公开(公告)号：US5149806A

公开(公告)日：1992-09-22

申请号：US500768

申请日：1990-03-28

Applicant: Dean M. Moren ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen

Inventor： Dean M. Moren ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen

IPC: C07D263/42 ,  C07D265/06 ,  C07D413/12 ,  C08G18/30 ,  C08G73/06 ,  C09D7/12 ,  C09D11/06 ,  C09J11/06

CPC classification number: C07D265/06 ,  C07D263/42

Abstract: Azlactone-functional Michael adducts are disclosed which are the Michael reaction products of 2-alkenyl azlactones and Michael donors selected from carbon and nitrogen nucleophiles. Reaction products which contain a plurality of azlactone groups are useful as step growth monomers in adhesives, sealants, and coatings.

公开(公告)号：US5081197A

公开(公告)日：1992-01-14

申请号：US602100

申请日：1990-10-23

Applicant: Steven M. Heilmann ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Sadanand V. Pathre

Inventor： Steven M. Heilmann ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Sadanand V. Pathre

IPC: C07D263/42 ,  C07D265/10 ,  C07D498/04 ,  C07D498/14 ,  C08F26/06 ,  C08F26/10 ,  C08F34/00 ,  C08F126/06

CPC classification number: C07D263/42

Abstract: This invention provides novel azlactone-functional oligomers of 2-alkenyl azlactones in which oligomerization has occurred predominantly via the 2-alkenyl group. Oligomerization of the 2-alkenyl group provides oligomers having 2 to 15 mer units with predominantly carbon-carbon backbone segments. Oligomerized in this fashion, the novel compositions possess azlactone groups which can be reacted with nucleophiles in the normal ring-opening sense. The oligomers are prepared by a novel process in which both Lewis and Bronsted acidic catalysts are effective. The reactive oligomers find utility as crosslinking agents for polymers containing azlactone-reactable nucleophilic groups.

Abstract translation: 本发明提供2-链烯基吖内酯的新型吖内酯官能低聚物，其中低聚主要通过2-链烯基发生。 2-烯基的低聚提供了具有主要为碳 - 碳骨架链段的2至15个mer单元的低聚物。 以这种方式低聚，新型组合物具有吖内酯基团，其可以以正常的开环方式与亲核试剂反应。 低聚物通过其中Lewis和Bronsted酸性催化剂都有效的新方法制备。 反应性低聚物可用作用于含有吖内酯可反应的亲核基团的聚合物的交联剂。

公开(公告)号：US5045615A

公开(公告)日：1991-09-03

申请号：US498044

申请日：1990-03-22

Applicant: Steven M. Heilmann ,  Larry R. Krepski ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Howell K. Smith, II

Inventor： Steven M. Heilmann ,  Larry R. Krepski ,  Dean M. Moren ,  Jerald K. Rasmussen ,  Howell K. Smith, II

IPC: C07C233/49 ,  C08F20/58

CPC classification number: C07C233/49 ,  C08F20/58

Abstract: Novel fluorinated, acrylamide monomers are prepared from 2-alkenyl azlactones reacted with fluorinated alcohols. The novel monomers have the formula ##STR1## wherein R.sup.1 and R.sup.6 are independently hydrogen or methyl; R.sup.2 and R.sup.3 independently can be an alkyl, cycloalkyl, or aryl group, or R.sup.2 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms;R.sup.4 and R.sup.5 are independently hydrogen or lower alkyl;a is 0 or 1;b is 1 or 2;X is a single bond, CH.sub.2, CH.sub.2 OCH.sub.2, and CH.sub.2 CH.sub.2 OCH.sub.2 ; andR.sub.F is a substantially perfluorinated alkyl, cycloalkyl, or aryl group when b is 1 and perfluorinated alkylene when b is 2.Novel polymers and copolymers can be prepared from the monomers of the invention.

Abstract translation: 从与氟化醇反应的2-链烯基吖内酯制备新的氟化丙烯酰胺单体。 新型单体具有式（III）其中R 1和R 6独立地为氢或甲基; R2和R3独立地可以是烷基，环烷基或芳基，或者R 2和R 3与它们连接的碳一起形成含有4-12个环原子的碳环; R4和R5独立地是氢或低级烷基; a是0或1; b为1或2; X是单键，CH2，CH2OCH2和CH2CH2OCH2; 当b为1时，RF为基本上全氟化的烷基，环烷基或芳基，当b为2时，RF为全氟化亚烷基。新颖的聚合物和共聚物可由本发明的单体制备。

公开(公告)号：US4837290A

公开(公告)日：1989-06-06

申请号：US217560

申请日：1988-07-11

Applicant: Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

Inventor： Jerald K. Rasmussen ,  Steven M. Heilmann ,  Frederick J. Palensky

IPC: C08F2/00 ,  C08F299/02 ,  C09D4/00 ,  C09J4/00

CPC classification number: C09D4/00 ,  C08F299/024 ,  C09J4/00

Abstract: A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oligomer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radically polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.

