Spray drying of microcapsule dispersions
    54.
    发明授权
    Spray drying of microcapsule dispersions 失效
    喷雾干燥微胶囊分散体

    公开(公告)号:US4489017A

    公开(公告)日:1984-12-18

    申请号:US512974

    申请日:1983-07-12

    摘要: A process for spray drying aqueous suspensions of microcapsules having walls of polyurea which have been formed in known manner from polyisocyanate and polyamine by interface polyaddition, in which from 1 to 10 parts by weight, based on the microcapsules, of a water-soluble silicate and/or a water-soluble alkaline earth metal salt or hydroxide are added to the aqueous reaction mixture of polyisocyanate and polyamine.

    摘要翻译: 喷雾干燥具有以已知方式由聚异氰酸酯和多胺形成的聚脲壁的微胶囊的水性悬浮液的喷雾干燥方法,其中基于微胶囊1至10重量份的水溶性硅酸盐和 /或水溶性碱土金属盐或氢氧化物加入多异氰酸酯和多胺的含水反应混合物中。

    Crosslinkable graft polymer dispersion of organopolysiloxanes containing
hydrogen-siloxane groups and Si-vinyl groups
    55.
    发明授权
    Crosslinkable graft polymer dispersion of organopolysiloxanes containing hydrogen-siloxane groups and Si-vinyl groups 失效
    含有氢硅氧烷基团和Si-乙烯基基团的有机聚硅氧烷的可交联接枝聚合物分散体

    公开(公告)号:US4463127A

    公开(公告)日:1984-07-31

    申请号:US454893

    申请日:1982-12-30

    IPC分类号: C08F283/00 C08F283/12

    CPC分类号: C08F283/128

    摘要: A graft copolymer dispersion is produced by polymerizing a mixture comprising by weight approximately(a) 1 to 99% of an organopolysiloxane mass containing Si-H groups and vinyl groups, and(b) 99 to 1% of a polymerizable vinyl monomer.Polymerization initiators and/or molecular weight controllers may also be present. The product is not crosslinked as produced but can be blended with a crosslinking agent, applied to a textile as a coating and the crosslinked.

    摘要翻译: 通过聚合包含重量约(a)1至99%的含有Si-H基和乙烯基的有机聚硅氧烷物质的混合物和(b)99至1%的可聚合乙烯基单体来制备接枝共聚物分散体。 聚合引发剂和/或分子量控制剂也可以存在。 该产品不是如所生产的那样交联,而是可以与交联剂共混,作为涂层施涂到织物上并且交联。

    Stable, organic multi-component dispersions
    56.
    发明授权
    Stable, organic multi-component dispersions 失效
    稳定的有机多组分分散体

    公开(公告)号:US4444946A

    公开(公告)日:1984-04-24

    申请号:US344083

    申请日:1982-01-29

    摘要: The invention relates to special stable dispersions which crosslink at room temperature upon exposure to moisture in the atmosphere. The dispersions comprise polysiloxanes, vinyl-grafted polysiloxanes and condensation products, e.g. by weight approximately comprisingI. 20-90% of at least one diorganopolysiloxane optionally terminated by OH,II. 5-85% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C. and/or a vinyl monomer-grafted derivative thereof, andIII. 5-85% of at least one organopolysiloxane modified by grafting with at least one vinyl monomer and comprising(A) 10-90% of a diorganopolysiloxane optionally terminated by OH,(B) 10-90% of polymerized units of at least one vinyl compound, and(C) 0-80% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C.

    摘要翻译: 本发明涉及在暴露于大气中的水分时在室温下交联的特殊的稳定分散体。 分散体包括聚硅氧烷,乙烯基接枝的聚硅氧烷和缩合产物,例如 约20-90%的至少一种二羟基硅氧烷,任选被OH,II终止。 5-85%至少一种脂族或混合的脂族/芳族缩聚产物或加聚产物,玻璃温度TG高达40℃的聚醚或乙烯基聚合物和/或其乙烯基单体接枝衍生物和III 。 通过与至少一种乙烯基单体接枝改性的至少一种有机聚硅氧烷的5-85%,并且包含(A)10-90%的任选被OH封端的二有机聚硅氧烷,(B)10-90%的至少一种乙烯基的聚合单元 化合物,和(C)0-80%的至少一种脂族或混合的脂族/芳族缩聚产物或加聚产物,聚醚或乙烯基聚合物,玻璃温度TG高达40℃。

    Process for the production of methyl methacrylate homo- or co-polymers
    57.
    发明授权
    Process for the production of methyl methacrylate homo- or co-polymers 失效
    制备甲基丙烯酸甲酯均聚物或共聚物的方法

    公开(公告)号:US4369296A

    公开(公告)日:1983-01-18

    申请号:US243877

    申请日:1981-03-16

    CPC分类号: C08F20/14

    摘要: A process for the polymerization of methyl methacrylate or mixtures thereof with up to 25%, by weight, based on total monomer, of vinyl monomers copolymerizable therewith, wherein polymerization is carried out in the presence of from 0.01 to 10%, by weight, based on total monomer, of one or more enol ethers derived from aliphatic or cycloaliphatic aldehydes or ketones.

