摘要:
The instant invention pertains to an organopolysiloxane composition for the formation of a cured release film wherein said organopolysiloxane composition cures rapidly under exposure to ultraviolet radiation to form a cured film that tightly adheres to various types of supports or base materials.The organopolysiloxane composition for the formation of a cured release film of the instant invention is comprised of (A) an organopolysiloxane that contains in each molecule at least 2 higher alkenyl groups as represented by the general formulaH.sub.2 C.dbd.CH--(CH.sub.2).sub.n --wherein n has a value of 2 to 8, (B) an organopolysiloxane that contains at least 2 mercaptoalkyl groups in each molecule, (C) an organopolysiloxane selected from the group consisting of organopolysiloxanes that contain in each molecule 1 higher alkenyl group with the general formulaC.sub.2 C.dbd.CH--(CH.sub.2).sub.n -wherein n=2 to 8 and organopolysiloxanes that contain 1 mercaptoalkyl group in each molecule, and (D) a photosensitizer.
摘要:
The combination of an organic peroxide, a platinum-containing hydrosilation catalyst that is encapsulated within microparticles of a thermoplastic silicone resin, and acetylenic alcohol as the platinum catalyst inhibitor imparts a unique and desirable combination of properties to organosiloxane compositions curable by a platinum-catalyzed hydrosilylation reaction when the compositions contain a gum-type organopolysiloxane as the major ingredient. The compositions have long term storage stability and cure completely when molded. Cured articles molded from the compositions exhibit excellent mold release properties together with the absence of scorching, mold staining and surface tackiness.
摘要:
A method for producing powder mixtures capable of inducing an even more intimate, microhomogeneous intermixing in a heterogeneous powder composed of at least two types of powders. The method is effective even for the mixing of an aggregable powder and a nonaggregable powder. According to the method, a heterogeneous powder composed of at least two type of powders that have been preliminarily mixed by stirring is introduced into an inlet while a rotating axle is turning and is axially transported within a cylinder by a screw. As the heterogeneous powder passes between rotating disks and fixed disks, it is subjected to a highly efficient mixing by compression and shear forces due to a sliding-shear action exerted between depressions and elevations installed on the opposing surfaces of the rotating disks and fixed disks. The mixture passes in sequence through multiple stages of the rotating and fixed disks. A powder mixture, which has been microhomogeneously interdispersed, is discharged from the outlet.
摘要:
This invention pertains to electroviscous fluids comprising a dispersion in an electrical insulating fluid of microparticles that are comprised of a polyelectrolyte or a mixture of a polyether and a polyelectrolyte wherein said polyelectrolyte consists of a carboxyaryl group-containing organopolysiloxane that has been neutralized by a base containing a monovalent or divalent metal. The electroviscous fluids of this invention provide a high electroviscous effect and good dispersion stability, and they are thermally stable and do not abrade surrounding equipment.
摘要:
Silicone resins containing monorganosiloxane and diorganosiloxane units and exhibiting reproducible values of molecular weight and dispersity are prepared by condensing a mixture of hydrolyzed silanes, adjusting the solids content of the condensed resin and then subjecting the resultant product to a re-equilibration reaction in the presence of an alkali metal compound.
摘要:
The present invention relates to a polyester-fiber-treatment agent that can impart smoothness and flexibility to polyester fiber at the same time that it also equips the polyester fiber with nonflammability. The treatment agent for the polyester fiber is based on an organosilicon compound that contains an organic group comprising a bromine-containing organic group bonded to silicon via carbon where the organosilicon compound has a bromine content of at least 5 weight percent.
摘要:
The present invention relates to a method for removing a silicone resin coating from a substrate comprising contacting the silicone resin coating with an aqueous alkali solution, wherein the silicone resin in the coating is a solid silicone resin having the formula (HR.sub.2 SiO.sub.1/2).sub.n (SiO.sub.4/2).sub.m, wherein R is an alkyl group, m is a number greater than 0, n is a number greater than 0, and n/m is greater than 0.2.
摘要:
The instant invention pertains to a high-productivity. high-yield method for the preparation of acryloxy group-containing or methacryloxy group-containing organosilicon compounds. The method of the instant invention comprises an addition reaction, in the presence of a hydrosilylation-reaction catalyst, between (A) an ester of acrylic acid with aliphatic ally unsaturated alcohol or aliphatically unsaturated phenol; or (B) an ester of methacrylic acid with aliphatically unsaturated alcohol or aliphatically unsaturated phenol; and (C) a silicon compound that contains silicon-bonded hydrogen and by then distilling the reaction mixture in the presence of a metal halide.
摘要:
There is described an organopolysiloxane which contains at least 2 amino groups, carboxyl groups, hydroxyl groups, or epoxy-functional organic groups at one and only one molecular chain terminal, as well as a method for the preparation of same. The organopolysiloxane has the formula ##STR1## wherein R is a monovalent hydrocarbon group which is free of aliphatically unsaturated bonds and wherein the groups R may be identical or different; A' is selected from the group consisting of groups, the carboxyl group, the hydroxyl group, and epoxy-functional organic groups; B is the same or a different divalent organic group having at least 2 carbon atoms; m is zero or one; and n is an integer with a value of zero to 200.
摘要:
A polyimide resin is prepared by reaction of a tetracarboxylic dianhydride with a specified class of amino functional organosilicon compounds followed by cycloimidization of the resultant polyamide acid intermediate. The resin is characterized by an excellent adhesion to various types of inorganic substrates such as glass. The present method employs relatively low temperatures for the cycloimidization reaction.