Abstract translation: 包含衍生自至少一种具有至少一个氨基，羟基或硫醇取代的聚氧化烯，聚亚烷基亚胺，聚酯，聚烯烃，聚丙烯酸酯或聚硅氧烷低聚物的亲核低聚物的丙烯酰氨基 - 酰基或甲基丙烯酰氨基 - 酰基低聚物的物质组合物， 公开了分子量在200至20,000范围内的亲核低聚物。 还公开了含有所述低聚物以及作为所述低聚物的热或光固化产物的丙烯酰氨基和甲基丙烯酰氨基酰化聚合物的可自由基聚合的含单体的组合物。 此外，公开了一种用于提供所述丙烯酰氨基和甲基丙烯酰氨基酰化的低聚物的方法，其可用于例如涂料，膜，印刷油墨，粘合剂和饱和物。

公开(公告)号：US4699843A

公开(公告)日：1987-10-13

申请号：US877794

申请日：1986-06-24

Applicant: Robert R. Charbonneau ,  Steven M. Heilmann ,  Jerald K. Rasmussen ,  Michael L. Tumey

Inventor： Robert R. Charbonneau ,  Steven M. Heilmann ,  Jerald K. Rasmussen ,  Michael L. Tumey

IPC: C09J133/08 ,  C08F26/06

CPC classification number: C09J133/08 ,  C09J2201/606 ,  Y10T428/2887 ,  Y10T428/2891

Abstract: Pressure-sensitive adhesives are prepared by the simultaneous polymerization of minor amounts of at least one alkenyl azlactone monomer and at least one arylic-functional carboxylic acid monomer, or precursors thereof, with a major amount of at least one acrylic monomer. The pressure-sensitive adhesives, after application to a substrate, will significantly increase in adhesion to the resultant bonded substrate after they are in the bonded configuration.

Abstract translation: 通过将少量的至少一种链烯基吖内酯单体和至少一种芳基官能的羧酸单体或其前体与主要量的至少一种丙烯酸单体同时聚合来制备压敏粘合剂。 施加到基材之后，压敏粘合剂在粘合构造之后的粘合性将显着增加。

公开(公告)号：US4694103A

公开(公告)日：1987-09-15

申请号：US865190

申请日：1986-05-19

Applicant: Larry R. Krepski ,  Howell K. Smith, II ,  Jerald K. Rasmussen ,  Steven M. Heilmann

Inventor： Larry R. Krepski ,  Howell K. Smith, II ,  Jerald K. Rasmussen ,  Steven M. Heilmann

IPC: C07C231/06 ,  A61K6/00 ,  C07B41/08 ,  C07B43/06 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C231/14 ,  C07C233/45 ,  C07C233/49 ,  C07C99/10

CPC classification number: A61K6/083 ,  A61K6/0029 ,  C07C233/45

Abstract: A novel, one-pot procedure for the preparation of N-acryloyl-.alpha.-amino acids involves the steps of:(i) reacting a ketone, an ammonium salt, and a cyanide salt in water, optionally in the presence of ammonium hydroxide and a co-solvent, to form an aminonitrile;(ii) acryloylating the aminonitrile in aqueous media to afford an acrylamidonitrile; and(iii) hydrolyzing with aqueous acid the acrylamidonitrile to provide the N-acryloyl-.alpha.-amino acid.

公开(公告)号：US4659801A

公开(公告)日：1987-04-21

申请号：US807351

申请日：1985-12-10

Applicant: Alan R. Katritzky ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen ,  Richard D. Tarr

Inventor： Alan R. Katritzky ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen ,  Richard D. Tarr

IPC: G03C1/10 ,  C07D277/20 ,  C07D277/36 ,  C08G73/06 ,  C08G75/00 ,  C08G75/32 ,  G03C1/34

CPC classification number: C08G75/32 ,  C08G73/06

Abstract: Novel polymers contain the [3H]-thiazole-2-thione ring system in the polymeric backbone. In another aspect, a method for preparing the poly(thiazolinethione) compounds is disclosed. The polymers are useful in the photographic arts.

Abstract translation: 新型聚合物在聚合物骨架中含有[3 H] - 噻唑-2-硫酮环系。 另一方面，公开了制备聚（噻唑啉硫酮）化合物的方法。 聚合物在照相艺术中是有用的。

公开(公告)号：US08586338B2

公开(公告)日：2013-11-19

申请号：US12993265

申请日：2009-05-27

Applicant: Mark R. Etzel ,  Yi He ,  Steven M. Heilmann ,  Jerald K. Rasmussen ,  Kannan Seshadri ,  Simon K. Shannon ,  Clinton P. Waller, Jr. ,  Douglas E. Weiss

Inventor： Mark R. Etzel ,  Yi He ,  Steven M. Heilmann ,  Jerald K. Rasmussen ,  Kannan Seshadri ,  Simon K. Shannon ,  Clinton P. Waller, Jr. ,  Douglas E. Weiss

IPC: C12N9/00 ,  C12N9/96 ,  C12N7/06 ,  C08C19/22

CPC classification number: B01D69/12 ,  B01D71/34 ,  B01D2325/12 ,  Y10T428/12264

Abstract: Ligand functionalized substrates, methods of making ligand functionalized substrates, and methods of using functionalized substrates are disclosed.

