公开(公告)号：US5043375A

公开(公告)日：1991-08-27

申请号：US614888

申请日：1990-11-16

申请人： Wolfgang Henning ,  Kirkor Sirinyan ,  Bruce Benda

发明人： Wolfgang Henning ,  Kirkor Sirinyan ,  Bruce Benda

IPC分类号： B05D7/02 ,  B32B27/32 ,  C08J7/04 ,  C08K5/05 ,  C08K5/06 ,  C09D7/12 ,  C09D123/26 ,  C09D123/28 ,  C09D151/06

CPC分类号： C09D7/125 ,  C08J7/047 ,  C09D123/26 ,  C09D123/28 ,  C09D151/06 ,  C09D7/1233 ,  C08K5/13 ,  C08L23/26 ,  C08L23/28

摘要： The present invention relates to a coating composition which contains a one- or two-component binder and, in addition,a) 0.1 to 15.0% by weight, based on the weight of the binder, of at least one coupling agent based on a chemically modified, amorphous polyolefin having an average molecular weight of 10,000 to 100,000, a non-uniformity of 1.0 to 6.5, a chlorine content of 2.5 to 50% by weight and a total content of nitrogen, oxygen, sulfur and silicon, in the form of chemically incorporated functional groups, of about 2.5 to 15% by weight, andb) 2.5 to 50% by weight, based on the weight of the amorphous polyolefin, of a bisphenol derivative corresponding to the formula ##STR1## The present invention also relates to a process for coating plastic substrates with this coating composition and to the coated plastics obtained therefrom.

摘要翻译： 本发明涉及一种涂料组合物，其含有一种或两种组分的粘合剂，另外，a）基于粘合剂重量的至少一种偶联剂为0.1至15.0重量％ 平均分子量为10,000至100,000，不均匀度为1.0至6.5，氯含量为2.5至50重量％，氮，氧，硫和硅的总含量的改性非晶形聚烯烃为 化学结合的官能团，约2.5至15重量％，和b）基于无定形聚烯烃的重量为2.5至50重量％的相应于下式的双酚衍生物。（I）本发明 还涉及用该涂料组合物涂覆塑料基材和由其获得的涂覆塑料的方法。

公开(公告)号：US4861663A

公开(公告)日：1989-08-29

申请号：US73567

申请日：1987-07-15

申请人： Kirkor Sirinyan ,  Hans-Joachim Laue ,  Rudolf Merten ,  Dietrich Michael ,  Milan-Josef Tima

发明人： Kirkor Sirinyan ,  Hans-Joachim Laue ,  Rudolf Merten ,  Dietrich Michael ,  Milan-Josef Tima

IPC分类号： C08J7/02 ,  C08J7/04 ,  C08J7/06 ,  H01B1/12

CPC分类号： C08J7/02 ,  C08J7/047 ,  C08J7/06 ,  C08J7/065 ,  H01B1/12 ,  C08J2377/00 ,  Y10S428/922 ,  Y10T428/31

摘要： The invention relates to a process for antistatic treatment or pretreatment for subsequent surface-coating of materials based on polyamides, polyimides or polyamideimides, where the molded articles of the material are treated with a solution of salt mixtures comprising(a) halides of elements of main groups 1 and/or 2 of the periodic system, in particular CaCl.sub.2, MgCl.sub.2, LiCl, NaCl and/or KCl and(b)(1) salts of weak inorganic bases with strong inorganic acids, in particular AlCl.sub.3, FeCl.sub.3, TiCl.sub.4, SbCl.sub.5, CaCl.sub.2, FeCl.sub.2, CuCl.sub.2, ZnCl.sub.2 and/or MoCl.sub.5(2) and/or the chelate complexes of (b1) with Schiff bases, amines, carboxylic acids, diketones, .alpha.,.beta.-unsaturated ketones and phosphines,(c) in a non-corrosive, organic swelling agent or solvent for the materials mentioned, where appropriate with the addition of water, preferably in an alcohol, at temperatures up to the boiling point of the solvents, preferably at temperatures of from -15.degree. C. to +60.degree. C., for from 0.5 to 30 minutes, and the molded articles are washed with water or solvents and subsequently dried.Antistatic molded articles treated by the process and molded articles pretreated for subsequent surface-coating, and the use thereof, are furthermore claimed.

摘要翻译： 本发明涉及用于随后的基于聚酰胺，聚酰亚胺或聚酰胺酰亚胺的材料表面涂层的抗静电处理或预处理的方法，其中材料的模制品用盐混合物溶液处理，所述盐混合物包含（a）主要元素的卤化物 特别是CaCl 2，MgCl 2，LiCl，NaCl和/或KCl的组1和/或2，和（b）（1）弱无机碱与强无机酸的盐，特别是AlCl 3，FeCl 3，TiCl 4，SbCl 5 ，CaCl 2，FeCl 2，CuCl 2，ZnCl 2和/或MoCl 5（2）和/或（b1）与席夫碱，胺，羧酸，二酮，α，β-不饱和酮和膦的螯合络合物，（c） 非腐蚀性有机溶胀剂或溶剂，适当时加入水，优选在醇中，在高达溶剂沸点的温度下，优选在-15℃至+ 60℃，0.5〜30分钟，a 然后用水或溶剂洗涤模制品，随后干燥。 还要求保护通过该方法处理的抗静电成型制品和预处理用于随后的表面涂覆的模塑制品及其用途。