    摘要翻译: 一种聚合甲基丙烯酸甲酯或其混合物的方法,其具有至多25重量%的基于总单体的可与其共聚的乙烯基单体,其中聚合在0.01至10重量%的基础上进行,基于 在一个或多个衍生自脂族或脂环族醛或酮的烯醇醚的总单体上。

    Process for the preparation of ethylene-vinyl ester graft polymer
dispersions
    59.
    发明授权
    Process for the preparation of ethylene-vinyl ester graft polymer dispersions 失效
    乙烯 - 乙烯基酯接枝聚合物分散体的制备方法

    公开(公告)号:US4329267A

    公开(公告)日:1982-05-11

    申请号:US238996

    申请日:1981-02-27

    CPC分类号: C08F255/026 C08F263/02

    摘要: A process for the preparation of dispersions of optionally cross-linked ethylene-vinyl ester graft polymers wherein an ethylene-vinyl ester copolymer is used as graft substrate and a vinyl ester of a C.sub.1 -C.sub.18 carboxylic acid and/or a C.sub.1 -C.sub.10 -alkyl ester of acrylic and/or methacrylic acid are used as a graft monomer which is polymerized, optionally together with a cross-linking agent having two or more C--C double bonds, in organic solution until at least 25% by weight of the graft monomer has been reacted, the reaction product is converted into a stable finely divided dispersion by the addition of a precipitating agent under the action of shearing forces and polymerisation is completed before, during or after the formation of the dispersion.

    摘要翻译: 用于制备任选交联的乙烯 - 乙烯基酯接枝聚合物的分散体的方法,其中使用乙烯 - 乙烯基酯共聚物作为接枝基材和C1-C18羧酸和/或C1-C10-烷基的乙烯基酯 使用丙烯酸和/或甲基丙烯酸的酯作为接枝单体,其在有机溶液中任选地与具有两个或更多个CC双键的交联剂一起聚合,直到至少25重量%的接枝单体已经被 反应后,通过在剪切力的作用下加入沉淀剂将反应产物转化成稳定的细碎分散体,并且在形成分散体之前,期间或之后完成聚合。

    Polyurethane foams and elastomers based on modified polyether polyols
    60.
    发明授权
    Polyurethane foams and elastomers based on modified polyether polyols 失效
    基于改性聚醚多元醇的聚氨酯泡沫和弹性体

    公开(公告)号:US4230823A

    公开(公告)日:1980-10-28

    申请号:US65307

    申请日:1979-08-09

    CPC分类号: C08F283/06 C08G18/632

    摘要: The instant invention is directed to a process for the preparation of modified polyether polyols comprising polymerizing of from 1 to 50 parts by weight of a mixture of 20 to 100% by weight (based on the total quantity of monomers) of acrylonitrile and 0 to 80% by weight of styrene in 50 to 99 parts by weight of the polyether polyol in the presence of a polymerization initiator which yields radicals, wherein said polymerization is carried out in the presence of from 0.1 to 1.5% by weight, based on the total quantity of monomers put into the process, of a compound of the formula:A=CH--X--RwhereinA represents a divalent group ##STR1## R represents a C.sub.1-18 alkyl, C.sub.1-10 cycloalkyl, or substituted or unsubstituted benzyl group, R' represents C.sub.1-8 alkyl group,n represents 0, 1 or 2 andX represents oxygen or sulfur.

    摘要翻译: 本发明涉及一种制备改性聚醚多元醇的方法,其包括将1-50重量份的20至100重量%(基于单体总量)的丙烯腈和0至80重量份的混合物聚合 在产生自由基的聚合引发剂的存在下,在50至99重量份的聚醚多元醇中,苯乙烯的重量%,其中所述聚合在基于总量的0.1至1.5重量%的存在下进行 的下式化合物:A = CH-XR其中A表示二价基团R表示C1-18烷基,C1-10环烷基或取代或未取代的苄基,R' 表示C 1-8烷基,n表示0,1或2,X表示氧或硫。