Aromatic polyester of 6,6'-(ethylenedioxy)di-2-naphthoic acid, process
for production thereof and film, fiber and other shaped articles
therefrom
    54.
    发明授权
    Aromatic polyester of 6,6'-(ethylenedioxy)di-2-naphthoic acid, process for production thereof and film, fiber and other shaped articles therefrom 失效
    6,6' - (亚乙二氧基)二-2-萘甲酸的芳族聚酯,其制备方法和薄膜,纤维和其它成型制品

    公开(公告)号:US4581438A

    公开(公告)日:1986-04-08

    申请号:US682760

    申请日:1984-12-17

    CPC分类号: C08G63/672 C08G63/6886

    摘要: A novel, substantially linear aromatic polyester comprising 6,6'-(ethylenedioxy)di-2-naphthoic acid as a main acid component and an aliphatic glycol having 2 to 10 carbon atoms in the main chain of the glycol as a main glycol component. The aromatic polyester is prepared by condensing an ethylene glycol diester of 6,6'-(ethylenedioxy)di-2-naphthoic acid, or a mixture of a major proportion of said naphthoate with a dicarboxylic acid, a diol, a hydroxycarboxylic acid or an ester-forming derivative thereof, at an elevated temperature. The aromatic polyester has excellent mechanical properties such as strength and Young's modulus.

    摘要翻译: 一种新型的基本上为线性的芳族聚酯,其包含作为主要酸成分的6,6' - (亚乙二氧基)二-2-萘甲酸和作为主要二元醇组分的二醇主链中具有2至10个碳原子的脂族二醇。 芳族聚酯通过将6,6' - (亚乙二氧基)二-2-萘甲酸的乙二醇二酯或主要比例的所述萘甲酸酯的混合物与二羧酸,二醇,羟基羧酸或 酯形成衍生物。 芳族聚酯具有优异的机械性能,如强度和杨氏模量。

    Process for producing porous, film-like or fibrous structure of aromatic
polyester
    55.
    发明授权
    Process for producing porous, film-like or fibrous structure of aromatic polyester 失效
    生产芳族聚酯多孔,薄膜状或纤维结构的方法

    公开(公告)号:US4419308A

    公开(公告)日:1983-12-06

    申请号:US479724

    申请日:1983-03-28

    摘要: A process for producing a porous, film-like or fibrous structure of an aromatic polyester, which comprises(1) forming a substantially non-oriented film-like or fibrous structure by melt-molding an aromatic polyester blend composed of(A) an aromatic polyester containing an aromatic dicarboxylic acid as a main acid component and an aliphatic diol and/or an alicyclic diol as a main glycol component, and(B) at least one low-molecular-weight compound selected from the group consisting of imide compounds and isocyanurate compounds being compatible, but substantially non-reactive, with the aromatic polyester and having a molecular weight of not more than 1,000, the amount of the low-molecular-weight compound being present in an amount of 10 to 300 parts by weight per 100 parts by weight of the aromatic polyester, and(2) extracting at least a major part of the low-molecular-weight compound from the resulting substantially non-oriented film-like or fibrous structure with an organic solvent which can dissolve the low-molecular-weight compound but under the extracting conditions does not substantially dissolve the aromatic polyester.

    摘要翻译: 一种制备芳族聚酯多孔,薄膜状或纤维结构体的方法,其包括(1)通过熔融模塑由(A)芳族化合物组成的芳族聚酯共混物形成基本上未取向的薄膜状或纤维结构体 含有作为主要酸成分的芳香族二羧酸和脂肪族二醇和/或脂环式二醇作为主要二醇成分的聚酯,(B)至少一种选自酰亚胺化合物和异氰脲酸酯的低分子量化合物 化合物与芳族聚酯相容但基本上不反应,分子量不超过1,000,低分子量化合物的量为每100份10至300重量份 的芳族聚酯,和(2)从有机溶剂得到的基本上未取向的膜状或纤维结构中提取至少大部分低分子量化合物 其可溶解低分子量化合物,但在萃取条件下基本上不溶解芳族聚酯。

    Process for producing aromatic polyesters having an increased degree of
polymerization
    57.
    发明授权
    Process for producing aromatic polyesters having an increased degree of polymerization 失效
    具有增加聚合度的芳族聚酯的制备方法

    公开(公告)号:US4331800A

    公开(公告)日:1982-05-25

    申请号:US144036

    申请日:1980-04-28

    IPC分类号: C08G69/44 C08G63/68

    CPC分类号: C08G69/44

    摘要: A process for producing an aromatic polyester having an increased degree of polymerization, which comprises reacting a substantially linear, fiber forming aromatic polyester containing terminal hydroxyl groups and having an aromatic dicarboxylic acid as a main acid component at an elevated temperature with a bis-cyclic imino ether compound of the formula [I] such as 2,2'-bis(2-oxazoline), 2,2'-bis(5,6-dihydro-4H-1,3-oxadine) thereby bonding the molecular chains of the aromatic polyester to each other by the terminal carboxyl groups thereof to rapidly form said aromatic polyester having an increased degree of polymerization.Said reaction can be carried out under atmospheric or elevated pressure.According to the process, an aromatic polyester having a low terminal caboxyl concentration and an increased degree of polymerization can be obtained.

    摘要翻译: 一种具有增加聚合度的芳族聚酯的制备方法,该方法包括使具有末端羟基并且具有芳族二羧酸作为主要酸成分的基本上直链的形成纤维的芳族聚酯在升高的温度下与双环亚氨基 醚化合物,如2,2'-双(2-恶唑啉),2,2'-双(5,6-二氢-4H-1,3-恶嗪等),由此将分子链 芳族聚酯通过其末端羧基彼此之间,以快速形成具有增加的聚合度的所述芳族聚酯。 所述反应可以在大气压或高压下进行。 根据该方法,可以得到具有低端甲氧基浓度和增加聚合度的芳族聚酯。