvent is allowed to cool in contact with a shaping surface, a shaped gel is formed. Contacting the shaped article with a lower alkyl ketone which is a nonsolvent for the acetylenic polymer but in which the halobenzene is soluble and then allowing the shaped object to dry causes the gel to shrink isotropically so that it retains the shape, although diminished in size, which it assumed on solidifying. If the halobenzene solvent is crystalline at room temperature, the solvent crystallizes in the polymer matrix as it cools. Extraction with a lower alkyl ketone or sublimation of the solvent crystals produces a shaped article having a microporous structure. The shaped articles are readily converted by heating in an inert atmosphere to the same shaped carbon articles which can be amorphous, vitreous or graphitic depending on the heating schedule and the maximum temperature to which the articles are heated.

    摘要翻译: 当在硝基苯或液体卤代苯溶剂中含有至少4重量%的二乙炔基苯和二元酚的二丙炔基醚的共聚物的热均匀溶液与成形表面接触时冷却,形成成形的凝胶 。 将成型制品与作为炔属聚合物的非溶剂的低级烷基酮接触,但其中卤代苯可溶,然后允许成形物体干燥,使凝胶各向同性收缩,使得其保持形状尽管尺寸减小, 它在凝固时假定。 如果卤代苯溶剂在室温下是结晶的,则溶剂在冷却时在聚合物基质中结晶。 用低级烷基酮提取或溶剂晶体的升华产生具有微孔结构的成型制品。 通过在惰性气氛中加热成型制品,可以根据加热方案和制品被加热的最高温度,使其成为可以是无定形的,玻璃状的或石墨的相同的成形碳制品。