Abstract translation: 配体功能化底物，制备配体官能化底物的方法，以及使用官能化底物的方法。

公开(公告)号：US20130206571A1

公开(公告)日：2013-08-15

申请号：US13703009

申请日：2011-05-12

Applicant: Steven M. Heilmann ,  Kenneth J. Valentas ,  Marc Von Keitz ,  Frederick J. Schendel ,  Paul A. Lefebvre ,  Michael J. Sadowsky ,  Laurie A. Harned ,  Lindsey R. Jader

Inventor： Steven M. Heilmann ,  Kenneth J. Valentas ,  Marc Von Keitz ,  Frederick J. Schendel ,  Paul A. Lefebvre ,  Michael J. Sadowsky ,  Laurie A. Harned ,  Lindsey R. Jader

IPC: C10B53/02 ,  C11B3/00 ,  C11B3/02

CPC classification number: C10B53/02 ,  B01D9/0013 ,  B01D9/0036 ,  C08H8/00 ,  C10G1/02 ,  C10G1/04 ,  C10G3/00 ,  C10G3/40 ,  C10G31/09 ,  C10G2300/1014 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  C11B1/10 ,  C11B1/108 ,  C11B1/14 ,  C11B3/006 ,  C11B3/008 ,  C11B3/02 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/582 ,  Y02P30/10 ,  Y02P30/20

Abstract: The present invention concerns low energy requiring methods for processing low cellulosic biomass materials into oil, char and liquid components. One method comprises the steps of subjecting the biomass to hydrothermal carbonization under specified reaction conditions for producing a combined char and oil fraction as well as an aqueous fraction, separating the combined oil and char fraction from the aqueous fraction by filtration; separating the combined oil and char fraction into individual oil and char fractions using an organic solvent for forming an oil depleted char fraction and a liquid oil and solvent solution, and separating the liquid oil and solvent solution into individual oil and solvent fractions by distillation.

Abstract translation: 本发明涉及将低纤维素生物质材料加工成油，炭和液体组分的低能量需求方法。 一种方法包括以下步骤：在特定的反应条件下对生物质进行水热碳化，以生产组合的焦炭和油馏分以及含水级分，通过过滤将组合的油和炭馏分与水级分相分离; 使用有机溶剂将组合的油和焦炭馏分分离成单独的油和炭馏分以形成耗油的炭馏分和液体油和溶剂溶液，并通过蒸馏将液体油和溶剂溶液分离成单独的油和溶剂馏分。

公开(公告)号：US08414664B2

公开(公告)日：2013-04-09

申请号：US12715595

申请日：2010-03-02

Applicant: Steven M. Heilmann ,  Kenneth J. Valentas ,  Marc von Keitz ,  Frederick J. Schendel ,  Paul A. Lefebvre ,  Michael J. Sadowsky

Inventor： Steven M. Heilmann ,  Kenneth J. Valentas ,  Marc von Keitz ,  Frederick J. Schendel ,  Paul A. Lefebvre ,  Michael J. Sadowsky

IPC: C10L5/44

CPC classification number: C10L5/44 ,  C10L9/086 ,  Y02E50/10 ,  Y02E50/30

Abstract: Algae-derived synthetic coal and filtrates. The invention described herein provides an algae-derived synthetic coal product and filtrates and process for preparing the same using an improved hydrothermal carbonization process. The synthetic coal product is similar to natural bituminous coal in terms of percent carbon content and energy equivalency while at the same time containing relatively low levels of sulfur and contaminant heavy metals. Unlike natural coal and other fossil fuels, because the carbon of the biomass is formed through photosynthesis, carbon dioxide formed during combustion is a “carbon neutral” event with little or no “new” carbon dioxide being added to the earth's atmosphere. The algae-derived filtrates contain useful constituents.

Abstract translation: 藻类衍生的合成煤和滤液。 本文描述的本发明提供了一种藻类衍生的合成煤产品和滤液，以及使用改进的水热碳化方法制备该产品的方法。 合成煤产品与碳含量和能量当量的百分比类似于天然烟煤，同时含有较低含量的硫和污染重金属。 与天然煤和其他化石燃料不同，由于生物质碳通过光合作用形成，燃烧过程中形成的二氧化碳是碳中和事件，很少或没有新的二氧化碳被添加到地球大气中。 藻类衍生的滤液含有有用成分。