Dyeing or printing process with new and known cationic
4,5-dihydro-iH-1,2,3-triazolium compounds as dyestuffs and new cationic
4,5-dihydro-1H-1,2,3-triazolium compounds
    51.
    发明授权
    Dyeing or printing process with new and known cationic 4,5-dihydro-iH-1,2,3-triazolium compounds as dyestuffs and new cationic 4,5-dihydro-1H-1,2,3-triazolium compounds 失效
    新的和已知的阳离子4,5-二氢-h-1,2,3-三唑鎓化合物作为染料和新的阳离子4,5-二氢-1H-1,2,3-三唑鎓化合物的染色或印刷方法

    公开(公告)号:US5749925A

    公开(公告)日:1998-05-12

    申请号:US670913

    申请日:1996-06-26

    Abstract: 4,5-Dihydro-1H-1,2,3-triazolium compounds of the formula (I) ##STR1## in which R.sup.1 and R.sup.2 independently of one another denote C.sub.6 -C.sub.14 -aryl or a heterocyclic radical having up to 3 rings and up to 4 heteroatoms from the series consisting of O, S and N, R.sup.3 and R.sup.4 independently of one another denote hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.4 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.17 -aralkyl, C.sub.6 -C.sub.14 -aryl or nitrile or R.sup.3 and R.sup.4 together denote a 2- to 5-membered C bridge, which can optionally be interrupted by up to two oxygen and/or nitrogen atoms, and X.sup.- denotes an anion, wherein all the alkyl, alkenyl, cycloalkyl, aralkyl and aryl radicals and fused and heterocyclic radicals present can optionally be substituted by nonionic substituents, carboxyl groups, ammonium groups and/or pyridinium groups, are used as dyestuffs. New 4,5-dihydro-1H-1,2,3-triazolium compounds correspond to the formula (I), with the provisos that if R.sup.3 and R.sup.4 in each case denote hydrogen then in the case where R.sup.1 =4-methylphenyl R.sup.2 does not represent 4-nitrophenyl, 4-methoxyphenyl or phenyl and R.sup.1 and R.sup.2 do not both simultaneously represent 4-methylphenyl, 4-nitrophenyl, 4-methoxyphenyl or phenyl.

    Abstract translation: R 1和R 2彼此独立地表示的式(I)的化合物(I)的4,5-二氢-1H-1,2,3-三唑鎓表示C 6 -C 14 - 芳基或具有至多 3个环和至多4个由O,S和N组成的系列的杂原子,R 3和R 4彼此独立地表示氢,C 1 -C 12 - 烷基,C 2 -C 12 - 链烯基,C 4 -C 8环烷基,C 7 -C 17 - 芳烷基,C 6 -C 14 - 芳基或腈,或者R 3和R 4一起表示2-至5-元C桥,其可以任选地被多达两个氧和/或氮原子间隔,X-表示阴离子,其中所有 存在的烷基,烯基,环烷基,芳烷基和芳基以及稠合和杂环基团可任选被非离子取代基,羧基,铵基和/或吡啶鎓基取代,用作染料。 新的4,5-二氢-1H-1,2,3-三唑鎓化合物对应于式(I),条件是如果R 3和R 4在每种情况下表示氢,则在R1 = 4-甲基苯基R2的情况下 不代表4-硝基苯基,4-甲氧基苯基或苯基,R1和R2不同时表示4-甲基苯基,4-硝基苯基,4-甲氧基苯基或苯基。

    Bis(indolyl)ethylene process
    57.
    发明授权
    Bis(indolyl)ethylene process 失效
    双(吲哚基)乙烯工艺

    公开(公告)号:US4897494A

    公开(公告)日:1990-01-30

    申请号:US261945

    申请日:1988-10-24

    CPC classification number: C07D209/08 C07D209/24

    Abstract: Bis(indolyl)ethylenes of the formula ##STR1## wherein R.sub.1 denotes hydrogen, alkyl, aralkyl or aryl,R.sub.2 denotes hydrogen, alkyl or aryl,R.sub.3 denotes hydrogen, alkyl, alkenyl, COOH or aryl andR.sub.4 denotes hydrogen, alkyl, alkoxy, cycloalkoxy or halogen, andthese substituents, in turn, can carry non-ionic radicals or a carboxyl group,are obtained by reaction of indoles of the formula ##STR2## with carboxylic acids of the formulaR.sub.3 --CH.sub.2 --COOH (III)their chlorides, esters, for example alkyl esters, or anhydrides in the presence of phosphorus oxychloride.

    Abstract translation: 式(I)的双(吲哚基)乙烯其中R1表示氢,烷基,芳烷基或芳基,R2表示氢,烷基或芳基,R3表示氢,烷基,烯基,COOH或芳基,R4表示氢,烷基 ,烷氧基,环烷氧基或卤素,并且这些取代基又可以携带非离子基团或羧基,通过式(II)的吲哚与式R 3 -CH 2 - 的羧酸反应获得, COOH(III)它们的氯化物,酯,例如烷基酯或酸酐,在磷酰氯的存在下。

    Chromogenic 4,4-diaryldihydroquinazolones
    58.
    发明授权
    Chromogenic 4,4-diaryldihydroquinazolones 失效
    显色的4,4-二芳基二氢喹唑啉酮

    公开(公告)号:US4754034A

    公开(公告)日:1988-06-28

    申请号:US789686

    申请日:1985-10-21

    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.2 denote the remaining members of a 5- or 6-membered ring which may contain further hetero atoms andthe rings A, B and C and the radicals mentioned can in turn carry nonionic substituents customary in dye-stuff chemistry, find utility in pressure-copyable thermoreactive and electrochromic recording materials.

    Abstract translation: 式(I)的4-二芳基二氢喹唑啉酮其中X 1,X 2和X 3彼此独立地表示氢,卤素,烷基,芳基,烷酰基氨基,芳酰氨基,异酰基,NY1Y2,OY3或SY3,至少一个 的基团X 1,X 2或X 3代表NY1Y2,OY3或SY3,R1表示氢,烷基,环烷基,芳烷基,芳基或与环C的邻碳的桥的成员,R2表示酸的基团, Y 1,Y 2和Y 3彼此独立地表示氢,烷基,环烷基,芳烷基芳基或杂芳基或5-位或6-元环的其余成员,其到达位置苯C原子之一并且可以含有 另外的杂原子或Y1 + Y2表示可含有更多杂原子的5或6元环的剩余成员,并且环A,B和C以及所提及的基团可以依次携带染料化学中常规的非离子取代基 ,可用于压力可复制的热反应和电致变色记录材料。

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