公开(公告)号：US4820580A

公开(公告)日：1989-04-11

申请号：US180509

申请日：1988-04-12

申请人： Jurgen Hocker ,  Jurgen Faehndrich ,  Hans Hespe ,  Kirkor Sirinyan ,  Dieter Wecker

发明人： Jurgen Hocker ,  Jurgen Faehndrich ,  Hans Hespe ,  Kirkor Sirinyan ,  Dieter Wecker

IPC分类号： A43B9/12 ,  B32B5/20 ,  B32B27/16 ,  B32B3/26 ,  B05D5/00 ,  B29C37/00 ,  B32B5/18

CPC分类号： C08G18/10 ,  A43B9/12 ,  B32B27/16 ,  B32B5/20 ,  C08G18/4238 ,  C08G18/4812 ,  C08L75/04 ,  C08L75/06 ,  C08G2101/0008 ,  Y10T428/249953 ,  Y10T428/31551

摘要： Composite materials are formed by subjecting a highly elastic material to a plasma treatment and then allowing a polyurethane foam forming mixture to foam on the plasma treated surface. These composites are particularly useful as shoe soles and as insulating materials.

摘要翻译： 通过使高弹性材料进行等离子体处理，然后使聚氨酯泡沫形成混合物在等离子体处理的表面上发泡来形成复合材料。 这些复合材料特别用作鞋底和绝缘材料。

公开(公告)号：US4636441A

公开(公告)日：1987-01-13

申请号：US785175

申请日：1985-10-07

申请人： Kirkor Sirinyan ,  Gerhard D. Wolf ,  Ulrich von Gizycki ,  Rudolf Merten

发明人： Kirkor Sirinyan ,  Gerhard D. Wolf ,  Ulrich von Gizycki ,  Rudolf Merten

IPC分类号： C23C18/28 ,  C23C18/30 ,  H05K3/18 ,  B32B9/04

CPC分类号： H05K3/181 ,  C23C18/28 ,  Y10T428/31663 ,  Y10T428/31699

摘要： For the electroless metallization of base carriers for the manufacture of printed circuit boards, those carrier materials are outstandingly suitable on which complex compounds are built up in which the ligands and the ions to be complexed have entered a "host-guest interrelationship". Examples of such activator compounds are complexes of crown ethers, cryptands and the like. The resulting printed circuit boards are distinguished by the high adhesive strengths of the metals deposited on them.

摘要翻译： 对于用于制造印刷电路板的基底载体的无电金属化，这些载体材料非常适合于其中复合化合物被构建，其中配体和待络合的离子进入“主客体相互关系”。 这种活化剂化合物的实例是冠醚，穴状物等的复合物。 所得印刷电路板的特征在于沉积在其上的金属的高粘合强度。

公开(公告)号：US4554183A

公开(公告)日：1985-11-19

申请号：US665799

申请日：1984-10-29

申请人： Kirkor Sirinyan ,  Gerhard D. Wolf ,  Rudolf Merten ,  Ulrich von Gizycki

发明人： Kirkor Sirinyan ,  Gerhard D. Wolf ,  Rudolf Merten ,  Ulrich von Gizycki

IPC分类号： C08J7/12 ,  C23C18/28 ,  C23C18/30 ,  H05K3/18 ,  H05K3/38 ,  B05D3/10

CPC分类号： C08J7/12 ,  C23C18/28 ,  C08J2377/00 ,  H05K3/181 ,  H05K3/381

摘要： A mild activation process for the electroless metallization of polyamide mouldings comprises treating the mouldings with a solution of a mixture of halides of elements of the 1st and 2nd main group of the Periodic Table (for example CaCl.sub.2) with salts of weak inorganic bases and strong inorganic acids (for example AlCl.sub.3) in a swelling agent or solvent for polyamides and with a metal-organic complex compound of elements of the 1st or 8th sub-group of the Periodic Table. The sequence is here immaterial.

摘要翻译： 用于聚酰胺模制品的无电金属化的温和活化方法包括用周期表第一和第二主族元素的卤化物（例如CaCl 2）与弱无机碱和强无机碱的盐的溶液 在溶胀剂或聚酰胺溶剂中使用酸（例如AlCl 3）和元素周期表第1或第8族的元素的金属 - 有机络合物。 这个序列在这里是无关紧要的。

公开(公告)号：US4472458A

公开(公告)日：1984-09-18

申请号：US457554

申请日：1983-01-13

申请人： Kirkor Sirinyan ,  Rudolf Merten ,  Gerhard D. Wolf ,  Henning Giesecke ,  Uwe Claussen ,  Harold Ebneth

发明人： Kirkor Sirinyan ,  Rudolf Merten ,  Gerhard D. Wolf ,  Henning Giesecke ,  Uwe Claussen ,  Harold Ebneth

IPC分类号： H01L31/04 ,  H01L21/288 ,  H01L21/445 ,  H01L31/18

CPC分类号： H01L21/445 ,  H01L21/288 ,  H01L2924/0002 ,  Y10T428/31678

摘要： The firmly adhesive metallization, in particular partial metallization, of the surface of semiconductors is possible, without pickling, by carrying out the activation with organometallic compounds of metals of the IB and VIIIB Groups of the Periodic Table of Elements, then reducing in a conventional manner and metallizing without current.

摘要翻译： 通过用元素周期表的IB和VIIIB族金属的有机金属化合物进行活化，半导体表面的牢固粘合的金属化，特别是部分金属化是可能的，而不会酸洗，然后以常规方式进行还原 并且无电流金属化。