摘要:
In a first step, basic components including (A) 100 parts by weight of an organopolysiloxane gum, (B) 5-100 parts by weight of a reinforcing silica filler, and (C) 0.1-30 parts by weight of a processing aid are fed batchwise to a closed mixer for mixing them at a temperature of room temperature to 150.degree. C. In a second step, the mixture is fed into a kneader/mixer for heat treating at a temperature of 150-250.degree. C. The first step achieves quick dispersion and cooperates with the second step to form a heat-curable silicone rubber compound in an efficient manner.
摘要:
A silicone rubber composition comprising an organopolysiloxane and a reinforcing silica filler can be improved in crepe hardening and shelf stability by blending a specific compound as a wetter.
摘要:
The silicone rubber composition of the present invention comprises (A) an organopolysiloxane obtained by mixing and heating an organopolysiloxane having a silanol group at both ends of the molecular chain and a silane or a siloxane having two hydrolyzable groups in the molecule, (B) a finely divided silica, and (C) a curing agent. The composition, wherein the content of low-molecule siloxanes is remarkably constrained, is quite useful in the application wherein low-molecular siloxanes are obnoxious, for example, in the application of electrical contacts and parts used adjacent thereto, roll materials of copying machines, gaskets for construction, etc.
摘要:
To a silicone rubber composition including (A) a diorganopolysiloxane having an aliphatic unsaturated hydrocarbon group, (B) an organohydrogenpolysiloxane having at least two SiH groups in a molecule, and (C) a platinum catalyst, is added (D) an organic silicon compound of the following general formula (2): ##STR1## wherein R.sup.2, R.sup.5, and R.sup.6 are independently selected from monovalent hydrocarbon groups free of an aliphatic unsaturated bond, R.sup.3 is a monovalent hydrocarbon group, R.sup.4 is hydrogen or methyl, and n is an integer of 0 to 3. The composition has a long pot life after addition of curing components (B) and (C) and is extrusion moldable into bubble-free transparent parts. The composition is prepared by mixing component (A) with components (B) and (C) while adding component (D) thereto.
摘要:
A manufacturing method of organosilanes having silanol groups which is characterized by mixing organoalkoxy silanes, having at most a 20 ppm content of chlorine, expressed by the general chemical formula (1) below:Si(R.sup.1).sub.m (R.sup.2).sub.n (OR.sup.3).sub.k (1)wherein each of R.sup.1 and R.sup.2 is either a substituted or unsubstituted monovalent hydrocarbon group; R.sup.3 is an alkyl group of 1 to 4 carbon atoms; subscripts m and n are 0, 1, 2, or 3; k is either 1 or 2; and the sum of subscripts m+n+k=4, with ion-exchanged water having an electroconductivity of at least 10.sup.10 M.OMEGA., then further adding a macro-porous cation-exchange resin with a pore volume measured by the mercury injection method of at least 0.1 ml/g to the said mixture, followed by stirring of the mixture and removal of the cation-exchange resin. According to the present invention, organosilanes having silanol groups which are useful as a dispersing agent in silicone rubbers may be obtained by a simple process from organoalkoxy silanes, such as relatively inexpensive dimethoxy dimethyl silane.
摘要翻译:具有硅烷醇基的有机硅烷的制造方法,其特征在于混合由通式(1)表示的含有至多20ppm含量的有机烷氧基硅烷:Si(R 1)m(R 2)n(OR 3)k (1)其中R1和R2各自为取代或未取代的单价烃基; R3是1-4个碳原子的烷基; 下标m和n分别为0,1,2或3; k是1或2; 和下标m + n + k = 4的总和,其中离子交换水的电导率至少为1010M欧米茄,然后进一步加入具有通过汞注入法测量的孔体积的大孔阳离子交换树脂 至少0.1ml / g,然后搅拌混合物并除去阳离子交换树脂。 根据本发明,可以通过有机烷氧基硅烷如相对廉价的二甲氧基二甲基硅烷的简单方法获得在硅橡胶中用作分散剂的具有硅烷醇基的有机硅烷。
摘要:
An expandable conductive-silicone rubber composition includes (A) an organopolysiloxane having at least two alkenyl groups, (B) conductive carbon black, (C) an organic peroxide of the formula: ##STR1## wherein R.sup.2 and R.sup.3 each are a monovalent C.sub.3 -C.sub.10 hydrocarbon group or a group of --SiR.sup.4.sub.3 wherein R.sup.4 is methyl, ethyl or phenyl, X is --(CH.sub.2).sub.n --, --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 -- or --(C.sub.2 H.sub.4 O).sub.m --C.sub.2 H.sub.4 -- wherein n=2 to 8 and m=1 to 4, (D) an organohydrogenpolysiloxane, (E) a platinum catalyst, and (F) a blowing agent. It is fully stable during shelf storage, has a long pot life, and is rapidly expandable and curable through hot air vulcanization into conductive silicone rubber foam having high conductivity and improved fatigue endurance of sponge cells when the foam is used as a sponge roll.
摘要:
A silicone rubber composition comprising (A) an organopolysiloxane, (B) an organic peroxide and (C) carbon black cures under anaerobic conditions into silicone rubber having improved physical properties. A composition further comprising (D) an organopolysiloxane copolymer consisting essentially of M and Q units in a molar M/Q ratio of 6/10 to 9/10 forms an anaerobic adhesive composition which is a useful sealant.
摘要:
A silicone rubber composition comprising (A) an alkenyl-containing organopolysiloxane, (B) a polycyclic aromatic compound having at least two phenyl groups, and (C) finely divided silica is easy to process and cures to silicone rubber having low hardness while retaining good physical properties.
摘要:
A conductive silicone rubber composition comprises a conductive silicone rubber composition comprising:(a) an organopolysiloxane of the following general formula (1): ##EQU1## wherein R.sup.1 is an unsubstituted or substituted monovalent hydrocarbon group having 1 to 10 carbon atoms and "a" is a positive number of 1.90 to 2.05,(b) conductive carbon black, and(c) an organic peroxide of the following general formula (2): ##STR1## wherein X is --CH.sub.2).sub.n in which "n" is an integer of 2 to 8 or ##STR2## and R.sup.2 and R.sup.3 are independently selected from monovalent hydrocarbon groups having 3 to 10 carbon atoms and --SiR.sub.3.sup.4 in which R.sup.4 is a methyl, ethyl or phenyl group.
摘要:
A silicone rubber composition comprising an organopolysiloxane and a curing agent is improved by adding a foaming agent in an amount of 0.1 to 10 parts by weight per 100 parts by weight of the organopolysiloxane. The composition is heat curable into silicone rubber films or coatings which are substantially unfoamed and tack-free on a surface.